• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.829-832
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• 2004

The pure product of 2,3-diaminophenazine was prepared by the enzyme-catalyzed reaction of ophenylenediamine-$H_2O_2$-horseradish peroxidase and characterized by UV/Vis spectroscopy, IR spectroscopy and NMR spectroscopy. The electrochemical behaviour of 2,3-diaminophenazine on the glassy carbon electrode was studied. The interaction between 2,3-diaminophenazine and deoxyribonucleic acid was studied by cyclic voltammetry method and UV/Vis spectroscopy, which indicated that the interaction between them is intercalation. The influence of reacting time was also studied. The binding ratio of the 2,3-diaminophenazine-DNA complex is calculated to be 1 : 2 and the binding constant is to be $5.07{\times} 10^3L{\cdot}mol^{-1}$ at room temperature.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
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• pp.187-189
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• 1994

Lead-acid battery is used widely as a power source at a automobile, industrial machines, folk lifts, U.P.S. etc. Since lead-acid battery is cheaper than any other ones. But this battery has many disadvantages such as heavy, low energy density, environment problem etc. In this article, we introduce potential step methods to investigate corrosion behaviour of positive grids for lead alloys.

• Steel and Composite Structures
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• 제32권1호
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• pp.37-57
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• 2019

This paper presents experimental and analytical studies to evaluate the cyclic behaviour of Circular Reinforced Concrete column Steel beam (CRCS) connections. Two 3/4-scale CRCS specimens are tested under quasi-static reversed cyclic loading. Specimens were strengthened with a tube plate (TP) and a steel doubler plate (SDP). Furthermore; nine interior beam-through type RCS connections are simulated using nonlinear three-dimensional finite element method using ABAQUS software and are verified with experimental results. The results revealed that using the TP improves the performance of the panel zone by providing better confinement to the concrete. Utilizing the TP at the panel zone may absorb and distribute stress in this region. Results demonstrate that TP can be used instead of SDP. Test records indicate that specimens with TP, with and without SDP maintained their maximum strength up to 4% drift angle, satisfying the recommendation given by AISC341-2016 for composite special moment-resisting frames.

• Steel and Composite Structures
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• 제23권3호
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• pp.303-315
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• 2017

This paper describes the finite element model for predicting the fundamental performance of embedded steel column base connections under monotonic and cyclic loading. Geometric and material nonlinearities were included in the proposed finite element model. Bauschinger and pinching effects were considered in the simulation of embedded column base connections under cyclic loading. The degradation of steel yield strength and accumulation of plastic damage can be well simulated. The accuracy of the finite element model is examined by comparing the predicted results with independent experimental dataset. It is demonstrated that the finite element model accurately predicts the behaviour and failure models of the embedded steel column base connections. The finite element model is extended to carry out evaluations and parametric studies. The investigated parameters include column embedded length, concrete strength, axial load and base plate thickness. Moreover, analytical models for predicting the initial stiffness and bending moment strength of the embedded column base connection were developed. The comparison between results from analytical models and those from experiments and finite element analysis proved the developed analytical model was accurate and conservative for design purposes.

• Advances in concrete construction
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• 제9권5호
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• pp.437-448
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• 2020

In high rise buildings that utilize precast large panel system for construction, the shear wall provides strength and stiffness during earthquakes. The performance of a wall panel system depends mainly on the type of connection used to transfer the forces from one wall element to another wall element. This paper presents an experimental investigation on different types of construction detailing of the precast wall to wall vertical connections under reverse cyclic loading. One of the commonly used connections in India to connect wall to wall panel is the loop bar connection. Hence for this study, three types of wet connections and one type of dry connection namely: Staggered loop bar connection, Equally spaced loop bar connection, U-Hook connection, and Channel connection respectively were used to connect the precast walls. One third scale model of the wall was used for this study. The main objective of the experimental work is to evaluate the performance of the wall to wall connections in terms of hysteretic behaviour, ultimate load carrying capacity, energy dissipation capacity, stiffness degradation, ductility, viscous damping ratio, and crack pattern. All the connections exhibited similar load carrying capacity. The U-Hook connection exhibited higher ductility and energy dissipation when compared to the other three connections.

• Advances in concrete construction
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• 제3권3호
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• pp.237-250
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• 2015

Beam-column joints are highly vulnerable locations which are to be designed for high ductility in order to take care of unexpected lateral forces such as wind and earthquake. Previous investigations reveal that the addition of steel fibres to concrete improves its ductility significantly. Also, due to presence of slab the strength and ductility of the beam increases considerably and ignoring the effect of slab can lead to underestimation of beam capacity and defiance of strong column weak beam concept. The influence of addition of steel fibres on the strength and behaviour of steel fibre reinforced high performance concrete (SFRHPC) interior beam-column-slab joints was investigated experimentally. The specimens were subjected to reverse cyclic loading. The variable considered was the volume fraction of crimped steel fibres i.e., 0%, 0.5% and 1.0%. The results show that the addition of steel fibres improves the first crack load, strength, ductility, energy absorption capacity and initial stiffness of the beam.

• Computers and Concrete
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• 제21권6호
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• pp.669-679
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• 2018

In this paper the behavior of reinforced concrete (RC) beam-column connections under cyclic loading was analyzed. The specimens, manufactured in a reduced-scale were made of (a) recycled aggregate concrete (RAC) by replacing 30% of natural coarse aggregate (NCA) with recycled coarse aggregate (RCA) and (b) RAC incorporating Polyethylene terephthalate (PET) fiber i.e., PET fiber-reinforced concrete (PFRC) at the joint region. PET fiber (aspect ratio=25) of 0.5% by weight of concrete used in the PFRC mix was obtained by hand cutting of post-consumer PET bottles. A reference specimen was also prepared using 100% of NCA and subjected to similar loading sequence. Comparing the results the structural behavior under cyclic loading of RAC specimens are quite similar to the reference specimens. Damage tolerance, load resisting capacity, stiffness degradation, ductility, and energy dissipation of the RAC specimens enhanced due to addition of PET fibers at the joint region. PFRC specimens also presented a lower damage indices and higher principal tensile stresses as compared to the RAC specimens. The results obtained gave experimental evidence on the feasibility of RAC for structural use. Using PET fibers as a discrete reinforcement is recommended for improving the seismic performance of RAC specimens.

• 대한기계학회논문집A
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• 제24권3호
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• pp.777-785
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• 2000

The low-cycle fatigue behaviors of cast AI-Si alloy and composite with reinforcement of SIC particles were compared with those of extruded unreinforced matrix alloy and composite in order to investigate the influence of cast and extrusion processes on the cyclic deformation and fatigue life. Generally, both cast and extruded composites including the unreinforced alloy exhibited cyclic hardening behaviour, with more pronounced strain-hardening for the composites with a higher volume fraction of the SiC particles. However, cast composite under a low applied cyclic strain showing no observable plastic strain exhibited cyclic softening behavior due to the cast porosities. The elastic modulus and yield strength of the cast composite were found to be quite comparable to those of the extruded composite, however, the extrusion process considerably improved the ductility and fracture strength of the composite by effectively eliminating the cast porosities. Low-cycle fatigue lives of the cast alloy and composite were shorter than those of the extruded counterparts. Large difference in life between cast and extruded composites was attributed to the higher influence of the cast porosities on the fatigue life of the composite than that of the unreinforced alloy material. A fatigue damage parameter using strain energy density effectively represented the inferior life in the low-cycle regime and superior life in the high-cycle regime for the composite, compared to the unreinforced alloy.

• 대한의용생체공학회:의공학회지
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• 제19권5호
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• pp.495-502
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• 1998

Y.C. Fung[1]에 의한 연조직의 점탄성에 관한 수학적 모델이론 (Fung's Quasi-linear vlscoelastic theory)을 이용하여 인간의 인두조직의 점탄성(vlscoelatlcity)특성을 측정하기 위하여 반복성하중(cyclic load) ,응력완화 (tensile stress relaxation), incremental load, 그리고 일축성인장 (uniaxial tensile) 시험 등을 실시하였다. 실험적으로 측정한 인두조직의 점탄성특성이 이미 조사된 다른 조직의 점탄성특성과 정량적으로 비교되었다. 인두조직의 점탄성특성의 정량화를 위하여 Y.C.Fung의 수학적 모델이 적용되었는데 응력완화(tensile stress relaxation) 시험 측정결과로부터 도출된 표준화된 응력완화(reduced stress relaxation)함수 G(t)와 일축성인장(uniaxial tensile)시험에서 도출된 탄성반응(elastic response)함수 5(t)를 이용하여 시간에 따른 응력의 궤적을 산출하여 이를 반복성 하중(cyclic load)실험에서 측정된 결과와 비교, 분석하였다. 이러한 인두조직의 점탄성특성에 관한 연구결과는 향후 유한요소를 이용한 인두의 생체역학적 모델의 기본 데이터로 이용될 수 있다.

• Structural Engineering and Mechanics
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• 제16권4호
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• pp.493-517
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• 2003

Attempts at improving beam-column joint performance has resulted in non-conventional ways of reinforcement such as the use of the crossed inclined bars in the joint area. Despite the wide accumulation of test data, the influence of the crossed inclined bars on the shear strength of the cyclically loaded exterior beam-column joints has not yet been quantified and incorporated into code recommendations. In this study, the investigation of joints has been pursued on two different fronts. In the first approach, the parameters that influence the behaviour of the cyclically loaded beam-column joints are investigated. Several parametric studies are carried out to explore the shear resisting mechanisms of cyclically loaded beam-column joints using an experimental database consisting of a large number of joint tests. In the second approach, the mechanical behaviour of joints is investigated and the equations for the principal tensile strain and the average shear stress are derived from joint mechanics. It is apparent that the predictions of these two approaches agree well with each other. A design equation that predicts the shear strength of the cyclically loaded exterior beam-column joints is proposed. The design equation proposed has three major differences from the previously suggested design equations. First, the influence of the bond conditions on the joint shear strength is considered. Second, the equation takes the influence of the shear transfer mechanisms of the crossed inclined bars into account and, third, the equation is applicable on joints with high concrete cylinder strength. The proposed equation is compared with the predictions of the other design equations. It is apparent that the proposed design equation predicts the joint shear strength accurately and is an improvement on the existing code recommendations.