• Title/Summary/Keyword: degree of branching

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The Prediction of Crack Growth Retardation Behavior by Crack Tip Branching Effects (Fatigue Behavior in variable Loading Condition) (균열가지 효과를 고려한 균열 성장 지연 거동 예측 (변동하중하에서의 피로거동))

  • 권윤기
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.8 no.2
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    • pp.126-136
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    • 1999
  • We studied on crack growth retardation in single overloading condition. Crack tip branching which as the second mechanism on crack growth retardation was examined. Crack tip branching was observed to kinked type and forked type. It was found that the branching angle range was from 25 to 53 degree. The variations of crack driving force with branching angle were calculated with finite element method The variation of {{{{ KAPPA _I}}}}, {{{{ KAPPA _II}}}} and total crack driving force(K) were examined respectively So {{{{ KAPPA _I}}}}, {{{{ KAPPA _II}}}} and K mean to mode I, II and total crack driving force. Present model(Willenborg's model) for crack growth retardation prediction was modified to take into consideration the effects of crack tip branching When we predicted retardation with modified model. it was confirmed that predicted and experimental results coincided with well each other.

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Synthesis and Liquid Crystalline Properties of Hyperbranched Aromatic Polyesters Consisting of Azoxybenzene Mesogens and Polymethylene Spacers

  • Park, Young-Suk;Lee, Jun-Woo;Jin, Jung-Il
    • Bulletin of the Korean Chemical Society
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    • v.23 no.9
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    • pp.1201-1210
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    • 2002
  • A new series of hyperbranched aromatic polyesters containing azoxybenzene mesogens and polymethylene spacers were prepared by polymerizing AB2 type monomers that have the isophthaloyl dicarboxylic acid terminal at one end and the p-oxyp henol terminal at the other end. The monomers contain a built-in azoxybenzene mesogen that is linked to the terminal groups through polymethylene spacers. The polyesters prepared were characterized by solution viscosity, differential scanning calorimetry, X-ray diffractometry and polarizing microscopy. All of the polyesters were found to be thermotropic (nematic). Their glass-transition temperatures and mesophase temperature ranges were very sensitive to the length of the two spacers existing in the repeating unit. The degree of branching of one of the polyesters was determined by the NMR spectroscopy and found to be 0.56.

Physicochemical Properties of Corn Starch-derived Branched Dextrin Produced by a Branching Enzyme

  • Song, Eun-Bum;Min, Byoung-Cheol;Hwang, Eun-Sun;Lee, Hyong-Joo
    • Food Science and Biotechnology
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    • v.17 no.2
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    • pp.234-240
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    • 2008
  • The optimal conditions for the production of branched dextrin from com starch (CSBD) using branching enzyme (BE) were established by investigating the degree of retrogradation of the gelatinized starch. The physicochemical properties of CSBD prepared using the established process were evaluated. It was found that physicochemical properties of com starch were greatly modified by BE treatment. CSBD had a higher dextrose-equivalent value and water solubility than the corresponding control. On the other hand, the viscosities in gelatinized solution and amylose contents of CSBD were lower than those of the control. A high-performance size-exclusion chromatography/multiangle laser light scattering/retractive index (HPSEC/MALLS/RI) system showed that the average molecular weight of CSBD was lower than that of the control. The pasting viscosities of CSBD were stable during the entire temperature cycle. In general, the BE treatment resulted in the retrogradation during storage being lower for CSBD than for the control.

Effect of Acupuncture and High Frequency Therapy Applied to the Region Branching to the External Carotid Artery on Reduction of Facial Edema in Patients with Sequelae of Peripheral Facial Palsy: A Case Report (말초성 안면마비 후유증 환자에서 침 치료와 바깥목동맥으로의 분지 영역에 시행한 고주파 병행 치료의 안면부종 감소 효과: 증례보고)

  • An, Sunjoo;Choi, Seonghwan;Kang, Shinwoo;Park, Seohyun;Keum, Dongho
    • Journal of Korean Medicine Rehabilitation
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    • v.30 no.4
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    • pp.233-241
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    • 2020
  • This study was performed to evaluate the effect of high frequency therapy applied to the region branching to the external carotid artery for peripheral facial paralysis sequelae. A patient suffering with facial edema due to facial paralysis sequelae had been treated with acupuncture, high frequency therapy on the branch area to the external carotid artery for 7 weeks. The evaluation of clinical outcome was done by degree of swelling by measuring the distance of the face and skin temperature of face through digital infrared thermographic imaging. After treatment, the patient's degree of swelling and the temperature difference between the affected side and normal side was decreased. In addition, the temperature was changed in the entire facial area as well as the treatment point of high frequency therapy. This result shows that acupuncture combined with high frequency therapy at the region branching to the external carotid artery could be an effective way to improve facial blood flow, although further clinical studies will be needed.

Synthesis and Characterization of Low Viscosity Aromatic Hyperbranched Polyester Epoxy Resin

  • Zhang, Daohong;Jia, Demin;Zhou, Zihu
    • Macromolecular Research
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    • v.17 no.5
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    • pp.289-295
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    • 2009
  • Low viscosity aromatic hyperbranched polyester epoxy resin (HTBE) was synthesized by the reaction between epichlorohydrin (ECH) and carboxyl-end hyperbranched polyester (HTB) which was prepared from inexpensive materials $A_2$ (1,4-butanediol glycol, BEG) and $B_3$ (trimellitic anhydride, TMA) by pseudo one-step method. The molar mass of the HTB was calculated from its acid value by "Recursive Probability Approach". The degree of branching (DB) of the HTB was characterized by model compounds and $^1H$ NMR-minus spectrum technology, and the DB of the HTB was about $0.47{\sim}0.63$. The viscosity and epoxy equivalent weight of the HTBE were $3,600{\sim}5,000\;cp$ and lower than 540 g/mol respectively. The reaction mechanism and structure of the $AB_2$ monomer, HTB and HTBE were investigated by MS, $^1H$ NMR and FTIR spectra technology. The molecular size of HTBE is under 8.65 nm and its shape is ellipsoid-like as determined by molecular simulation.

Lipoic Acid Conjugated Chitosan Copolymer for the Delivery of 5-Fluorouracil (5-Fluorouracil 전달을 위한 리포산이 결합된 키토산 공중합체)

  • Lee, Sun-Young;Kim, Young-Jin
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.149-154
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    • 2012
  • The amphiphilic copolymer by the conjugation of biocompatible chitosan and antioxidant lipoic acid was studied as a drug delivery carrier. The amphiphilic copolymer was self-assembled to form nanoparticles in the aqueous solution. 5-Fluorouracil widely used as an anticancer drug was encapsulated inside the nanoparticles by a solid dispersion method. The degree of branching of lipoic acid on chitosan was controlled to obtain the optimal condition for the drug delivery carrier. The sizes of nanoparticles were about 250 nm by the dynamic light scattering. The encapsulation efficiency of nanoparticles were about 10%. The copolymer with 42% degree of branching showed the best performance as a drug delivery carrier.

A Study on the Physicochemical Properties of Buckwheat Starches (메밀 전분의 이화학적 특성에 관한 연구)

  • Lee, Mi-Sook;Sohn, Kyung-Hee
    • Korean journal of food and cookery science
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    • v.8 no.3
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    • pp.291-296
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    • 1992
  • The physicochernical properties of Korean buckwheat starches were investigated. The results were as follows; 1. Water binding capacity of kangwon hull buckwheat starch was 106.55% and that of Kangwon rice buckwheat was 99.35%. 2. The pattern of change in swelling power of hull buckwheat starch for increasing temperature started to increase at 60$^{\circ}C$ and increased rapidly from 80$^{\circ}C$, and that of rice buckwheat increased slowly from 60$^{\circ}C$ to 90$^{\circ}C$. 3. The ranges of gelatinization temp. of hull buckwheat and rice buckwheat starches were 70~75$^{\circ}C$ and 75~85$^{\circ}C$, respectively. 4. The blue value of hull buckwheat starch and rice buckwheat starch were 6.25 and 0.62, respectively. 5. The alkali number of hull buckwheat starch and rice buckwheat starch were 1.28 and 3.68 respectively. 6. The amylose content of hull buckwheat and rice buckwheat starch were 32.26% and 38.09%. 7. Periodate oxidation of hull buckwheat starch resulted that amylose had me average molecular weight of 103, 004, degree of polymerizatlon of 572 and amylopectin had me degree of branching of 7.64, glucose unit per segment of 13.09, and periodate oxidation of rice buck wheat starch resulted mat amylose had me average molecular weight of 125, 654, degree of polymerization of 698 and amylopectin had degree of branching of 6.59, glucose unit per segment of 15.16.

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Effect of Branching-agent Content on the Electrochemical Properties of Partially Fluorinated Poly(Arylene Ether Sulfone) Block Ionomer Membranes (부분불소계 Poly(Arylene Ether Sulfone) 블록이오노머막의 전기화학적 특성에 대한 분지체 함량의 효과)

  • Jeon, Seong-Hoon;Chang, Bong-Jun;Kang, Ho-Cheol;Kim, Jeong-Hoon;Joo, Hyeok-Jong
    • Membrane Journal
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    • v.21 no.1
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    • pp.1-12
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    • 2011
  • Partially fluorinated poly(arylene ether sulfone) block ionomer membranes with different branch degree for fuel cell applications were investigated. A sulfonable monomer, a non-sulfonable monomer and a trifunctional branching agent were synthesized and the sulfonable monomer was oligomerized to obtain block structures. The oligomer was then further polymerized with the non-sulfonable monomer and the branching agent. The mole ratio of oligomer : non-sulfonable monomer was fixed at 4:6 and the content of the branching agent was varied from 0 to 2 mol% (BBC-40Bx). Post-sulfonation of BBC-40Bx was carried out using chlorosulfonic acid (CSA) (SBBC-40Bx). All the synthesized compounds were characterized by $^1H$-NMR, $^{19}F$-NMR and FT-IR. It was confirmed that the ion exchange capacity (IEC), water uptake and ion conductivity of SBBC-40Bx increased with the increment of branching agent content.

Morphological and Cultural Characteristics of Trichoderma spp. Associated with Green Mold of Oyster Mushroom in Korea

  • Park, Myung-Soo;Seo, Geon-Sik;Lee, Kang-Hyun;Bae, Kyung-Sook;Yu, Seung-Hun
    • The Plant Pathology Journal
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    • v.21 no.3
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    • pp.221-228
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    • 2005
  • A total of 179 isolates of Trichoderma spp. were collected from oyster mushroom substrates in Korea. On the basis of morphological and cultural characteristics, Trichoderma isolates were divided into seven groups, namely T. atroviride, T. citrinoviride, T. harzianum, T. longibrachiatum, T. virens, and two unidentified species, referred to as Trichoderma sp. 1 and 2. The predominant species was Trichoderma sp. 2 (n=86) followed by Trichoderma sp. 1 (n=52). Trichoderma sp. 1 and 2 were morphologically distinct not only from the other species of Trichoderma reported but also from each other in the characteristics such as mycelial growth rate, colony appearance, shape of conidia and conidiophores and branching pattern of phialides, although branching pattern of phialides of Trichoderma sp. 1 was similar to that of T. harzianum. In virulence test, the degree for compost colonization of Trichoderma sp. 2 was significantly greater than that of the other Trichoderma species. Trichoderma sp. 2 was found to be the main cause of green mold disease in oyster mushroom production. More work including molecular characterization is needed to confirm the species of Trichoderma sp. 1 and 2.

Studies on the population biology of some clonal plants in a coastal reclaimed land

  • Choung, Yeon-Sook;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.14 no.3
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    • pp.327-343
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    • 1991
  • Clonal growth and rhizome architecture of calmagrostis epigeios, were studied in a 15-year old coastal reclamed land. As c. epigeios patch grew from center to margin radially over time, concentric annuli were added. the radial increases of the mature patch were 80~130cm/yr. the patch ages of c. epigeios estimated by relationships between the diameter and is radial increament, were 1~6year old. There were the marked variations of density, phytomass, shoot height and inflorecence frequency with increasing age of rhizome system within the patch. the maximum performance occurred at 2-year-old concentric annuli of the patch. The growth phasic continuum with aging was divided into 5 grwth phases ; pioneer, building, matyre, senile and degenerate. The rhizome aging had a more significant effect on the inflorescence frequency than on the other attributes. new rhizomes tended to diverge from the direction of the parent ramet by sympodial growth. in a 1-year-old patch, average length of rhizome segment was 7cm, average number of internode was 6, and the tillering frequency was 27%. The tillering in the early stage resultd in the increase of shoot density and the producation of multibranching rhizome. as the result of that, circular patchwas formed in a year. The branching structure based on such facts was represented graphically in branching degree of 60 and 100. therefore, c. epigeios with clonal growth may establish and grow vigorously earlier than other glycophytes in high salt conditions such as the coastal reclaimed land.

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