• Journal of the Korean Magnetics Society
• /
• v.5 no.2
• /
• pp.112-114
• /
• 1995

We show physically and mathematically that magnetoelastic coupling coefficients can be predicted to have a form of $B^{eff}=B^{b}+B^{s}/t$, sirniiarily in effective magnetic anisotropy energy in ultrathin films. The inverse thickness dependnce of magnetoelastic coupling coefficients implies lots of technical potentials.

• Tunnel and Underground Space
• /
• v.8 no.1
• /
• pp.26-36
• /
• 1998

To assess the groundwater flow near high-level radioactive waste repositories, it is important to understand the effect of coupling among thermal, hydraulic, and mechanical effects. In this paper, detailed mathematical approach to model the groundwater flow near the waste form surrounded by buffer, influenced by decay heat of radioactive waste along with stress change is developed. Two cases(1) before the full expansion of buffer and (2) after the full expansion of buffer are modelled. Based on the mathematical models in this paper, detailed numerical study shall be pursued later.

• Journal of the Korean Chemical Society
• /
• v.36 no.2
• /
• pp.324-328
• /
• 1992

The $^1H$ NMR chemical shifts and coupling constants for ${\alpha}$-, permethyl-${\alpha}$-, ${\beta}$-and permethyl-${\beta}$-cyclodextrins in neutral aqueous media were assigned based on the 470MHz spectra. In order to obtain accurate chemical shifts and coupling constants the experimental spectra were analyzed with the Raccoon spin simulation program. The rotamer distribution around the$C_{5-}C_6$ bond of the cyclodextrins evaluated from the coupling constants of $J_{56a}$ and $J_{56b}$. In our calculation of the ${\alpha}$-, and ${\beta}$-cycliodextrin showed that gg conformers were most favorable form and tg conformers were least favorable form. It is very interesting to note the changes in $J_{56a}$, $J_{56b}$ coupling constants of permethylated ${\alpha}$- and ${\beta}$-cyclodextrins from unmodified one. The gg conformers were more increased than unmodified one and instead of tg conformers gt conformers were least favorable one upon methylation.

• Bulletin of the Korean Chemical Society
• /
• v.21 no.10
• /
• pp.969-972
• /
• 2000

[Fe II Fe III $BPLNP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)ami-no)methyl]-4-nitrophenol (HBPLNP) . Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electrochemical methods. Complex 1 exhibits two strong bands at 498 nm $(\varepsilon=$ 2.6 ${\times}10^3M-^1cm-^1)$ and 1363 nm $(\varepsilon=$ 5.7 ${\times}10^2M-^1cm-^1)$ in $CH_3CN.$ These are assigned to phenolate-to-FeIII and intervalence charge-transfer transitions, respectively. NMR spectrum of complex 1 exhibits sharp isotropically shifted resonances, which number is half of those expected for a valence-trapped species, indicating that electron transfer between FeⅡ and FeⅢ centers is faster than NMR time scale at room temperature. Complex 1 undergoes quasireversible one-electron redox processes. The $FeIII_2/FeIIFeIII$ and $FeIIFeIII/FeII_2$ redox couples are at 0.807 and 0.167 V ver-sus SCE, respectively. It has Kcomp = 5.9 ${\times}$10 1s(acetato) ligand combination sta-bilizes a mixed-valence FeIIFeIII complex in the air. Interestingly, complex 1 exhibits intense EPR signals at g = 8.56, 5.45, 4.30 corresponding to mononuclear high-spin FeⅢ species, which suggest a very weak magnetic coupling between the iron centers. Magnetic susceptibility study shows that there is a very weak antiferromag-netic coupling (J = $-0.78cm-^1$, H = $-2JS_1${\times}$S_2)$ between FeII and FeIII centers. Thus, we can suggest that complex 1 has a very weak antiferromagnetic coupling between the iron centers due to the electronic effect of the nitro group in the bridging phenolate ligand.

• Geomechanics and Engineering
• /
• v.13 no.2
• /
• pp.285-300
• /
• 2017

Shallow coal resources are increasingly depleted, the mining has entered the deep stage. Due to "High stress, high gas, strong adsorption and low permeability" of coal seam, the gas drainage has become more difficult and the probability of coal and gas outburst accident increases. Based on the flow solid coupling theory of coal seam gas, the coupling model about stress and gas seepage of coal seam was set up by solid module and Darcy module in Comsol Multiphysics. The gas extraction effects were researched after applying hydraulic technology to increase permeability. The results showed that the effective influence radius increases with the expanded borehole radius and drainage time, decreases with initial gas pressure. The relationship between the effective influence radius and various factors presents in the form: $y=a+{\frac{b}{\left(1+{(\frac{x}{x_0})^p}\right)}}$. The effective influence radius with multiple boreholes is obviously larger than that of the single hole. According to the actual coal seam and gas geological conditions, appropriate layout way was selected to achieve the best effect. The field application results are consistent with the simulation results. It is found that the horizontal stress plays a very important role in coal seam drainage effect. The stress distribution change around the drilling hole will lead to the changes in porosity of coal seam, further resulting in permeability evolution and finally gas pressure distribution varies.

• Journal of Magnetics
• /
• v.18 no.2
• /
• pp.130-134
• /
• 2013

Most electrical machines like motor, generator and transformer are symmetric in terms of magnetic field distribution and mechanical structure. In order to analyze these problems effectively, many coupling techniques have been introduced. This paper deals with a coupling scheme for open boundary problem of symmetric and periodic structure. It couples an analytical solution of Fourier series expansion with the standard finite element method. The analytical solution is derived for the magnetic field in the outside of the boundary, and the finite element method is for the magnetic field in the inside with source current and magnetic materials. The main advantage of the proposed method is that it retains sparsity and symmetry of system matrix like the standard FEM and it can also be easily applied to symmetric and periodic problems. Also, unknowns of finite elements at the boundary are coupled with Fourier series coefficients. The boundary conditions are used to derive a coupled system equation expressed in matrix form. The proposed algorithm is validated using a test model of a bush bar for the power supply. And the each result is compared with analytical solution respectively.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.997-1008
• /
• 2012

This work provides an alternative derivation of third order response functions in four wave mixing spectroscopy of multichromophoric macromolecular systems considering only single exciton states. For the case of harmonic oscillator bath linearly and diagonally coupled to exciton states, closed form expressions showing all the explicit time dependences are derived. These expressions can provide more solid physical basis for understanding 2-dimensional electronic spectroscopy signals. For more general cases of system-bath coupling, the quantum master equation (QME) approach is employed for the derivation of multistep time evolution equations for Green function-like operators. Solution of these equations is feasible at the level of 2nd order non-Markovian QME, and the new approach can account for inter-exciton coupling, dephasing, relaxation, and non-Markovian effects in a consistent manner.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2002.12a
• /
• pp.14-15
• /
• 2002

Iron nitride alloy films prepared in the form of laminated ${(Fe_{97}Al_3)}_{85}N_{15}/Al_2O_3$ multilayers (Ml's) due to excellent soft magnetic properties and high saturation magnetization [1, 2] are very promising materials for poles and shields in ultra high density thin film heads. The present work concerns the ferromagnetic (FM) coupling effect as a function of the thickness of $Al_2O_3$ spacers by analysis of the magnetic domain structure.

• Journal of Magnetics
• /
• v.20 no.4
• /
• pp.336-341
• /
• 2015

MnBi alloys were fabricated by arc melting and annealing at 573 K. The heat treatment enhanced the content of the low-temperature phase (LTP) of MnBi up to 83 wt%. The Bi-excess assisted LTP MnBi alloys were used in the hybridization with the Nd-Fe-B commercial Magnequench ribbons to form the hybrid magnets (100-x)NdFeB/xMnBi, x = 20, 30, 40, 50, and 80 wt%. The as-milled powder mixtures of Nd-Fe-B and MnBi were aligned in a magnetic field of 18 kOe and warm-compacted to anisotropic and dense bulk magnets at 573 K by 2,000 psi for 10 min. The magnetic ordering of two hard phase components strengthened by the exchange coupling enhanced the Curie temperature ($T_c$) of the magnet in comparison to that of the powder mixture sample. The prepared hybrid magnets were highly anisotropic with the ratio $M_r/M_s$ > 0.8. The exchange coupling was high, and the coercivity $_iH_c$ of the magnets was ~11-13 kOe. The maximum value of the energy product $(BH)_{max}$ was 8.4 MGOe for the magnet with x = 30%. The preparation of MnBi alloys and hybrid magnets are discussed in details.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2007.11a
• /
• pp.824-828
• /
• 2007

In this paper Statistical Energy Analysis has been considered to predict middle, high frequency air borne interior noise. PIM method is used for verification. Damping loss factor and coupling loss factor have been derived from the response(SPL) of sub systems when the power is applied. The airborne SEA model of vehicle is modeled through AutoSea2. Insulation material's absorption coefficient and transmission loss are acquired from closed form solution and experiment.