• Title/Summary/Keyword: decay properties

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J-aggregates of Merocyanine Dye : formation and structural change on chemical and thermal treatments (메로시아닌 색소의 J-회합체 ; 형성과 열.화학적인 처리에 의한 변화)

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1398-1400
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    • 1998
  • The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the case of optical absorption spectra of the LB films by the heat treatment at $70^{\circ}C$ in the air, both of the shifted absorption bands decay and a monomer absorption peak of about 530 nm appears instead. And, the formation and dissociation of J-aggregates, anisotropic behavior was no longer observed in the heat treated merocyanine dyes LB films. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorption peak shifts and mixed components.

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Relationship between Biodegradation of Biosynthetic Plastics, Poly-$\beta$-Hydroxybutyrate, and Soil Temperature (생합성 플라스틱 Poly-$\beta$-Hydroxybutyrate의 생분해와 토양온도의 관계)

  • 조강현;이혜미;조경숙
    • The Korean Journal of Ecology
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    • v.21 no.3
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    • pp.277-282
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    • 1998
  • The microbial degradation of $poly-{\beta}-hydroxybutyrate$ (PHB) films was studied in soil microco는 incubated at a constant temperature of 2, 10, 20, 30 and $40^{\circ}C$ for up to 49 days. The degradation rate measured through loss of weight was enhanced by incubation at a higher temperature. At the soil temperature $40^{\circ}C$, $poly-{\beta}-hydroxybutyrate$ was rapidly degraded at a decay rate of 3.5% weight loss per day. The degradation of $poly-{\beta}-hydroxybutyrate$ did not affected significantly the chemical properties of soils such as pH and electric conductivity. However, microbial activity of soil in terms of dehydrogenase activity was increased by the degradation of $poly-{\beta}-hydroxybutyrate$.

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MULTIPLE SCALE ANALYSIS OF A DELAYED PREDATOR PREY MODEL WITHIN RANDOM ENVIRONMENT

  • Saha, Tapan;Bandyopadhyay, Malay
    • Journal of applied mathematics & informatics
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    • v.26 no.5_6
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    • pp.1191-1205
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    • 2008
  • We consider a delayed predator prey model. The local stability and Hopf bifurcation results are stated taking the time delay as a control parameter. We apply multiple scale analysis to analyze the effects of additive white noises near the Hopf bifurcation point at the positive interior equilibrium state. The governing equations for the amplitude of oscillations on a slow time scale are derived. We identify the process of amplitude of oscillations and derive its transient properties. We show that oscillations, which would decay in the deterministic system whenever time delay lies below its critical value, persists for long time under the validity of multiple scale analysis.

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INVESTIGATION OF TRIPLET STATE AND SINGLET OXYGEN DYNAMICS OF BENZOPHENONE IN POLAR AND NONPOLAR SOLUTIONS WITH TIME-RESOLVED TWO-COLOR THERMAL LENSING METHOD

  • Ha, Jeong-Hyon
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.141-145
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    • 1996
  • The heat generated by nonradiative decay dynamics induces thermal lens effect. From such an effect, photodynamic properties of solutions can be investigated with two-color pulsed thermal lens experiments which have the time resolution of down to nanoseconds. In this study, using nanosecond two-color thermal lens method, we investigated the triplet state of benzophenone and the singlet oxygen state dynamics in various oxygen concentration solvents. The measured triplet state lifetimes, singlet oxygen relaxation times and singlet oxygen formation quantum yields are in good agreement with the reference values. From these parameters the existence of the triplet exciplex formation between benzophenone and benzene is proved, and it is also suggested that the relaxations of triplet states of benzophenone undergo coupled dynamics with some of singlet oxygens in oxygen-rich conditions.

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Synthesis and Properties of Novel T-type Nonlinear Optical Polyurethane Containing Tricyanovinylthienyl Group with Enhanced Thermal Stability of Dipole Alignment

  • Cho, You-Jin;Kim, Mi-Sung;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.424-430
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    • 2011
  • A novel T-type polyurethane 7 containing 1-(2,5-dioxyphenyl)-2-(5-(1,2,2-tricyanovinyl)-2-thienyl)ethenes as NLO chromophores, which constitute part of the polymer backbone, was prepared. Polyurethane 7 is soluble in common organic solvents such as DMF and DMSO. It shows a thermal stability up to $270^{\circ}C$ from TGA thermogram with $T_g$ value obtained from DSC thermogram near $155^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at 1560 nm fundamental wavelength is $3.56{\times}10^{-9}$ esu. Polymer 7 exhibits a thermal stability even at $5^{\circ}C$ higher than $T_g$, and no significant SHG decay is observed below $160^{\circ}C$, which is acceptable for nonlinear optical device applications.

Cold stroage of Citrus unshiu Marc. var. okitsu produced in Cheju (제주산 흥진조생 온주밀감의 저온저장)

  • Go, Jeong-Sam;Yang, Sang-Ho;Kim, Seong-Hak
    • Food Science and Preservation
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    • v.3 no.2
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    • pp.105-111
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    • 1996
  • The conditions of cold stroage of Citrus unshiu Marc. var. okitsu produced in Cheju were investigated. The changes of peel moisture contents soluble solids, total sugar, vitamin C and density were slightly occured, and decay ratio was below 20% on keeping freshness relatively till late of March during cold storage. After thats decayed citrus fruits were increased gradually mainly from cold injury with lower temperature and high humidity. The loss of fruit weight, decrease of fruit hardness, and decrease of acid content were occured gradually during cold stroage. Because of the difficulty of long term storage for Citrus unshiu, the conditions and periods of cold storage would be determined after considering the physicochemical properties of fruits every year.

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Study on the Test Method for Measuring Vibration Damping Properties using Bae Type Specimen (시험 방법에 따른 바(Bar) 형 시편의 동특성 비교)

  • Lee, Yong-Bong;Kwon, Hyu-Sang;Jung, Sung-Soo;Jun, Byung-Soo
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1939-1944
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    • 2000
  • Different test methods were used to measure and compare the loss factor of a steel beam. They are free vibration logarithmic decay method, half-power bandwidth method using narrow-band analysis, wide-band analysis method with inverse FFT. In these tests, specimens are clamped at one end. Free vibration method and half-power bandwidth method gave good results. Effect of vibration pick-ups were tested. We also tried center excitation method but could not obtain loss factor.

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Rapid Surface Heating Promotes Laser Desorption Ionization of Thermally Labile Molecules from Surfaces

  • Han, Sang Yun
    • Mass Spectrometry Letters
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    • v.7 no.4
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    • pp.91-95
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    • 2016
  • In recent years, matrix-free laser desorption ionization (LDI) for mass spectrometry of thermally labile molecules has been an important research subject in the pursuit of new ionization methods to serve as alternatives to the conventional matrix-assisted laser desorption ionization (MALDI) method. While many recent studies have reported successful LDI of thermally labile molecules from various surfaces, mostly from surfaces with nanostructures, understanding of what drives the LDI process still requires further study. This article briefly reviews the thermal aspects involved in the LDI mechanism, which can be characterized as rapid surface heating. The thermal mechanism was supported by observed LDI and postsource decay (PSD) of peptide ions produced from flat surfaces with special thermal properties including amorphous Si (a-Si) and tungsten silicide ($WSi_x$). In addition, the concept of rapid surface heating further suggests a practical strategy for the preparation of LDI sample plates, which allows us to choose various surface materials including crystalline Si (c-Si) and Au tailorable to specific applications.

Properties of Charge Accumulation in Glass under Electron Beam Irradiation (전자빔 조사중 유리의 전하축적 특성)

  • Park, Chan;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2305-2306
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    • 2008
  • Charging of spacecraft occurs in plasma and radiation environment. Especially, we focused on an accident caused by internal charging in a glass material that was used as the cover plate of solar panel array, and tried to measure the charge distribution in glass materials under electron beam irradiation by using a PEA (Pulsed Electro-Acoustic method) system. In the case of a quartz glass (pure $SiO_2$), no charge accumulation was observed either during or after the electron beam irradiation. On the contrary, positive charge accumulation was observed in glass samples containing metal-oxide components. It is found that the polarity of the observed charges depends on the contents of the impurities. To identify which impurity dominates the polarity of the accumulated charge, we measured charge distributions in several glass materials containing various metal-oxide components and calculated the trap energy depths from the charge decay characteristics of all glass samples.

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Aerosol filtration and electrostatic properties of electrospun nanofiber air filters (전기방사 나노섬유 에어필터의 정전기적 특성 및 에어로졸 여과특성)

  • Park, Hyun-Seol;Lim, Koung Soo
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.71-81
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    • 2009
  • In this study, Nylon 6,6 electrospun (ES) nanofiber filter media were prepared at various spinning conditions. The ES filters tested had no intrinsic electrical charges. The ES filters were triboelectrically charged in the course of filter sample handling, and the charge was drastically decayed in a few hours. On the other hand, the corona charged melt blown filter media showed a permanent electrical charge. The electrical charge state of the ES filters was also examined by comparing collection efficiencies of ES filters for uncharged and charged aerosol particles.

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