• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.1
• /
• pp.59-66
• /
• 2020

In this study, self - healing solid capsules of crystal growth type which can be mixed directly with repair mortar were prepared, and the quality and crack healing performance of repair mortar with self - healing solid capsules were evaluated. The table flow and the air flow rate of the repair mortar material mixed with self-healing solid capsules were found to have no significant influence on table flow and air volume regardless of mixing ratio. Compressive strength tended to decrease with increasing capsule mixing ratio. As a result of evaluation of crack healing properties according to constant water head permeability test, initial water permeability decreased, and reaction products were generated over time and cracks were healed.

• Korean Journal of Crystallography
• /
• v.9 no.1
• /
• pp.30-38
• /
• 1998

A new frequency weighing sensor was applied to grow Bi12GeO20 crystals in the auto-di-ameter control system of Czochralski method. The rotation rate was varied in the range of 23 to 21 rpm to preserve flat interface in a given heat configuration. To prevent the constitutional super-cooling from the evaporation loss, 105% stoichiometric amount of Bi2O3 was employed, equivalent to 6.18 molar ratio of Bi2O3 to GeO2. Transparent and light brown Bi12GeO20 single crystal in uniform diameter was grown. The dislocation density was determined to be 103/cm2 corresponding to the optical quality in commercial applications. The grown crystal measured diameter 25 mm and length 70 mm and the preferred growth direction was confirmed to be <110>.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.1
• /
• pp.16-23
• /
• 2021

Lithium carbonate recovered from the waste solution generated during the lithium secondary battery manufacturing process contains heavy metals such as cobalt, nickel, and manganese. In this study, the recrystallization of lithium carbonate was performed to remove heavy metals contained in the powder and to increase the purity of lithium carbonate. First, the leaching efficiency of lithium carbonate according to pH in the aqueous hydrochloric acid solution was examined, and the effect on the recrystallization of lithium carbonate according to the equivalent and concentration of sodium carbonate was confirmed. As the equivalent and concentration of sodium carbonate increased, the recovery rate of lithium carbonate improved. And the SEM image showed that the crystal shape was changed depending on the reaction conditions with sodium carbonate. Finally, the high purity lithium carbonate of 99.9% or more was recovered by washing with water.

• Journal of the Korean Ceramic Society
• /
• v.55 no.2
• /
• pp.108-115
• /
• 2018

The increasing demands for three-dimensional (3D) electronic and optoelectronic devices have triggered interest in epitaxial growth of 3D semiconductor materials. However, most of the epitaxially-grown nano- and micro-structures available so far are limited to certain forms of crystal arrays, and the level of control is still very low. In this review, we describe our latest progress in 3D epitaxy of oxide and nitride semiconductor crystals. This paper covers issues ranging from (i) low-temperature solution-phase synthesis of a well-regulated array of ZnO single crystals to (ii) systematic control of the axial and lateral growth rate correlated to the diameter and interspacing of nanocrystals, as well as the concentration of additional ion additives. In addition, the critical aspects in the heteroepitaxial growth of GaN and InGaN multilayers on these ZnO nanocrystal templates are discussed to address its application to a 3D light emitting diode array.

• Korean Journal of Crystallography
• /
• v.2 no.2
• /
• pp.32-40
• /
• 1991

The effects of compositional variation, rotation speel and pulling rate on the growth of optical quality Bi120e02(1 crystals were examined. It was found to flatten the shape of crystal-melt interface for yowing a single crystals less than about 30mm in diameter at the rotation speed of 50rpm. Diameter of crystals with flat interface was increased as the pulling rate. The precipitation of Bi40e3012 phase set limits to pulling rate of BGO crystals. Precipitate-free BGO crystals were grown under pulling rate of 2mm l hr which released the stress resulted from too hi어 Pulling rate, and from 6. IBi203·GeO2 batch composition obtained by addition of 0.1 mole Bi203 into Bi-deficient melts to fill up the deficiency resulted from gradual volatilization of Bi2O). The pale-yellow colored crystals had good quality in that dislocation density was less than 103pits/cm, and it also exhibited transmittance of 70% and optical activity of 23°/mm. and SAW velosity was measured 1700m/sec on 111 cut 110 propagating BGO crystals. The SAW filter with electrode thickness of 9.8um was fabricated by using the electron beam and dry etching technique, it makes Bi12GeO20 devices intersting for color TV IF with half device size.

• Journal of the Korean Ceramic Society
• /
• v.45 no.5
• /
• pp.280-284
• /
• 2008

In order to investigate residence time effect on the growth of ZrC film, the ZrC films grew with various system total pressure (P) and total flow rate (Q) by low pressure chemical vapor deposition because residence time is function of system total pressure and total flow rate. Thermodynamic calculations predict that the decomposition of source gases ($ZrCl_4$ and $CH_4$) would be low as increasing the residence time. Thermodynamic calculations results were proved by investigating deposition rate with various residence time. Deposition rate decreased with residence time of source gas increased. Besides, depletion effect accelerated diminution of deposition rate at high residence time. On the other hands, the deposition rated was increased as decreasing the residence time because fast moving of intermediate gas species decrease the depletion effect. The crystal structure was not changed with residence time. However, the largest size of faceted grain showed up to specific residence time and the size of grain was decreased whether residence time increase or not.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.351-351
• /
• 2011

Graphene has drawn great interests because of its distinctive band structure and physical properties[1]. A few of the practical applications envisioned for graphene include semiconductor applications, optoelectronics (sola cell, touch screens, liquid crystal displays), and graphene based batteries/super-capacitors [2-3]. Recent work has shown that excellent electronic properties are exhibited by large-scale ultrathin graphite films, grown by chemical vapor deposition on a polycrystalline metal and transferred to a device-compatible surface[4]. In this paper, we focussed our scope for the understanding the graphene growth at different conditions, which enables to control the growth towards the application aimed. The graphene was grown using chemical vapor deposition (CVD) with methane and hydrogen gas in vacuum furnace system. The grown graphene was characterized using a scanning electron microscope(SEM) and Raman spectroscopy. We changed the growth temperature from 900 to $1050^{\circ}C$ with various gas flow rate and composition rate. The growth condition for larger domain will be discussed.

• Journal of the Korean GEO-environmental Society
• /
• v.7 no.6
• /
• pp.5-12
• /
• 2006

This study was conducted to investigate the effect of operational parameters such as dosage of magnesium and phosphate, pH, reaction time and existence crystal core for the removal of nitrogen and phosphorus in anaerobic fermentation supernatant by struvite crystallization. Optimal mole ratio of $Mg^{2+}:NH_4{^+}:PO_4{^{3-}}$ was 1.2:1.0:1.2. Under the optimal molar ratio, removal ratio and reaction rate constant of $NH_4{^+}-N$ and $PO_4{^{3-}}-P$ were 79.2, 96.8%, 0.157 and $0.344min^{-1}$, respectively. Optimal pH and reaction time were 11 and 10 minutes, respectively, in the optimal molar ratio. Residual concentration of $NH_4{^+}-N$ and $PO_4{^{3-}}-P$ showed lowest value with 1 g/L of crystal core addition. SEM analysis of struvite crystallization with crystal core showed higher crystal core growth than that of without crystal core. Struvite precipitate proved to be orthorhomic crystal structure by XRD analysis.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.15 no.1
• /
• pp.39-44
• /
• 2005

A sheet type of green body was made with the mixture of 60 wt% red clay, 20 wt% fly ash, and 20 wt% stone sludge. Indentations were made on the surfaces of sheets to investigate fracture rate of 1 to 5 mm artificial light-weight aggregates by various drying, breaking, and forming methods. Drying methods of green bodies were natural, electric oven, microwave, and fast drying by torch. Breaking methods of green bodies were ballmill Ⅰ, ballmill Ⅱ, free dropping in the box, and mechanical breaking with roller mill. The depth and width of indent on the surface of the sheet were varied and the thickness of green bodies was also changed to investigate effects of indentation on fracture rates. The highest fracture rate of 42 % among the various drying methods was obtained by microwave drying for 210 sec and the highest fracture rate of 65 % among the various breaking method was obtained by ballmill Ⅱ method. In forming method, an yield of larger aggregates than Ф = 5 mm decreased and that of smaller aggregates than Ф = 5 mm in creased with increasing depth of indentation (only in 3 mm thick green body)and with increasing thickness of green body. The size of aggregates was most homogeneous (by judging from the measurement of aspect ratio of 1 to 5 mm aggregates.) when 3 mm thick green body was rapidly dried by torch and was broken by ballmill Ⅱ method.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.21 no.2
• /
• pp.82-86
• /
• 2011

Lightweight aggregate which is composed of sintered polycrystalline materials usually has a certain portion of pores inside of it. Because of such a structural characteristics, it tends to that movement of water in aggregate shows an abnormal behavior against the change of outside environment. In general, water movement behavior is controlled by porosity, distribution of pore size; however, dense surface layer will also affect water movement behavior in case of artificially sintered aggregates. Factors affecting water movement behavior in the aggregate are pore distribution, pore shape, pre-wetting method, etc. In this study, absorption characteristics of aggregate under the pressure and absorption rate according to water dipping time are analyzed for the basis of pressure pumping of lightweight concrete. Two kinds of aggregates were used for the test: one is made by 'L' company in Germany and the other is of our own made at the pilot plant in Kyonggi University. Absorption rate of aggregate is measured according to water dipping time, vacuum pressure, and quenching condition. Absorption rate of aggregate with $300^{\circ}C$ quenching is higher than that of aggregate with 24 hr water dipping. Generally the more vacuum the higher water absorption rate. Water absorption rate of 'L' aggregate under -300 mmHg is 54 % higher than that of aggregate with 24 hr water dipping; however, only 2 % increase in water absorption was measured for the K622 and K73 which were of our own.