• Title/Summary/Keyword: core stability

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Modeling, Preparation, and Elemental Doping of Li7La3Zr2O12 Garnet-Type Solid Electrolytes: A Review

  • Cao, Shiyu;Song, Shangbin;Xiang, Xing;Hu, Qing;Zhang, Chi;Xia, Ziwen;Xu, Yinghui;Zha, Wenping;Li, Junyang;Gonzale, Paulina Mercedes;Han, Young-Hwan;Chen, Fei
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.111-129
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    • 2019
  • Recently, all-solid-state batteries (ASSBs) have attracted increasing interest owing to their higher energy density and safety. As the core material of ASSBs, the characteristics of the solid electrolyte largely determine the performance of the battery. Thus far, a variety of inorganic solid electrolytes have been studied, including the NASICON-type, LISICON-type, perovskite-type, garnet-type, glassy solid electrolyte, and so on. The garnet Li7La3Zr2O12 (LLZO) solid electrolyte is one of the most promising candidates because of its excellent comprehensively electrochemical performance. Both, experiments and theoretical calculations, show that cubic LLZO has high room-temperature ionic conductivity and good chemical stability while contacting with the lithium anode and most of the cathode materials. In this paper, the crystal structure, Li-ion transport mechanism, preparation method, and element doping of LLZO are introduced in detail based on the research progress in recent years. Then, the development prospects and challenges of LLZO as applied to ASSBs are discussed.

Electrical Characteristics Measurement of Eddy Current Testing Instrument for Steam Generator in NPP (원전 증기발생기 와전류검사 장치의 전기적 특성 측정)

  • Lee, Hee-Jong;Cho, Chan-Hee;Yoo, Hyun-Joo;Moon, Gyoon-Young;Lee, Tae-Hun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.5
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    • pp.465-471
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    • 2013
  • A steam generator in nuclear power plant is a heatexchager which is used to convert water into steam from heat produced in a nuclear reactor core, and the steam produced in steam generator is delivered to the turbine to generate electricity. Because of damage to steam generator tubing may impair its ability to adequately perform required safety functions in terms of both structural integrity and leakage integrity, eddy current testing is periodically performed to evaluate the integrity of tubes in steam generator. This assessment is normally performed during a reactor refueling outage. Currently, the eddy current testing for steam generator of nuclear power plant in Korea is performed in accordance with KEPIC & ASME Code requirements, the eddy current testing system is consists of remote data acquisition unit and data analysis program to evaluate the acquired data. The KEPIC & ASME Code require that the electrical properties of remote data acquisition unit, such as total harmonic distortion, input & output impedance, amplifier linearity & stability, phase linearity, bandwidth & demodulation filter response, analog-to-digital conversion, and channel crosstalk shall be measured in accordance with the KEPIC & ASME Code requirements. In this paper, the measurement requirements of electrical properties for eddy current testing instrument described in KEPIC & ASME Code are presented, and the measurement results of newly developed eddy current testing instrument by KHNP(Korea Hydro & Nuclear Power Co., LTD) are presented.

Studies on the Microencapsulation of ${\omega}-3$ Polyunsaturated Fatty Acid (${\omega}-3$계 지방산의 미세캡슬화에 관한 연구)

  • Kim, Chul-Hyun;Lee, Kyung-Wook;Baick, Seung-Chun;Kwak, Hae-Soo;Kang, Jong-Ok
    • Korean Journal of Food Science and Technology
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    • v.28 no.4
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    • pp.743-749
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    • 1996
  • This study was carried out to investigate the microencapsulatuion of ${\omega}-3$ fatty acid isolated from fish oil and to obtain fundamental information on the utilization of the ${\omega}-3$ fatty acid in the dairy foods field. To obtain the desirable microencapsulation efficiency, 1.5% agar and 0.5% gelatin were used as coating materials, and 0.5% SFAN 60 (HLB 4.5 value) was used to maintain the emulsion stability. The optimal mixing ratio of coating material to core material was 8:2 (w/w). The thermostability of microencapsulated product was not maintained above $60^{\circ}C$. Microencapsulation efficiency was kept at about 90% at $4^{\circ}C$ and $10^{\circ}C$ for 7 days storage at various temperatures. At $20^{\circ}C$ and $30^{\circ}C$, however, about 80% microencapsulatuion efficiency was obtained for 3 days storage. About 80.57% microcapsule was destroyed by 1%> pepsin solution at $37^{\circ}C$ for 10 min.

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A Study on the Quantitative Evaluation of the Load Distribution Factors Considering the Design Conditions of Tunnel Especially for the Ring-cut Excavation Method (터널 설계조건을 고려한 하중분배율의 정량적 산정에 관한 연구 -ring-cut 굴착공법을 중심으로-)

  • 장석부;문현구
    • Geotechnical Engineering
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    • v.14 no.5
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    • pp.5-16
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    • 1998
  • 2-D numerical methods have been applied to analyze the stability of tunnels because of computation efficiency, though the ground around the tunnel under construction shows 3-D reformational behaviour due to the transverse and longitudinal arching effects. Load distribution factors are introduced to the 2-D analysis for the consideration of the effects of the tunnel advance in three dimensions. The load distribution factors influence significantly the ground deformation and the load of primary supports like shotcrete and rockbolts. According to the previous studies for 3-D numerical studies. it was shown that load distribution factors were heavily dependent on the ground deformational properties, tunnel size and the advance length of a tunnel. However, as the quantitative methods evaluating the factors have not been presented yet, constant values have been assigned to the factors for 2-D analysis even if the conditions for tunnel design are different. Accordingly, this paper presents the method to evaluate quantitatively the load distribution factors through the regression analysis of 3-D analysis data on 72 design cases. Also, new modification to the load distribution factors are suggested for the ring-cut excavation method because the conventional 2-D analysis is not able to consider the support effects of the core left on the tunnel face.

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In-situ Synchrotron Radiation Photoemission Spectroscopy Study of Property Variation of Ta2O5 Film during the Atomic Layer Deposition

  • Lee, Seung Youb;Jeon, Cheolho;Kim, Seok Hwan;Lee, Jouhahn;Yun, Hyung Joong;Park, Soo Jeong;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.362-362
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    • 2014
  • Atomic layer deposition (ALD) can be regarded as a special variation of the chemical vapor deposition method for reducing film thickness. ALD is based on sequential self-limiting reactions from the gas phase to produce thin films and over-layers in the nanometer scale with perfect conformality and process controllability. These characteristics make ALD an important film deposition technique for nanoelectronics. Tantalum pentoxide ($Ta_2O_5$) has a number of applications in optics and electronics due to its superior properties, such as thermal and chemical stability, high refractive index (>2.0), low absorption in near-UV to IR regions, and high-k. In particular, the dielectric constant of amorphous $Ta_2O_5$ is typically close to 25. Accordingly, $Ta_2O_5$ has been extensively studied in various electronics such as metal oxide semiconductor field-effect transistors (FET), organic FET, dynamic random access memories (RAM), resistance RAM, etc. In this experiment, the variations of chemical and interfacial state during the growth of $Ta_2O_5$ films on the Si substrate by ALD was investigated using in-situ synchrotron radiation photoemission spectroscopy. A newly synthesized liquid precursor $Ta(N^tBu)(dmamp)_2$ Me was used as the metal precursor, with Ar as a purging gas and $H_2O$ as the oxidant source. The core-level spectra of Si 2p, Ta 4f, and O 1s revealed that Ta suboxide and Si dioxide were formed at the initial stages of $Ta_2O_5$ growth. However, the Ta suboxide states almost disappeared as the ALD cycles progressed. Consequently, the $Ta^{5+}$ state, which corresponds with the stoichiometric $Ta_2O_5$, only appeared after 4.0 cycles. Additionally, tantalum silicide was not detected at the interfacial states between $Ta_2O_5$ and Si. The measured valence band offset value between $Ta_2O_5$ and the Si substrate was 3.08 eV after 2.5 cycles.

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The Study on Design of Circuit Card Assembly on Servo Control Unit for Automated Resupply Vehicle K56 (K56 탄약운반장갑차용 서보제어기의 회로카드조립체 설계에 관한 연구)

  • Lee, Ju-Seung;Kim, Seong-Jin;Bae, Gong-Myeong;Kwon, Soon-Mo;Park, Hyean-Jo;Choi, Jun-Sok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.102-109
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    • 2019
  • This paper describes the design of the circuit card assembly to eliminate the communication error on a servo control unit installed in the automated resupply vehicle K56. K56 is a weapon system that automates the supply and loading of ammunition on the K-55A1 self-propelled artillery. As the core item responsible for ammunition movement control, the servo control unit is required to have good communication stability and reliability, but the conventional unit has recognized a problem that communication error intermittently occurs, resulting in an emergency stop phenomenon. We analyzed the communication signal of the servo control unit and identified the failure cause of the circuit card assembly to solve this problem. In addition, the signal interference in data/address line of the circuit card assembly was confirmed through analysis of the failure cause, and redesigned to avoid the interference, such as adjustment of the distance between communication lines and position change. Finally, the proposed cause analysis and redesign were verified through the component of servo control unit and attachment test on K56. We expected these study results to be used as reference for the design of other similar items.

Mechanical Properties and 3D CAD Images of the Appearance of Knitted Fabric with Acetate/Polyester Composite Yarn by Different Yarn Twisting Methods (연사방법에 따른 아세테이트/폴리에스터 복합사 편성물의 역학적 특성 및 3D CAD System에 의한 외관특성)

  • Kim, So-Jin;Jeon, Dong-Won;Park, Young-Hwan
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.33-43
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    • 2006
  • The purpose of this study was to eximine the effect of different yam twisting methods on mechanical properties and 3D CAD images of plain knitted fabrics made of composite yarns. Six yams were used in this study: four different composite yams of the six consist of acetate and functional polyester (Poly-m) with the ratio of 70:30, and the rest two are the original acetate $100\%$ yam and the poly-m $100\%$ yarn. The four kinds of composite yarns were processed in combinations of twisting processes such as interlacing, false twisting, two for one twisting, combined twisting and single covering, and the two original yams were knitted without any twisting process. Sixteen mechanical properties of all the six knitted fabrics, knitted under the same knitting conditions, were measured by KES-FB system with the outer knit condition. The results were as follows; 1) When the sample applied with the false twisting process at the temperature as high as $220^{\circ}C$, ENT, B, HB, G and RC values of samples increased which leads to increasing dimensional stability. 2) To gain the high bending and shear properties in the single covering process, selecting the core yarn with such properties is the most important factor. 3) Interlacing process effected to increase RC value. 4) False twisting process after interlacing process gave bulkiness and un-interlaced part in yam was increased SMD value. The SMD value of the kilted fabric of the composite yarn, which was put through the combined twist process, was higher than those of which simple process such as the two for one twist or the single covering process applied. In order to achieve the silk-like surface feel of knitted fabric, the sin91e covering process is recommended. 5) Examining the simulation images of the knifed fabrics of composite yarn, which were generated by the 3D CAD system based on the mechanical properties of the fabric, led that appearance could be changed as different twisting methods were applied.

Construction of a Microsatellite DNA Profile Database for Pear Cultivars and Germplasm (배 품종 및 유전자원에 대한 Microsatellite DNA 프로파일 데이터베이스 구축)

  • Hong, Jee-Hwa;Shim, Eun-Jo;Kwon, Yong-Sham
    • Horticultural Science & Technology
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    • v.35 no.1
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    • pp.98-107
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    • 2017
  • A DNA profile database was constructed to investigate the genetic relatedness of 72 germplasm samples of Pyrus and related cultivars using microsatellite markers. Three P. pyrifolia, four P. commus, and one P. betulifolia cultivars with different morphological traits were screened using 387 pairs of microsatellite primers. A core set of 11 primer pairs was selected to obtain 133 polymorphic amplified fragments meeting three criteria: high polymorphism information contents (PIC), high repeatability, and distinct allele patterns. The number of alleles per locus ranged between 4 and 22. Average PIC was 0.743 (range: 0.557 - 0.879). Cluster analysis using the unweighted pair - group method with arithmetical average (UPGMA) separated the 72 pear cultivars and germplasm samples into four major groups: Chinese, European pears, and a cluster of 55 Asian pears that could be reclassify into two subcluster, I - $1^{st}$ and II - $2^{nd}$, according to pedigree information. Almost all of the cultivars were discriminated by 11 microsatellite marker genotypes. The microsatellite DNA profile database may be utilized as tool to verify distinctness, uniformity, and stability between candidate cultivar, and to verify in the distinctness of existing cultivars.

Correlation of Tectolineaments and Discontinuities in connection with Slope Failure (사면 붕괴와 관련 구조선 분석과 불연속면의 상관성 연구)

  • Baek, Yong;Koo, Ho-Bon;Kim, Seung-Hyun
    • The Journal of Engineering Geology
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    • v.11 no.3
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    • pp.303-313
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    • 2001
  • A cut-slope near Guam-Ri Hwado-Eup Namyangju-Si Kyunggi-Do collapsed during a heavy rainfall over 400mm at 28th of August 2000. The cut-slope collapse reportedly developed mainly by block sliding along a set of discontinuities, although slope angle of the cut-slope was 40$^{\circ}$(1:1.2) that agrees with the road construction criteria. This study aims to analyze differences and correlations among several data-collecting methods limited to discontinuity analysis related with cut-slope collapse. This study started with analysing discontinuity surface characteristics, geology of the country rock and orientations of the discontinuities directly related with the collapse. Analysis of aerial photos around the study area provided regional lineament data, and discontinuity plane description and measurements were collected from core logging and Borehole Image Processing System (BIPS). Spearmans correlation ranking coefficient method was used to get correlation of discontinuity planes according to analysis methods. The result suggests that the correlation coefficient is ${\gamma}_s$ = 0.91 Plus, stability analysis of discontinuity plane orientation data using equal-area stereonet revealed that the study area is unstable to planar failure. This study suggests that the cut-slope angles currently applied should be shallower and that significant attention is required to orientation distribution of discontinuities existed in cut-slopes studies.

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Implications of Growth Arrest Induced by Overproduction of RraB in Escherichia coli (RraB의 발현에 따른 대장균의 성장 저해의 원인 규명)

  • Ryou, Sang-Mi;Yeom, Ji-Hyun;Go, Ha-Young;Shin, Eun-Kyoung;Lee, Kang-Seok
    • Korean Journal of Microbiology
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    • v.46 no.2
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    • pp.223-227
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    • 2010
  • RNase E plays a major role in the degradation and processing of a large number of RNA transcripts in Escherichia coli and forms the core component of the degradosome, a large protein complex involved in RNA metabolism. RraA and RraB are recently discovered protein inhibitors of RNase E and are evolutionarily conserved. In this study, we observed that, unlike RraA, overexpression of RraB did not rescue growth arrest of E. coli cells overexpressing RNase E. To examine whether this phenomenon stems from differential inhibitory effects of RraA and RraB on RNase E substrates, we analyzed three in vivo RNase E substrates. The results showed that RraA inhibited RNase E activity more efficiently than RraB on the degradation of RNA I, which controls the copy number of ColE1-type plasmid, and rpsO mRNA encoding ribosomal protein S15, while RraB was unable to inhibit the processing of pM1 RNA, a precursor of the RNA component of RNase P, by RNase E. Our results imply that RraB inhibits RNase E activity in a more substrate-dependent manner than RraA and this property of RraB may explain why overexpression of RraB could not rescue cells overexpressing RNase E from growth arrest.