• 제목/요약/키워드: curing rate

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경량기포혼합 준설토의 강도특성 (Strength Characteristics of Light-Weight Cement mind Marine Clay with Foam)

  • 박건태;김주철;윤길림;이종규
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.483-490
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    • 2002
  • A massive amount of marine clay produced as dredging of coast and sea bed is often dumped in open sea and filled in pond. The treatment of marine clay demand a large area and make fatal environmental problems for echo system. This research work intend to manufacture a light-weight landfill materials which are produced by mixing the dredged marine clay with various amount cement and foam. An extensive Uniaxial and Triaxial compression test are carried out to investigate the strength characteristics of the light-weight cement mixed marine clay with foam under various test conditions. The results indicated that the required unit weight has been achieved with negligible change after 28days curing time in water. It is also recognized that the compressive strength of light-weight landfill materials linearly decrease with increasing initial water content, and the rate of strength decrease with increasing initial water content in water curing was smaller than that of air curing Futhermore, the rate of strength decreased with increasing initial water content, however, the rate become smaller as cement content increased.

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지방족 폴리우레탄 접착제의 합성과 접착 특성 (Synthesis and Adhesion Properties of Aliphatic Polyurethane Adhesive)

  • 박창무;최성옥;정노희
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.461-469
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    • 2010
  • Polyurethane adhesive is used in various fields as flexible packaging materials including a food packaging field. Therefore, the purpose of this study is synthesis of polyurethane adhesive which uses aliphatic isocyanate, and compares with aromatic isocyanate. The isocyanates for this test are toluene-2,4-diisocyanate(TDI), hexamethylene diisocyanate(HDI), 4,4-dicyclohexyl ethane diisocyanate($H_{12}MDI$), and isophorone diisocyanate(IPDI). And, the effect of any other diisocyanate are evaluated by several methods as for curing rate test, accelerate weathering test, and peel strength test. The polyurethane adhesive using curing catalyst and HDI has adhesion strength of about 560 g/15 mm between aluminium foil and nylon, about 1,520 g/15 mm between nylon and CPP. Those parameters are similar to polyurethane adhesive with TDI. Also, in case of curing rate, those are similar to TDI type polyurethane adhesive. Moreover, data of ${\Delta}E$ as color variation by QUV tester is equal to 4.12, as 48% against those of TDI type.

경화제의 입체 이성질체 구조가 에폭시 수지의 경화 거동과 열 및 기계적 특성에 미치는 영향 (Effect of Stereoisomeric Structures of Curing Agents on Curing Behaviors, Thermal and Mechanical Properties of Epoxy Resins)

  • 이민규;권웅;정의경
    • 한국염색가공학회지
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    • 제30권3호
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    • pp.180-189
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    • 2018
  • To study the effect of stereoisomeric structures of curing agents on curing behaviors, thermal and mechanical properties of epoxy resins, DGEBA(diglycidyl ether of bisphenol A) epoxy resin and 3,3'- and 4,4'-DDS(diaminodiphenyl sulfone) curing agents were selected. The curing initiation temperature and activation energy of DGEBA/3,3'-DDS was lower than DGEBA/4,4'-DDS. DGEBA/3,3'-DDS has a faster curing rate and higher degree of cure than DGEBA/4,4'-DDS, suggesting that 3,3'-DDS has higher reactivity than 4,4'-DDS. Tensile strength and fracture toughness of DGEBA/3,3'-DDS was lower than those of DGEBA/4,4'-DDS, indicating that mechanical properties of the epoxy resin can be different only by the stereoisomeric difference in chemical structure of the curing agent.

Bottom Ash와 혼합재료의 혼합비 및 양생방법에 따른 강도특성 분석 (Analysis of Strength Characteristic for Bottom Ash Mixtures as Mixing Ratio and Curing Methods)

  • 최우석;손영환;박재성;노수각;봉태호
    • 한국농공학회논문집
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    • 제55권3호
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    • pp.129-140
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    • 2013
  • Bottom Ash is industrial by-product from a thermoelectric power plant. An immense quantities of bottom ash have increased each year, but most of them is reclaimed in ash landfill. In this study, in order to raise recycling rate of Bottom Ash, it is suggested to cure Bottom Ash (BA) mixtures mixed with cement, lime, Fly Ash (FA), and oyster shell (OS). Mixtures of 5~20 % mixing ratio had been cured for 1, 3, 7, 14, and 28 days using sealed curing and air-dry curing method. Unconfined compressive strength test was conducted to determine strength and deformation modulus ($E_{50}$) change for mixtures as mixing ratio and curing day, water contents of mixtures were measured after test. As a result, strength and $E_{50}$ were increased as mixing ratio and curing days, but values and tendencies of them appeared in different as kind of mixture, mixing ratio, curing method, and curing days. The results showed the addition of cement, lime, Fly Ash, and oyster soil in Bottom Ash could improved strength and $E_{50}$ and enlarge its field of being used.

전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법(II) (A new evaluation method of UV curing process by using electrical properties(II))

  • 이문학;김성빈;이태훈;류정이;김태훈;손세모
    • 한국인쇄학회지
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    • 제22권1호
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    • pp.39-52
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    • 2004
  • A novel evaluation method is investigated for measuring the ability of acid amplification of acid amplifier. The method is based on the measurement of conductivity change by the acid generation according to UV radiation. It is found that the decrease of conductivity is caused by photopolymerization of epoxy monomer during UV curing process of ink film and the by the rate of UV curing. In this paper, the novel acid amplifiers were synthesized and measured thermal stability by means of DSC. It was found that mono-type acid amplifiers were more stable than di-type. It is possible to make the dynamical evaluation the curing rate of UV curable ink in curing process by this method.

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석탄회를 사용한 저강도 고유동화재의 경화 특성 분석 (Curing Characteristics of Controlled Low Strength Material Made with Coal Ashes)

  • 김주형;조삼덕;공진영;정혁상;천병식
    • 한국지반환경공학회 논문집
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    • 제11권11호
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    • pp.77-85
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    • 2010
  • 석탄회를 주재료로 하는 저강도 고유동화재의 특성을 분석하기 위해 일축압축강도시험을 수행하였으며, 경화 시간을 분석하였다. 동일한 배합비 상태에서 함수비가 낮을수록 일축압축강도 증가율이 큰 것으로 나타났으며, 초기 3일 동안에는 이와 같은 현상이 뚜렷하게 나타나고 있음을 확인하였다. 또한, 가장 경제적인 시멘트 첨가비로 소형 모형지반을 조성하여 동적콘관입시험을 통해 배합비에 따른 저강도 고유동화재의 특성을 분석한 결과, 목표 일축압축강도인 500kPa(콘관입률 20mm/blow) 도달시간은 약 10일 정도 소요되는 것으로 나타났으며, 10일이 경과한 후에는 배합비와 상관없이 경화속도가 급격하게 감소하는 것으로 나타났다.

촉진양생이 콘크리트의 28일 압축강도에 미치는 영향에 관한 연구 (A Study on the Effect of Accelerated Curing on 28-Days Compressive Strength of Concrete)

  • 최세규;유승룡;김생빈
    • 콘크리트학회지
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    • 제8권4호
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    • pp.141-148
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    • 1996
  • 기존의 촉진양생 연구는 1960~1970년대에 주로 실행된 것으로, 전체 증기양생기간이 18시간 또는 24시간인 경우에 대하여 연구되었고, 상기 연구 결과는 수동식 항온항습조를 사용하였으므로 온도상승구배의 효과에 대하여 명확한 규명을 할 수 없다고 판단되었다. 따라서 국내 PC공장 여건에서 그 직접적인 적용이 불가능한 실정이다. 본 연구는 효과적인 콘크리트 촉진양생에 대한 기본 자료를 정립할 목적으로, 국내 PC 공장에서 사용하는 배합표를 근거로 시험공시체를 제작한 후, 각 해당 양생주기 조건을 변화시켜 가면서 실험하였다. 탈형시 및 수중양생 재령28일의 측정하고 비교 검토한 결과, 재령 28일 후 설계강도값을 초과하는 가장 효과적인 촉진양생조건, 본 실험조건 하에서 전양생시간은 커다란 영향을 미치지 않았으며, 온도상승구배는 $30^{circ}C/hr$ 이하로, 최고양생온도는 $82^{\circ}C$이하로 양생해야 하며, 또한 촉진양생 후 2차 양생으로 강도증진을 도모함이 촉진양생의 효과를 증대시킬 수 있다고 판단되었다.

Effect of Wet Curing Duration on Long-Term Performance of Concrete in Tidal Zone of Marine Environment

  • Khanzadeh-Moradllo, Mehdi;Meshkini, Mohammad H.;Eslamdoost, Ehsan;Sadati, Seyedhamed;Shekarchi, Mohammad
    • International Journal of Concrete Structures and Materials
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    • 제9권4호
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    • pp.487-498
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    • 2015
  • A proper initial curing is a very simple and inexpensive alternative to improve concrete cover quality and accordingly extend the service life of reinforced concrete structures exposed to aggressive species. A current study investigates the effect of wet curing duration on chloride penetration in plain and blended cement concretes which subjected to tidal exposure condition in south of Iran for 5 years. The results show that wet curing extension preserves concrete against high rate of chloride penetration at early ages and decreases the difference between initial and long-term diffusion coefficients due to improvement of concrete cover quality. But, as the length of exposure period to marine environment increased the effects of initial wet curing became less pronounced. Furthermore, a relationship is developed between wet curing time and diffusion coefficient at early ages and the effect of curing length on time-to-corrosion initiation of concrete is addressed.

Evaluation of early age mechanical properties of concrete in real structure

  • Wang, Jiachun;Yan, Peiyu
    • Computers and Concrete
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    • 제12권1호
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    • pp.53-64
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    • 2013
  • The curing temperature is known to influence the rate of mechanical properties development of early age concrete. In realistic sites the temperature of concrete is not isothermal $20^{\circ}C$, so the paper measured adiabatic temperature increases of four different concretes to understand heat emission during hydration at early age. The temperature-matching curing schedule in accordance with adiabatic temperature increase is adopted to simulate the situation in real massive concrete. The specimens under temperature-matching curing are subjected to realistic temperature for first few days as well as adiabatic condition. The mechanical properties including compressive strength, splitting strength and modulus of elasticity of concretes cured under both temperature-matching curing and isothermal $20^{\circ}C$ curing are investigated. The results denote that comparing temperature-matching curing with isothermal $20^{\circ}C$ curing, the early age concretes mechanical properties are obviously improved, but the later mechanical properties of concretes with pure Portland and containing silica fume are decreased a little and still increased for concretes containing fly ash and slag. On this basement using an equivalent age approach evaluates mechanical properties of early age concrete in real structures, the model parameters are defined by the compressive strength test, and can predict the compressive strength, splitting strength and elasticity modulus through measuring or calculating by finite element method the concreted temperature at early age, and the method is valid, which is applied in a concrete wall for evaluation of crack risking.

Relationship between Compressive Strength of Geo-polymers and Pre-curing Conditions

  • Kim, Hyunjung;Kim, Yooteak
    • Applied Microscopy
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    • 제43권4호
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    • pp.155-163
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    • 2013
  • Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.