• 제목/요약/키워드: corrosion time

검색결과 1,184건 처리시간 0.027초

중성화와 염해를 고려한 콘크리트의 복합열화 예측 (Prediction of Deterioration Process for Concrete Considering Combined Deterioration of Carbonation and Chlorides Ion)

  • 이창수;윤인석
    • 콘크리트학회논문집
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    • 제15권6호
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    • pp.902-912
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    • 2003
  • 전 세계적으로 콘크리트 구조물의 열화를 발생하는 가장 중요한 원인은 중성화와 염소이온이다. 대체적으로 많은 콘크리트 구조물에서 염소이온과 중성화로 인하여 철근이 부식되며 이에 대한 많은 연구가 이루어지고 있다. 그러나 실구조물의 상황은 염소이온과 중성화가 복합적으로 발생함에도 불구하고 많은 연구들이 각각의 단일열화에 대한 연구가 이루어지고 있으며 복합열화에 대한 연구는 매우 드문 상황이다. 본 연구는 2중 복합 매체에 대한 확산모델을 이용하여 중성화된 콘크리트의 염소이온 프로파일을 예측하고자 하였다. 실험결과에 의하여 중성화 깊이로부터 3∼5 mm영역에 염소이온의 농축현상이 발생하였으며 2중 복합 구조체에 적용할 수 있는 확산 방정식에 중성화된 콘크리트와 비중성화된 콘크리트의 시간의존적인 염소이온 확산 계수를 고려하여 내구수명예측에 반영하였다.

고로슬래그가 치환된 시멘트복합체의 열역학적 모델링 (Thermodynamic Modelling of Blast Furnace Slag Blended Cement Composites)

  • 양영탁;차수원
    • 한국건설순환자원학회논문집
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    • 제5권4호
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    • pp.488-495
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    • 2017
  • 본 연구에서는 열역학적 평형을 이용한 OPC의 재령에 따른 운동학적 수화 생성물 모델링과 GGBS의 치환률에 따른 수화 생성물의 변화를 모델링하였다. 열역학 데이터는 GEMS의 3rd party 데이터베이스, Cemdata18을 사용하였고, 시멘트 수화 모델링은 Parrot & Killoh 모델을 적용하였다. OPC모델링에서 재령에 따라 Pore solution의 이온 농도와 수화 생성물의 질량 및 부피 변화를 관찰할 수 있었다. GGBS모델링에서는 치환률이 증가함에 따라 장기강도를 지배하는 C-S-H의 생성량은 증가하지만, 내구성에 영향을 미치는 Portlandite의 생성량이 감소하여 탄산화에 대한 대책이 필요할 것으로 판단된다.

해수환경중 전착원리에 의해 형성시킨 환경친화적인 코팅막의 특성 분석 (Properties Analysis of Environment Friendly Coating Films Formed by Using Electrodeposition Principle on Seawater)

  • 백상민;이찬식;김기준;문경만;이명훈
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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    • pp.196-197
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    • 2005
  • Cathodic protection is one of the successful ways to prevent corrosion of steel structures in marine environments. The unique feature of cathodic protection in seawater is the formation of calcareous deposits on cathodic metal surface. The formation principles of calcareous deposit seawater had been known for a long time. That is, cathodic reduction reactions associated with cathodic protection in seawater generate $OH^-$ at the metal surface in accordance with the formular ; 1/2 $O_2$ + $H_2O$ + $2e^-$ $2OH^-$ and $2H_2O$ + $2e^-$ ${\rightarrow}$ $H_2$ + $2OH^-$. These reactions increase the pH at the metal / seawater interface. The high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the formular ; $Mg^{2+}$ + $2(OH)^-$ ${\rightarrow}$ $Mg(OH)_2$ and $Ca^{2+}$ + $HCO_3^-$ + $OH^-$ ${\rightarrow}$ $H_2O$ + $CaCO_3$. These are typically the main compounds in calcareous deposits. It obviously has several advantages compared to the conventional coatings, since the environment-friendly calcareous deposit coating is formed by the elements($Mg^{2+}$, $Ca^{2+}$) naturally present in seawater. In this study, environmental friendly calcareous deposit films were prepared on steel plates by electro plating technic in natural seawater. The influence of current density on composition ratio, structure and morphology of the coated films were investigated by scanning electron microscopy formation process of calcareous deposits films in natural seawater. And we confirmed the properties of all the films can be improved greatly by controlling the material structure and morphology with effective use of the electroplating method in natural seawater.

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다구찌 기법을 적용한 섬유금속적층판 접착층의 에너지 해방률 강화에 대한 연구 (Study on Enhancement for Interfacial Energy Release Rate of Adhesive Layer in Fiber Metal Laminates using Taguchi Method)

  • 길민규;박으뜸;송우진;강범수
    • Composites Research
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    • 제29권5호
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    • pp.249-255
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    • 2016
  • 섬유금속적층판은 우수한 피로특성, 내부식성, 충격저항 등으로 인하여 항공우주산업에서 널리 사용되고 있다. 본 논문에서는 다구찌 기법을 사용하여 섬유금속적층판의 내부 에너지 해방률을 향상시킬 수 있는 공정 조건을 도출하는 절차에 대해 실험적 연구가 수행되었다. 내부 접착력 향상을 위한 제조공정을 도출하기 위해서, 표면처리, 접착필름의 용융점 유지시간 및 초기 압력이 서로 다르다는 조건하에서 제작한 시편들에 대해서 Double cantilever beam과 End-notched flexure 시험을 수행하였다. 시험으로부터 모드 I과 모드 II의 에너지 해방률을 측정한 후, 다구찌 기법의 망대특성에 의한 신호 잡음비를 비교하여 효율적인 제조공정을 도출하였다.

전로용 MgO-C질 내화벽돌의 손상요인 (Wear Mechanisum of Carbon Bearing BOF Refreactories)

  • 김의훈;오영우;이철수;김종성;김종희
    • 한국세라믹학회지
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    • 제23권1호
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    • pp.51-59
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    • 1986
  • It was the first time the MgO-C brick was developed for the lining materials in the hot spots in electric are furnace in 1972. MgO-C brick is high registant to thermal and structural spalling. Futhermore for the reason that carbon is hard to react with slag and MgO is high fireproof MgO-C brick shows a high corrosion registance to slag attack compared with conventional basic refractories. Owing to their excellent properties the use of MgO-C refractories are being developed widely in the field of shaped refractories and even in that of monolithic refractories. In this paper the oxidation of carbon the infiltration of slag into the brick texture and effects of additions were investigated. The results obtained were as follows : 1) The use of fused MgO-clinker and high purity carbon as raw materials increased the corosion registance and hot modulus of rupture of MgO-C brick. 2) As the oxidation reaction of the carbon proceeded the slag infiltrated into the brick texture. And then the slag components reacted with the MgO grains and formed low melting point compounds particulary CaO.MgO.$SiO_2$ and 3CaO.MgO.$2SiO_2$ that resulted in the wear of the brick. 3) It is recongnized the Al, Si, $B_3C$ effects on the oxidation registant properties of MgO-C brick by contribu-ting to the decrease of permeability according to the formation of $Al_4C_3$, SiC, $B_2O_3$ and the decrease of open pores relating to the formation of MgO.Al2O3, $SiO_2$, 3MgO.$B_2O_3$ at the decarbonized layer.

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열처리한 교정용 호선의 기계적 성질과 금속유리에 대한 연구 (THE EFFECTS OF HEAT TREATMENT ON MECHANICAL PROPERTIES AND METAL RELEASE FROM HEAT-TREATED ORTHODONTIC ARCHWIRES)

  • 최철민;이병태
    • 대한치과교정학회지
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    • 제20권2호
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    • pp.381-390
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    • 1990
  • The purpose of this study was to evaluate the effects of heat treatment on mechanical properties in $0.016^{{\prime}{\prime}}{\times}0.022^{{\prime}{\prime}}$ blue Elgiloy wires and to measure the amounts of nickel and chromium released from the wires in artificial saliva. Ultimate tensile strength, yield strength and elongation were measured with universal testing machine (Instron). and the amounts of nickel and chromium released from the sample were measured with atomic absorption spectrophotometer after one week immersion in the artificial saliva. Ultimate tensile strength and yield strength were progressively increased below $1000^{\circ}F$, but elongation was decreased. And the results were reversed above $1100^{\circ}F$. After heat treatment of the sample for 9 minutes at $1000^{\circ}F$, the maximum tensile strength and yield strength were $213.6kg/mm^2$, $140.1kg/mm^2$, respectively. Both tensile strength and yield strength were decreased progressively above $1100^{\circ}F$. Elongation was appeared the minimum value (8.6%) after heat treatment for 9 minutes and 12 minutes at $1000^{\circ}F$. There was a pronounced increase in nickel and chromium liberation with increasing time and temperature. The maximum amounts of nickel and chromium released form the sample were $4.947{\mu}m/cm^2$, $3.088{\mu}g/cm^2$, respectively after heat treatment for 12 minutes at $1300^{\circ}F$. Heat treatment is applied to orthodontic wires, especially cobalt-chromium alloys, for the purpose of stress-relievning and hardening. When the heat-treatment of orthodontic wires, the heating procedure should be well controlled in order to have no effect on corrosion resistance and mechanical properties.

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터보차저 컨트롤 플레이트의 절삭량 최소화를 위한 정형공정 (Net Shaping Process to Minimize Cutting amount of Turbocharger Control Plate)

  • 윤필환;이선봉
    • 한국기계가공학회지
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    • 제16권4호
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    • pp.53-61
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    • 2017
  • Turbocharger is a device for increasing the power of a vehicle engine. The control plate is the main component for fixing the vane of the turbocharger. Now, the control plate is made of austenite steel cutting after the casting process. It has excellent corrosion, heat resistance and mechanical characteristics of material. However, present the process is made by cutting after casting. when cutting is processed after casting, so materials, processing time, and processing energy are lost. Therefore, this study proposes a process to powder compact use of stainless steel Deklak2 and to minimize amount of cutting through net shape process. The mechanical properties of Deklak2 were verified by tensile test, hardness test and relative density measurement, and the governed equation was defined. Also, the curvature radius 1, 2 and the density, affects the shape, were selected as the design parameters, and the best process conditions was proposed through the Taguchi method and the evaluation of SN ratio. And then prototype molds were fabricated and compared with the results of the finite element analysis for the verification, and it was found that the tendency of relative density and dimension was coincided. Therefore, it was found that the amount of cutting can be minimized by only the net shape process after the sintering process and it can be applied to mass production.

Etching characteristics of Al-Nd alloy thin films using magnetized inductively coupled plasma

  • Lee, Y.J.;Han, H.R.;Yeom, G.Y.
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 1999년도 추계학술발표회 초록집
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    • pp.56-56
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    • 1999
  • For advanced TFT-LCD manufacturing processes, dry etching of thin-film layers(a-Si, $SiN_x$, SID & gate electrodes, ITO etc.) is increasingly preferred instead of conventional wet etching processes. To dry etch Al gate electrode which is advantageous for reducing propagation delay time of scan signals, high etch rate, slope angle control, and etch uniformity are required. For the Al gate electrode, some metals such as Ti and Nd are added in Al to prevent hillocks during post-annealing processes in addition to gaining low-resistivity($<10u{\Omega}{\cdot}cm$), high performance to heat tolerance and corrosion tolerance of Al thin films. In the case of AI-Nd alloy films, however, low etch rate and poor selectivity over photoresist are remained as a problem. In this study, to enhance the etch rates together with etch uniformity of AI-Nd alloys, magnetized inductively coupled plasma(MICP) have been used instead of conventional ICP and the effects of various magnets and processes conditions have been studied. MICP was consisted of fourteen pairs of permanent magnets arranged along the inside of chamber wall and also a Helmholtz type axial electromagnets was located outside the chamber. Gas combinations of $Cl_2,{\;}BCl_3$, and HBr were used with pressures between 5mTorr and 30mTorr, rf-bias voltages from -50Vto -200V, and inductive powers from 400W to 800W. In the case of $Cl_2/BCl_3$ plasma chemistry, the etch rate of AI-Nd films and etch selectivity over photoresist increased with $BCl_3$ rich etch chemistries for both with and without the magnets. The highest etch rate of $1,000{\AA}/min$, however, could be obtained with the magnets(both the multi-dipole magnets and the electromagnets). Under an optimized electromagnetic strength, etch uniformity of less than 5% also could be obtained under the above conditions.

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부재의 강성변화에 따른 강철도 트러스 교량의 발생응력 예측에 관한 연구 (A Study on the Expection of the Stress to the Stiffness Variation of Members on Truss Railway Bridge)

  • 조선규
    • 한국강구조학회 논문집
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    • 제9권4호통권33호
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    • pp.535-541
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    • 1997
  • 공용중에 있는 철도 교량의 거동 상태를 평가하는 데 있어서는 각 부재에 대한 현장 실측을 통하여 하중의 분배와 발생응력 등을 파악하는 것이 가장 정확하나 이는 매우 어렵다. 그래서. 현장 실측을 거치지 않고 자료조사 및 현지 외관조사 등으로 획득이 가능한 교량의 형식, 각 부재의 손상 정도 및 위치, 열차 교통 특성 등의 간접자료를 사용하여 대상교량의 발생응력을 추정하는 것에 대한 연구가 필요하다. 따라서, 본 연구에서는 교량에서 발생하는 부재의 응력변화 특성을 정량적으로 평가하기 위하여 여러 가지 손상중에서도 부식에 의한 단면의 감소와 강성의 변화를 고려하여 시물레이션에 의한 부재의 발생응력을 구하였다. 이로부터 각 부재의 발생응력의 정도와 면화를 조사하였으며 각 부재간의 상호관계를 고찰하였다. 그 결과 단면의 감소에 따라 트러스 주부재에 발생하는 응력은 대체적으로 선형적으로 증가하고 하현재가 가장 크게 영향을 받는 것으로 나타났다. 또한, 부재에 발생하는 응력의 증가량은 각각의 부재에 발생하는 응력의 증가량을 더하므로서 큰 오차없이 계산될 수 있음을 알 수 있었다.

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LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구 (A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence)

  • 문형순;권봉재;정문영;신상룡
    • 한국정밀공학회지
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    • 제15권8호
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    • pp.17-25
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    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

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