• Journal of Mechanical Science and Technology
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• 제14권2호
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• pp.152-158
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• 2000

The contents of this paper include the evaluation of corrosion characteristics and the behaviour of stress corrosion cracking (SCC) for the weldment and post weld heat treatment (PWHT) specimen and parent of HT -60 steel using a slow strain rate test (SSRT) in synthetic seawater. Corrosion characteristics were obtained from the polarization curves by potentiostat, and SCC phenomena were evaluated through the parameters such as reduction of area and time to failure by comparing the experimental results in corrosive environment with those obtained in air. Corrosion rate of the weldment was the fastest, followed by parent and PWHT specimen. SCC phenomena between the weldment of HT-60 steel and synthetic seawater were shown. Besides, SCC was dependent upon the pulling speed greatly. Maximum severity of SCC was obtained at a speed of $10^{-6}mm/min$, whereas SCC could not be seen almost at $10^{-4}mm/min$. The resistance to SCC for PWHT specimen was improved considerably compared that of the weldment at $10^{-6}mm/min$. In case of SCC failure, it was verified from SEM examination that brittle mode and lots of pits could be seen at the fractured region near the surface of the specimen.

• Steel and Composite Structures
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• 제48권1호
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• pp.27-41
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• 2023

Under the long-term effect of corrosive environment, many cold-formed steel (CFS) structures have serious corrosion problems. Corrosion leads to the change of surface morphology and the loss of section thickness, which results in the change of instability mode and failure mechanism of CFS structure. This paper mainly investigates the elastic local buckling behavior of corroded CFS columns. The surface morphology scanning test was carried out for eight CFS columns accelerated corrosion by the outdoor periodic spray test. The thin shell finite element (FE) eigen-buckling analysis was also carried out to reveal the influence of corrosion surface characteristics, corrosion depth, corrosion location and corrosion area on the elastic local buckling behaviour of the plates with four simply supported edges. The accuracy of the proposed formulas for calculating the elastic local buckling stress of the corroded plates and columns was assessed through extensive parameter studies. The results indicated that for the plates considering corrosion surface characteristics, the maximum deformation area of local buckling was located at the plates with the minimum average section area. For the plates with localized corrosion, the main buckling shape of the plates changed from one half-wave to two half-wave with the increase in corrosion area length. The elastic local buckling stress decreased gradually with the increase in corrosion area width and length. In addition, the elastic local buckling stress decreased slowly when corrosion area thickness was relatively large, and then tends to accelerate with the reduction in corrosion area thickness. The distance from the corrosion area to the transverse and longitudinal centerline of the plate had little effect on the elastic local buckling stress. Finally, the calculation formula of the elastic local buckling stress of the corroded plates and CFS columns was proposed.

• 대한기계학회논문집A
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• 제26권4호
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• pp.731-738
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• 2002

To understand failure behavior of pipe thinned by flow accelerated corrosion, in this study, the pipe failure tests were performed on 102mm-Sch.80 carbon steel pipe with various local wall thinning shapes, and the failure mode, load carrying capacity, and deformability were investigated. The tests were conducted under loading conditions of 4-points bending and internal pressure. The experimental results showed that the failure mode of thinned pipe depended on magnitude of internal pressure and thinning length as well as loading direction and thinning depth and angle. The variation in load carrying capacity and deformability of thinned pipe with thinning length was determined by stress type appled to the thinning area and circumferential thinning angle. Also, the effect of internal pressure on failure behavior was dependent on failure mode of thinned pipe, and it promoted crack occurrence and mitigated local buckling at thinned area.

• Corrosion Science and Technology
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• 제21권1호
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• pp.32-40
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• 2022

The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as E_HOMO, E_LUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

• Corrosion Science and Technology
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• 제2권6호
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• pp.283-288
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• 2003

The cathodic protection method is being widely used in marine structural steel, however a high tensile steel like RE 36 steel for marine structural steel is easy to get hydrogen embrittlement due to over protection during cathodic protection as well as preferential corrosion of HAZ(Heating Affected Zone) part. In this paper, corrosion resistance and mechanical properties such as elongation and hydrogen embrittlement were investigated with not only in terms of electrochemical view but also SSRT(Slow Strain Rate Test) method with applied constant cathodic potential, analysis of SEM fractography in case of both As-welded and PWHT(Post-Weld Heat Treatment) of $550^{\circ}C$. The best effect for corrosion resistance was apparently indicated at PWHT of $550^{\circ}C$ and elongation was increased with PWHT of $550^{\circ}C$ than that of As-welded condition. On the other hand. Elongation was decreased with applied potential shifting to low potential direction which may be caused by hydrogen embrittlement, however the susceptibility of hydrogen embrittlement was decreased with PWHT of $550^{\circ}C$ than that of As-welded condition and Q.C(quasi cleavage) fracture mode was also observed significantly according to increasing of susceptibility of hydrogen embrittlement. Eventually it is suggested that an optimum cathodic protection potential range not causing hydrogen embrittlernent is from -770 mV(SCE) to -850 mV(SCE) in As-welded condition while is from -770 mV(SCE) to -875 mV(SCE) in PWHT of $550^{\circ}C$.

• 한국재료학회지
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• 제13권9호
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• pp.625-630
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• 2003

Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as Polyaniline(PANI). Polyaniline films were electrosynthesized by oxidation of aniline on cold rolled and weathering sheets using the potentiostatic mode from an aqueous oxalic acid medium. Potentiodynamic polarization curves were obtained for cold rolled and weathering sheets in the aqueous solution of 3% sodium chloride. The structure and properties of polyaniline film were elucidated using SEM, DSC, SST. A high corrosion resistance of polyaniline films were observed with a gain of the corrosion potential around 600-900 mV positive in the substrate covered with polyaniline than in the case without it.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.274-277
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• 2004

The most important mode of subcritical crack growth is primary water stress corrosion crack, which was the reported mechanism from the root cause analysis of the crack in the bimetallic welds. Stress corrosion crack growth evaluations was carried out for several flaw shapes of both axial and circumferential flaws, using the steady-state stresses including residual stresses. This evaluation considered the possibility of additional flaws in the primary loops of nuclear power plant, even though no such flaws have been identified by Ultrasonic Test. Consequently, Results show that the predicted flaw sizes will determine acceptability for continued service and maintenance.

• 한국표면공학회지
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• 제31권4호
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• pp.223-230
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• 1998

The separator for a molten carbonate fuel cell(MCFC) is mode of stainless steel and known to the suscepibility to corrosion due to environments of high temperature molten carbonte electrolyte. Considering the sensitization of stainless steel in the temperature range of 425~$815^{\circ}C$, the separator is expected to be sensitized so that the interganular corrosion (IGC) occurs during the cell operation at about $650^{\circ}C$. In this study, EPR(electrochemical potentiokinetic reactivation) technique was examined by relating some elements(mainly C and Cr) to the degree of sensitization of austenitic stainless steels in the molten carbonate salt at $650^{\circ}C$and the possible mechanism of intergranular corrosion was analyzed.

• 한국주조공학회지
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• 제40권5호
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• pp.129-133
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• 2020

The outcomes of solution annealing and stress corrosion cracking in cold-worked 316L austenitic stainless steel have been studied using x-ray diffraction (XRD) and the slow strain rate test (SSRT) technique. The good compatibility with a high-temperature water environment allows 316L austenitic stainless steel to be widely adopted as an internal structural material in light water reactors. However, stress corrosion cracking (SCC) has recently been highlighted in the stainless steels used in commercial pressurized water reactor (PWR) plants. In this paper, SCC and inter granular cracking (IGC) are discussed on the basis of solution annealing in a chloride environment. It was found that the martensitic contents of cold-worked 316L stainless steel decreased as the solution annealing time was increased at a high temperature. Moreover, mode of SCC was closely related to use of a chloride environment. The results here provide evidence of the vital role of a chloride environment during the SCC of cold-worked 316L.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.699-710
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• 2020

Pitting corrosion commonly shaped in hull structure due to marine corrosive environment seriously causes the deterioration of structural performance. This paper deals with the ultimate strength behaviors of stiffened ship panels damaged by the pits subjected to uniaxial compression. A series of no-linear finite element analyses are carried out for three stiffened panels using ABAQUS software. Influences of the investigated typical parameters of pit degree (DOP), depth, location and distribution on the ultimate strength strength are discussed in detail. It is found that the ultimate strength is significantly reduced with increasing the DOP and pit depth and severely affected by the distribution. In addition, the pits including their distributions on the web have a slight effect on the ultimate strength. Compared with regular distribution, random one on the panel result in a change of collapse mode. Finally, an empirical formula as a function of corrosion volume loss is proposed for predicting the ultimate strength of stiffened panel.