• 제목/요약/키워드: coordination center

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분자동력학법에 의한(62-x)CaO·38Al2O3 ·xBaO 유리의 구조 분석 (A study on the Structure of (62-x)CaO·38Al2O3 ·xBaO Glasses by Molecular Dynamics Simulation)

  • 이성주;강은태
    • 한국세라믹학회지
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    • 제44권3호
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    • pp.175-181
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    • 2007
  • Molecular dynamics simulation (MD) of $(62-x)CaO{\cdot}38Al_{2}O_{3}{\cdot}xBaO$ glasses has been carried out using empirical potentials with the covalent term. The simulations closely reproduce the total neutron correlation functions of glass with 5 mol% BaO and physical properties of these glasses such as elastic constants. For these glasses, aluminum is tetrahedrally coordinated by oxygen, but there is a part of five-fold and six-fold coordination of aluminum. There are no major changes to the mid-range structure of glass, as barium is substituted for calcium. To predict the barium coordination number, we have used the bond valence (BV) theory and also compared the results of simulation with Bond valence. The coordination number for oxygen around barium atoms is close to 8 and the average distance of barium and oxygen is nearly 2.80 A. The viscosity of these glasses increases with the content of barium oxide substituted for calcium oxide.

Development of Korean the Version of the Developmental Coordination Disorder Questionnaire (DCDQ-K)

  • Ko, JooYeon;Lee, WanHee;Woon, JungJee;Kim, YoungA
    • The Journal of Korean Physical Therapy
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    • 제32권1호
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    • pp.44-51
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    • 2020
  • Purpose: This study translated the developmental coordination disorder questionnaire'07 (DCDQ'07) into Korean and investigated the psychometric properties of the Korean DCDQ (DCDQ-K) using validation processes. Methods: The subjects were 300 parents with typically developing children aged 5-15 years (162 girls and 138 boys, mean age 9.24 years, SD 2.59) across the country. To develop the Korean DCDQ, a forward-backward-original author feedback-panel meeting-pilot study with parents was done. The internal consistency, test-retest reliability performed two weeks apart, content validity, discriminative validity, convergent validity, and constructive validity were examined with the pre-version of the DCDQ-K. Results: Approximately 15.33% of the subjects were probably shown DCD using DCDQ-K. Significant differences in age and province were observed in the DCDQ-K total score. The reliabilities and validities were good in the DCDQ-K. Conclusion: The DCDQ-K is a reasonable screening tool for DCD children.

Hydrothermal Synthesis, Crystal Structure and EPR Property of Tetranuclear Copper(II) Cluster [Cu4OCl6(C14H12N2)4]

  • Jian, Fang-Fang;Zhao, Pu-Su;Wang, Huan-Xiang;Lu, Lu-De
    • Bulletin of the Korean Chemical Society
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    • 제25권5호
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    • pp.673-675
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    • 2004
  • The tetranuclear copper(II) cluster compound $[Cu_4OCl_6(C_{14}H_{12}N_2)_4]$ has been synthesized by hydrothermal reaction and studied by X-ray diffraction. The four copper(II) atoms locate four capsheaves of a tetrahedral skeletal structure and a oxygen atom as interstitial atom occupies the center position of the same tetrahedron, and each edge of the Cu-Cu tetrahedron is bridged by one ${\mu}_2$-Cl anion. The copper atom possesses slightly distorted trigonal bipyramidal geometry with three ${\mu}_2$-Cl atoms in equatorial position and the interstitial O atom and one N atom from 3-benzyl-benzimidazole ligand occupying axial position. The Cu-Cu distances are in the range of 3.0986-3.1162 ${\AA}$. The EPR spectrum suggested that the copper(II) ground state $d_{x2-y2}$ and the coordination geometry was trigonal bipyramidal.

Verbal Conjunctions in Korean, English and Japanese

  • Oh, Chisung
    • 비교문화연구
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    • 제32권
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    • pp.109-132
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    • 2013
  • This paper compares sequential and non-sequential verbal conjunctions in Korean, English, and Japanese by looking at how sequential verbal conjunction is treated in each language. It frist reviews verbal conjunctions in Korean, where sequential conjunction is treated as subordination and non-sequential conjunction is treated as coordination, and looks at verbal conjunctions in English and Japanese to see whether or not sequential conjunction in those languages is subordination. According to Oh (2010), sequential and non-sequential conjunctions in Korean behave quite differently with respect to the tense and negation in the final conjunct. Also, Cho (1995, 2005) and Kwon (2004) show that syntactic operations such as extraction and scrambling clearly distinguish sequential conjunction from non-sequential conjunction. The purpose of this paper is to see how sequential and non-sequential conjunctions are analyzed in English and Japanese and to compare those languages with Korean, especially focusing on whether or not sequential conjunctions in English and Japanese are treated as subordination. For this purpose, I first investigate how tense and negation, which provided crucial evidence for concluding that Korean sequential conjunction is subordination, is interpreted in sequential and non-sequential verbal conjunctions in English and Japanese. Also, I investigate the syntactic properties of sequential and non-sequential conjunctions with respect to syntactic operations such as extraction and scrambling in those languages. The results of the investigation show that in Japanese, which is considered typologically similar to Korean, the sequential conjunction is a case of subordination, while in English, which is considered typologically different from Korean, both sequential and non-sequential conjunctions are treated as coordination.

전자공업육성(電子工業育成) 시스템의 설계(設計) (Design of an Electronics Industry Development System)

  • 최덕원
    • 대한산업공학회지
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    • 제4권1호
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    • pp.5-10
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    • 1978
  • In this paper it was attempted to design a system for the effective development of electronics industry by use of systems management concept. For the design of this system, current status of electronics industry was analyzed; problem area was derived through this analysis and developmental strategy was determined. As an organization for centeralized coordination, "Electronics Industry Committee" was proposed. The committee controls three specialized organizations such as R&D center, marketing management center, and council for political support. Each function of these special organizations was introduced and special role as a system manager was described.

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Coordination Modes and Properties of Ag(I) Complex with N,N,N',N',N''-Pentamethyldiethylenetriamine

  • Chun, In-Sung;Kwon, Jung-Ah;Bae, Myung-Nam;Lee, Sim-Seong;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • 제27권7호
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    • pp.1005-1008
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    • 2006
  • The reaction of $AgClO_{4}$ with acyclic potential tridentate N,N,N',N',N''-pentamethyldiethylenetriamine (pmdeta) has given colorless crystals suitable for X-ray crystallography. The crystal structure ($P2_{1}$/n, a = 14.413(1) $\AA$, b = 25.270(2) $\AA$, c = 16.130(1) $\AA$, b = $103.012(1){^{\circ}}$, V = 5723.7(8) A$\AA^{3}$, Z = 4, R = 0.0349) has been solved and refined. Three silver(I) ions connect four pmdeta ligands to produce discrete complex of $[Ag_3(pmdeta)_4](ClO_4)_3$. A pmdeta ligand is bridged to three silver(I) ions, and three other pmdeta ligands are chelated to each silver(I) center in a tridentate mode. Thus, the product is a rare tri-nuclear silver(I) complex with two different chemical environments. $^{13}C$ NMR and $MAS\;^{13}$C NMR indicate that the tri-nuclear silver(I) complex is not rigid in solution. The contact angles and thermal analyses of the complex are measured and discussed.

유럽연합의 개방형 정책조정 (Open Method of Coordination)에 대한 이론적 기대와 현실: 빈곤정책의 사례 (Evaluation of the Open Method of Coordination in Social Inclusion: Theoretical Expectations and Reality)

  • 김승현
    • 국제지역연구
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    • 제14권3호
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    • pp.57-80
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    • 2010
  • 이 연구에서는 개방형 정책조정방법이 사회적 포용의 영역에 도입된 이후, 과정의 변화와 정책효과에 대한 평가를 시도한다. 2000년 리스본이사회에서 결정된 개방형 정책조정방법의 정책도구들은 결과지향적인 신공공관리론과 과정지향적인 숙의적 다중질서라는 거버넌스이론을 배경으로 한다고 볼 수 있다. 역사적 변화과정을 살펴볼 때 결과지향적인 신공공관리론의 정책도구인 목표설정, 수범사례의 벤치마킹, 분권적 의사결정의 경우 애매하거나 아예 거부되었고, 제도적 틀을 넘지 못함으로써 효율성을 추구할 수 없었다. 아울러 규범적인 숙의적 다중질서이론이 제시하는 것처럼 학습을 위해 숙의와 상호검토를 추구하고 있으나, 실제 운영은 성찰적인 숙의과정에 미치지 못하고, 상호검토도 제도적 한계를 보임으로써 원활한 학습이 이루어지지 않는다. 10여 년간 개방형 정책조정방법이 집행되었지만 정책효과의 측면에서도 유의미한 결과를 찾을 수 없다. 그렇지만 빈곤문제에 대한 인식이 변하고 시민사회가 활발하게 조직되어 참여가 확대되고 있는 점은 긍정적인 효과이다.

Institution for Regional Innovation System: The Korean case

  • Kang, Byung-Joo;Oh, Deog-Seong
    • World Technopolis Review
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    • 제4권2호
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    • pp.46-61
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    • 2015
  • There is an implicit assumption in most regional innovation policy studies that once a policy has been made the policy will be implemented. This assumption is not valid for regional innovation policies formulated in many countries. This assumption rests upon certain political and organization conditions. It is frequently said that regional innovation system in Korea is one of the successful cases because of properly established institution for the implementation of innovation policies. The components of institution for innovation are defined in this article. For the analysis of institution for regional innovation system in Korea, three aspects such as organization, policies & programs, and governance structure were taken into account. Institution for regional innovation system in Korea is analyzed with three aspects: (1) organization for policy implementation, (2) innovation policy, and (3) governance structure. Firstly, organizations for innovation in Korea are composed of three categories such as organizations for policy formulation, organizations for policy implementation and agencies for coordination. Secondly, there are two categories of policies for innovation: (1) policies for the enhancement of national competitiveness and policies for the regional innovation capacity building, and (2) policies for fostering manpower and policy for regulatory reform. Thirdly, innovation governance in Korea is composed of three layer structure: (1) top level governance which is composed of two committee, three ministries and two agencies, (2) local level governance such as one innovation related offices and one center for regulatory reform, and (3) one category of agency for coordination as a regional platform.

니켈실리사이드의 색차분석 (Color Difference Characterization on Nickel Silicides)

  • 정영순;송오성;김득중;최용윤;김종준
    • 한국표면공학회지
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    • 제38권1호
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    • pp.44-48
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    • 2005
  • We prepared nickel silicide layers from p-Si(l00)/SiO₂(2000 Å)/poly-Si(700 Å)/Ni(400 Å) structures, feasible for gates in MOSFETs, by annealing them from 500℃~900℃ for 30 minutes. We measured the color coordination in visible range, cross sectional micro-structure, and surface topology with annealing temperature by an UV-VIS-IR spectrometer, field effect scanning electron microscope(FE-SEM), and scanning probe micro-scope respectively. We conclude that we may identify the nickel silicide by color difference of 0.90 and predict the silicide process reliability by color coordination measurement. The nickel silicide layers showed similar thickness while the columnar grains size and surface roughness increased as annealing temperature increased.