• Title/Summary/Keyword: cyclic behaviors

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Structural performance by strengthening types of wood frames using H shaped steel joints (H형강 접합부를 갖는 목조 골조의 보강형식에 따른 구조성능)

  • Kim, Soon-Chul;Moon, Youn-Joon;Yang, Il-Seung;Park, Geun-Hong
    • KIEAE Journal
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    • v.8 no.3
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    • pp.77-83
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    • 2008
  • The effective mixture of structural laminated timber and other materials is expected to extend the potentials of building structures because of the potentials to realize high performance in structural safety. The classical joint types using drift pin and bolts are occurred local failures due to the small bearing area. In result, new joints using H shaped steel were suggested in this research. The objective of this study is to evaluate elasto-plastic behaviors by strengthening types of wood frames with new joints connecting structural laminated timber with H shaped steel. A total of five specimens of about one-second scale were tested. Specimens had columns with 1,050 height and $84mm{\times}100mm$ section, and a beams with 1,950mm length and $130mm{\times}100mm$ section. Also, the specimens were stiffened by brace, hwang-toh brick, and autoclaved lightweight concrete. The results of the test showed that the specimen stiffened with autoclaved lightweight concrete was characterized by fairly good strength and stiffness than those of the other specimens. Initial stiffness of H-2.0D-NS specimen with 2 times inserting length of beam height showed 1.33 times than that of H-1.5D-NS specimen. However, the strength of H-2.0D-NS specimen has not improved too much than H-1.5D-NS specimen.

Preparation of LiCoO$_2$from Used Lithium Ion Battery by Hydrometallurgical Processes

  • Lee, Churl-Kyoung;Rhee, Kang-In;Yang, Dong-Hyo;Yu, Hyo-Shin
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.240-244
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    • 2001
  • Recycling process involving mechanical, thermal, hydrometallurgical, and sol-gel step has been applied to recover cobalt and lithium from spent lithium ion batteries and to synthesize LiCoO$_2$from leach liquor as cathodic active materials. Electrode materials containing lithium and cobalt could be concentrated with 2-step thermal and mechanical treatment. Leaching behaviors of the lithium and cobalt in nitric acid media was investigated in terms of reaction variables. Hydrogen peroxide in 1 M HNO$_3$solution turned out to be an effective reducing agent by enhancing the leaching efficiency. O f many possible processes to produce LiCoO$_2$, the amorphous citrate precursor process (ACP) has been applied to synthesize powders with a large specific surface area and an exact stoichiometry. After leaching used LiCoO$_2$with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.1 by adding a fresh LiNO$_3$solution. Then, 1 M citric acid solution at a 100% stoichiometry was also added to prepare a gelatinous precursor. When the precursor was calcined at 95$0^{\circ}C$ for 24 hr, purely crystalline LiCoO$_2$was successfully obtained. The particle size and specific surface area of the resulting crystalline powders were 20 пm and 30 $\textrm{cm}^2$/g, respectively The LiCoO$_2$powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

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Numerical analysis of the seismic performance of RHC-PVCT short columns

  • Xue, Jianyang;Zhao, Xiangbi;Ke, Xiaojun;Zhang, Fengliang;Ma, Linlin
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.257-267
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    • 2019
  • This paper presents the results of cyclic loading tests on new high-strength concrete (HC) short columns. The seismic performance and deformation capacity of three reinforced high-strength concrete filled Polyvinyl Chloride tube (RHC-PVCT) short columns and one reinforced high-strength concrete (RHC), under pseudo-static tests (PSTs) with vertical axial force was evaluated. The main design parameters of the columns in the tests were the axial compression ratio, confinement type, concrete strength, height-diameter ratio of PVCT. The failure modes, hysteretic curves, skeleton curves of short columns were presented and analyzed. Placing PVCT in the RHC column could be remarkably improved the ultimate strength and energy dissipation of columns. However, no fiber element models have been formulated for computing the seismic responses of RHC-PVCT columns with PVT tubes filled with high-strength concrete. Nonlinear finite element method (FEM) was conducted to predict seismic behaviors. Finite element models were verified through a comparison of FEM results with experimental results. A parametric study was then performed using validated FEM models to investigate the effect of several parameters on the mechanical properties of RHC-PVCT short columns. The parameters study indicated that the concrete strength and the ratio of diameter to height affected the seismic performance of RHC-PVCT short column significantly.

Electrochemical Characteristics of Lithium Ion Battery Anode Materials of Graphite/SiO2 (리튬이차전지 음극재로서 Graphite/SiO2 합성물의 전기화학적 특성)

  • Ko, Hyoung Shin;Choi, Jeong Eun;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.592-597
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    • 2014
  • The graphite/$SiO_2$ composites as anode materials for lithium-ion batteries were prepared by sol-gel method to improve the graphite's electrochemical characteristics. The prepared graphite/$SiO_2$ composites were analysed by XRD, FE-SEM and EDX. The graphite surface modified by silicon dioxide showed several advantages to stabilize SEI layer. The electrochemical characteristics were investigated for lithium ion battery using graphite/$SiO_2$ as the working electrode and Li metal as the counter electrode. Electrochemical behaviors using organic electrolytes ($LiPF_6$, EC/DMC) were characterized by charge/discharge, cycle, cyclic voltammetry and impedance tests. The lithium ion battery using graphite/$SiO_2$ electrodes had better capacity than that of using graphite electrodes and was able to deliver a discharge capacity with 475 mAh/g at a rate of 0.1 C. Also, the capacity retention ratio of the modified graphite reaches 99% at a rate of 0.8 C.

Nonlinear Analysis Model Considering Failure Mode of Unreinforced Masonry Wall (파괴모드를 고려한 비보강 조적벽체의 비선형 해석모델)

  • Baek, Eun-Lim;Kim, Jung-Hyun;Lee, Sang-Ho;Oh, Sang-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.4
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    • pp.33-40
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    • 2014
  • The final purpose of this study is to evaluate the seismic performance of unreinforced masonry (URM) building more accurately. For that, shear strength and hysteresis model considering failure mode of the URM wall were discussed. The shear strength of URM wall without openings could be calculated by determining on the minimum value between the rocking strength suggested by domestic research and the sliding strength suggested by FEMA. The wall having openings could be predicted properly by the FEMA method. And the nonlinear hysteresis models for flexural and shear behaviors considering failure mode were proposed. As the result of the nonlinear cyclic analysis that carried out using suggested models, these analysis models were proper to represent the seismic behavior of URM walls.

Electrochemical Characteristics of Hybrid Capacitor using Core-shell Structure of MCMB/Li4Ti5O12 Composite (Core-shell 구조의 MCMB/Li4Ti5O12 합성물을 사용한 하이브리드 커패시터의 전기화학적 특성)

  • Ko, Hyoung Shin;Choi, Jeong Eun;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.52-57
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    • 2014
  • The MCMB-$Li_4Ti_5O_{12}$ with core-shell structure was prepared by sol-gel process to improve low cycle capability of MCMB in this study. The electrochemical characteristics were investigated for hybrid capacitor using MCMB-$Li_4Ti_5O_{12}$ as the negative electrode and $LiMn_2O_4$, Active carbon fiber as the positive electrode. The electrochemical behaviors of hybrid capacitor using organic electrolytes ($LiPF_6$, EC/DMC/EMC) were characterized by charge/discharge, cyclic voltammetry, cycle and impedance tests. The hybrid capacitor using MCMB-$Li_4Ti_5O_{12}/LiMn_2O_4$ electrodes had better capacitance than MCMB hybrid systems and was able to deliver a specific energy with 67 Wh/kg at a specific power of 781 W/kg.

Nonlinear Analysis of Precast Concrete Wall Structures (프리캐스트 콘크리트 판구조의 비선형 해석)

  • 서수연;이원호;이리형
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.2
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    • pp.189-196
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    • 2000
  • The objective of this paper is to propose an analysis technique to predict the behavior of PC wall structures subjected to cyclic load. While PC wall panel is idealized by finite elements, the joints at which PC walls are connected each other are idealized by nonlinear spring elements. Axial and shear spring elements are developed for simulating shear, compression and tension behaviors of joints. The strength and stiffness of each spring elements we presented from the previous research results and incorporated into the computer program of DRAIN-2DX. The proposed analysis technique is evaluated by analyzing specimens previously tested and comparing with those. On the strength, stiffness, energy dissipation and lateral drift, analytical results show good agreements with test results. This means the proposed technique is effective to predict the response of the PC wall structures.

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A Study on Hot Straining Embrittlement of Coarse Grained HAZ in Steel Weldments (강 용접열영향부 조립역의 열변형취화에 관한 연구)

  • 정세희;김태영;임재규
    • Journal of Welding and Joining
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    • v.3 no.1
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    • pp.22-31
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    • 1985
  • Hot straining embrittlement is one of the most important factors which cause the brittle fracture initiation even in the service temperature in the case of mild steel and high tensile steel. Therefore it is necessary to analyze thoroughly the hot straining embrittlement occurred in weld HAZ of the structural steels. The behaviors of plastic deformation and fracture toughness at the notch tip of the hot strained weld HAZ in structural steels (SB 41 KS, SA 588-Grade A ASTM) have been studied by the recrystallization technique and crack opening displacement (COD) test method. The obtained results are summarized as follows; 1. The plastic zone is formed at the notch tip of weld HAZ owing to nomotonic and cyclic hot stran, and the maximum plastic strain increases with the accumulated hot straining amounts. 2. The distribution of the effective strain at the plastic deformed zone in HAZ can be determined as follows; (.epsilon. over bar $_{p}$ )$_{\chi}$=.epsilon. over bar $_{cr}$ ( $R_{/chi}$/.chi.)$^{m}$ where, .epsilon. over bar $_{cr}$ : (SB 41; .epsilon. over bar $_{cr}$ = 0.2, SA 588; .epsilon. over bar $_{cr}$ = 0.1) 3. The embrittlement of weld HAZ in SB 41 and SA 588 is influenced by hot strain, and the degree of embrittlement becomes deeper with hot straining amounts. 4. The embrittlement of weld HAZ of SB 41 is not influenced by the hot straining amounts until .epsilon. over bar $_{max}$ = 0.36, $R_{\chi}$ = 0.065mm, however the embrittlement of structure in SA 588 is considerably influenced even by a small quantity of the hot straining amounts.s.

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ALD-assisted Hybrid Processes for improved Corrosion Resistance of Hard coatings

  • Wan, Zhixin;Kwon, Se-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.105-105
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    • 2016
  • Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.

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Shear Strength and Failure Mode of Architectural Masonry Walls (내진보강된 치장조적벽의 파괴특성과 전단강도)

  • Jin, Hee-Yong;Han, Sang-Whan;Park, Young-Mi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.89-92
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    • 2008
  • This study investigates the shear behavior of architectural masonry veneer wall reinforced with specific reinforcement details proposed by this study. For this purpose, experimental tests were conducted using one un-reinforced masonry(URM) wall specimen and three reinforced masonry(RM) wall specimens under quasi static cyclic loads. Un-reinforced(plain) masonry wall is expressed that behavior and failure mode are different for aspect ratio(L/H) and axial compressive force. The test variables are wall aspect ratio and presence of reinforcement. These specimens are masonry structure for architectural clading that is not to exist the axial compressive force. thus the axial compressive force is excepted from test variable. Test result, Behavior of specimens are dominated over rocking mode, but final failure modes are combined with different behaviors. And FEMA273 has proposed the equation of shear strength of masonry pier subjected to in-plane loading. Shear strength equations are classified four types of failure mode that is Rocking, and Toe-Crushing, Bed-Joint-Sliding and Diagonal-Tension. FEMA273 equations predict the behavior modes well, but shear strength is shown in different result.

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