• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.11
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• pp.4664-4670
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• 2010

Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.

• International Journal of Industrial Entomology and Biomaterials
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• v.45 no.2
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• pp.56-69
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• 2022

Silk is a unique natural biopolymer with outstanding biocompatibility, high mechanical strength, and superior optical transparency. Due to its excellent properties, silk has been widely reported as an ideal biomaterial for several biomedical applications. Recently, fluorescent silk protein, a variant of native silk, has been reported as a biophotonic material with the potential for bioimaging and biosensing. Despite the realization of fluorescent silk, the traditional degumming process of fluorescence silk is crude and often results in fluorescence loss. The loss of fluorescent properties is attributed to the sensitivity of silk fibroin to temperature and solvent concentration during degumming. However, there is no comprehensive information on the influence of these processing parameters on fluorescence evolution and decay during fluorescent silk processing. Therefore, we conducted a spectroscopic study on fluorescence decay as a function of temperature, concentration, and duration for fluorescent silk cocoon degumming. Sodium carbonate solution was tested for degumming the fluorescent silk cocoons with different concentrations and temperatures; also, sodium carbonate solution is combined with Alcalase enzyme and triton x-100 to find optimal degumming conditions. Additionally, we conducted a molecular dynamics study to investigate the fundamental effect of temperature on the stability of the fluorescent protein. We observed degumming temperature as the prime source of fluorescent intensity reduction. From the MD study, fluorescence degradation originated from the thermal agitation of fluorescent protein Cα atoms and fluctuations of amino acid residues located in the chromophore region. Overall, degumming fluorescent silk with sodium carbonate and Alcalase enzyme solution at 25 ℃ preserved fluorescence.

• International Journal of Naval Architecture and Ocean Engineering
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• v.5 no.2
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• pp.227-245
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• 2013

Reliable strength assessment of the Liquefied Natural Gas (LNG) cargo containment system under the sloshing impact load is very difficult task due to the complexity of the physics involved in, both in terms of the hydrodynamics and structural mechanics. Out of all those complexities, the proper selection of the design sloshing load which is applied to the structural model of the LNG cargo containment system, is one of the most challenging one due to its inherent randomness as well as the statistical analysis which is tightly linked to the design sloshing load selection. In this study, the response based strength assessment procedure of LNG cargo containment system has been developed and proposed as an alternative design methodology. Sloshing pressure time history, measured from the model test, is decomposed into wavelet basis function targeting the minimization of the number of the basis function together with the maximization of the numerical efficiency. Then the response of the structure is obtained using the finite element method under each wavelet basis function of different scale. Finally, the response of the structure under entire sloshing impact time history is rapidly calculated by synthesizing the structural response under wavelet basis function. Through this analysis, more realistic response of the system under sloshing impact pressure can be obtained without missing the details of pressure time history such as rising pattern, oscillation due to air entrapment and decay pattern and so on. The strength assessment of the cargo containment system is then performed based on the statistical analysis of the stress peaks selected out of the obtained stress time history.

• Journal of Photoscience
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• v.9 no.2
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• pp.78-81
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• 2002

Fluorescence rise and decay curves of carotenoids were measured in solutions and in pigment protein complexes with a femtosecond time-resolved fluorescence spectroscopy. For linear carotenoids, the S$_2$ lifetimes showed the maximum value around n = 9-10. The conjugation of a keto-carbonyl group shortened the S$_2$lifetime and prolonged the S$_1$lifetime. The excitation relaxation dynamics within carotenoids and the excitation energy transfer kinetics from carotenoids to chlorophylls are discussed as a function of molecular structure of carotenoids.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.4 no.2
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• pp.83-90
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• 1992

A wave prediction model of DP type with shallow water effects is presented. An intercom-parison study of the shallow water wave models has been made to verify applicability of this model which has source functions of Inoue, propagation scheme by Gadd and dissipation functions due to bottom friction. The energy distribution shows reasonable results and for the bottom friction JONS-WAP decay function seems to be more appropriate.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1994.04a
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• pp.137-144
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• 1994

In this study, a new procedure for solving 2-D dynamic problems of semi-infinite medium in time domain by boundary element method (BEM) is presented. Efficient modelling of the far field region, infinite boundary elements are introduced. The shape function of the infinite boundary element is a combination of decay functions and Laguerre functions. Though the present shape functions have been developed for the time domain analysis, they may be also applicable to the frequency domain analysis. Through the response analysis in a 2-D half space under a uniformly distributed dynamic load, it has been found that an excellent accuracy can be achieved compared with the analytical solution

• Journal of Mechanical Science and Technology
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• v.17 no.10
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• pp.1485-1495
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• 2003

We investigate the triboelectrostatic separation of polyvinylchloride (PVC) from mixed plastics in the laboratory scale triboelectrostatic separation system. The flow and electric fields in the precipitator are obtained from the numerical solution of finite volume method. Using these flow and electric fields, we solved the particle motion equation considering the inertia, drag, gravity and electrostatic forces acted on the particles. The particle trajectories are obtained using a Lagrangian method as a function of different important variables such as Reynolds number, Stokes number, electrostatic force, electric charge and electric field distribution, inclined angle of plane electrodes, particle rebounding, particle charge decay rate after impact on the electrode surface, etc., in order to determine the optimal design conditions. The present predicted results for the cumulative yield represent well the experimental ones.

• Proceedings of the KIEE Conference
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• 1991.07a
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• pp.73-77
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• 1991

200hrs operational characteristics of the single cell in phosphoric acid fuel cell was studied. The initial performance of single cells was examined as a function of PTFE content of electrode in the range of 30 to 60 wt.%. The cell with the electrode of 40wt.% PTFE was chosen for the 200hrs operation. The cell voltage decay was found to be about 0.5mV/hr for 200hrs operation. These results of cell performance were discussed as related to the internal resistance and the exchange current density of the cell.

• Nuclear Engineering and Technology
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• v.2 no.4
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• pp.263-268
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• 1970

The spectrum of continuous transfer operator arising in a time-energy dependent neutron transport equation is analyzed. Four theorems concerning on the spectrum are proved. A convolution theorem of the generalized Mellin energy transform is given. Also the completeness theorem necessary for a final solution is proved. A unique time decay constant 1 - c is found, which is dominant asymptotically.

• Coupled systems mechanics
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• v.7 no.3
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• pp.255-268
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• 2018

Stability of MBC1, a specific matching boundary condition, is proved for atomic simulations of a diatomic chain. The boundary condition and the Newton equations that govern the atomic dynamics form a coupled system. Energy functions that decay along with time are constructed for both the boundary with the same type atoms and the one with different type atoms. For a nonlinear chain, MBC1 is also shown stable. Numerical verifications are presented. Moreover, MBC1 is proved to be stable for a two dimensional square lattice.