• Title/Summary/Keyword: controlled synthesis

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Synthesis of Glycidyl Azido Copolyetherdiol for Solid Propellant Polyurethane Binder (Glycidyl Azido Copolyetherdiol을 이용한 Polyurethane의 합성과 특성분석)

  • Shin, Bum-Sik;Lee, Bum-Jae;Park, Young-Chul;Hwang, Kab-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.231-236
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    • 2008
  • The well-defined copolymers derived from Epichlorohydrin(ECH), Tetrahydrofuran(THF) were synthesized by Cationic ring-opening polymerization(CROP) with 1,4-Butandiol, a initiator, and $BF_3THF$ Complex, a catalyst via Activated monomer mechanism, which could lead to hydroxyl-terminated polyethers. The molecular weight of polymers were dependant on the ratio of [monomer]/[diol], Copolymer structures were controlled by monomers feed ratio, ECH and THF added. This polymers were functionalized from Chlorine group to Azide group using $S_N2$ reaction. Synthesized polymers were found to be as the prepolymer for polyurethane. Polyurethane was synthesized in the presence of N-100/IPDI mixture, a curing agent, and TPB(triphenyl bismuth)/MA(Maleic anhydride) mixture, a catalyst system. The curing behavior and mechanical properties of polyurethane after mixing with various prepolymer’s composition and the molecular weight were studied.

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Synthesis of Biodegradable Aliphatic Polyester with Amino Group in the Side Chain (곁사슬에 아미노기를 도입한 생분해성 지방족 폴리에스테르의 합성)

  • Lee, Chan-Woo
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.381-385
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    • 2010
  • Aiphatic diester monomer, 3-[(benzyloxycarbonylamino)butyl]-1,4-dioxane-2,5-dione (BABD), was synthesized with the N-$\varepsilon$-benzyloxy-carbonyl-L-lysine as starting material. This monomer was synthesized to add the functionality to poly(lactic acid)s. BABD unit was successfully incorporated into the PLLA chain which was confirmed by $^1H$ NMR. The copolymer composition could be controlled by the feed ratios of monomer. The $M_n$ of this resultant polymer is expected to reach high molecular weight after the purification of monomer and optimization of polymerization time, though the polymer showed relatively low degree of polymerization ($M_n$=3300). The copolymer is expected to possess the enhanced hydrophilicity and the possibility of chemical modification on amino group.

Acupoint Sticking Therapy for Endometriosis ; Systematic Review (자궁내막증의 혈위 첩부 치료에 대한 체계적 문헌고찰)

  • Bae, Ju-Eun;Park, Kyung-Dug;Yoon, Young-Jin
    • The Journal of Korean Obstetrics and Gynecology
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    • v.32 no.3
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    • pp.162-173
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    • 2019
  • Objectives: The purpose of this review was to overview and evaluate the efficacy of acupoint sticking therapy for women with endometriosis. Methods: We searched for randomized controlled clinical trials (RCTs) using acupoint sticking therapy on endometriosis in 5 electronic databases such as EMBASE, Pubmed, and CAJ. The results of the studies were analyzed and the risk of bias was assessed by using Cochrane risk of bias tool. Results: Two RCTs were included for analysis. In the selected studies, Treatment group was higher effective cure rate than any control group. In one RCT, Acupoint sticking therapy was only used, but the other RCT was treated acupoint sticking therapy combined with acupuncture. So, Interventions in 2 studies were not same, Quantitative synthesis was impossible. Conclusion: The limitation of this review is that the number of studies included is small. However, our systematic review provides a basis for acupoint sticking therapy for endometriosis. Acupoint sticking therapy was considered as one of external treatment method for patients with endometriosis.

Diameter-Controllable Synthesis and Enhanced Photocatalytic Activity of Electrospun ZnO Nanofibers (전기방사를 이용하여 제조된 산화아연 나노섬유의 직경제어 및 광촉매 특성)

  • Ji, Myeong-Jun;Yoo, Jaehyun;Lee, Young-In
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.79-86
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    • 2019
  • A heterogeneous photocatalytic system is attracting much interest for water and air purification because of its reusability and economical advantage. Electrospun nanofibers are also receiving immense attention for efficient photocatalysts due to their ultra-high specific surface areas and aspect ratios. In this study, ZnO nanofibers with average diameters of 71, 151 and 168 nm are successfully synthesized by facile electrospinning and a subsequent calcination process at $500^{\circ}C$ for 3 h. Their crystal structures, morphology features and optical properties are systematically characterized by X-ray diffraction, scanning electron microscopy, UV-Vis and photoluminescence spectroscopies. The photocatalytic activities of the ZnO nanofibers are evaluated by the photodegradation of a rhodamine B aqueous solution. The results reveal that the diameter of the nanofiber, controlled by changing the polymer content in the precursor solution, plays an important role in the photocatalytic activities of the synthesized ZnO nanofibers.

Implementation Method for DASH-based Free-viewpoint Video Streaming System (DASH 기반 자유시점 비디오 스트리밍 시스템 구현)

  • Seo, Minjae;Paik, Jong-ho
    • Journal of Internet Computing and Services
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    • v.20 no.1
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    • pp.47-55
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    • 2019
  • Free-viewpoint video (FVV) service provides multi viewpoints of contents and synthesizes intermediate video files which are not captured on some view angles so that enables users to watch as they choose wherever they want. Synthesizing video is necessary technique to provide FVV video service, because every video of the FVV contents for different view angles cannot be stored to the content server physically. For the reason, fast view synthesis can improve the quality of video service and increase user's satisfaction. One of the studies for FVV service, a method was proposed to transmit FVV service based on DASH (Dynamic Adaptive Streaming over HTTP). There is big advantage on using DASH that it is commonly used to transport video service. However, the method was only a conceptual proposal, so it is difficult to implement the system using the proposal. In this paper, we propose an implementation method to provide real-time FVV service smoothly. We suggest a system structure and operation method on the server and client side in detail, which is to be applicable to synthesize video quickly. Also, we suggest generating FVV service map additionally which controls a FVV service overall. We manage real-time information of the whole service through the service map. The service can be controlled by reducing the possible delay from network situation.

Synthesis and Characterization of Bandgap-modulated Organic Lead Halide Single Crystals

  • Park, Dae Young;Byun, Hye Ryung;Lee, A Young;Choi, Ho Min;Lim, Seong Chu;Jeong, Mun Seok
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1716-1724
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    • 2018
  • Single crystal of organic lead halide ($CH_3NH_3PbX_3$; $CH_3NH^+_3$ = methylammonium (MA), $X=Cl^-$, $Br^-$, $I^-$) is the best candidate for material intrinsic property studies due to no grain boundary and high crystal quality than the film having a lot of grain boundary and surface defects. The representative crystallization methods are inverse temperature crystallization (ITC) and anti-solvent vapor assisted crystallization (AVC). Herein, we report bandgap modulated organic lead halide single crystals having a bandgap ranging from ~ 2.1 eV to ~ 3 eV with ITC and AVC methods. The bandgap modulation was achieved by controlling the solvents and chloride-to-bromide ratio. Structural, optical and compositional properties of prepared crystals were characterized. The results show that the crystals synthesized by the two crystallization methods have similar properties, but the halide ratios in the crystals synthesized by the AVC method are controlled more quantitatively than the crystals synthesized by ITC.

Synthesis of Al-Ni-Co-Y Bulk Metallic Glass fabricated by Spark Plasma Sintering (방전 플라즈마 소결법을 이용한 Al-Ni-Co-Y 벌크 비정질 합금의 제조)

  • Jeong Pyo Lee;Jin Kyu Lee
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.41-46
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    • 2023
  • In this study, an Al82Ni7Co3Y8 (at%) bulk metallic glass is fabricated using gas-atomized Al82Ni7Co3Y8 metallic glass powder and subsequent spark plasma sintering (SPS). The effect of powder size on the consolidation of bulk metallic glass is considered by dividing it into 5 ㎛ or less and 20-45 ㎛. The sintered Al82Ni7Co3Y8 bulk metallic glasses exhibit crystallization behavior and crystallization enthalpy similar to those of the Al82Ni7Co3Y8 powder with 5 ㎛ or less and it is confirmed that no crystallization occurred during the sintering process. From these results, we conclude that the Z-position-controlled spark plasma sintering process, using superplastic deformation by viscous flow in the supercooled liquid-phase region of amorphous powder, is an effective process for manufacturing bulk metallic glass.

Capacitance Enhancement and Evaluation of Gold-Deposited Carbon Nanotube Film Ion-Selective Electrode (금 입자 증착된 탄소나노튜브의 커패시턴스 증가 및 박막형 이온 선택성 전극으로서의 특성 평가)

  • Do Youn Kim;Hanbyeol Son;Hyo-Ryoung Lim
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.310-317
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    • 2023
  • Small-film-type ion sensors are garnering considerable interest in the fields of wearable healthcare and home-based monitoring systems. The performance of these sensors primarily relies on electrode capacitance, often employing nanocomposite materials composed of nano- and sub-micrometer particles. Traditional techniques for enhancing capacitance involve the creation of nanoparticles on film electrodes, which require cost-intensive and complex chemical synthesis processes, followed by additional coating optimization. In this study, we introduce a simple one-step electrochemical method for fabricating gold nanoparticles on a carbon nanotube (Au NP-CNT) electrode surface through cyclic voltammetry deposition. Furthermore, we assess the improvement in capacitance by distinguishing between the electrical double-layer capacitance and diffusion-controlled capacitance, thereby clarifying the principles underpinning the material design. The Au NP-CNT electrode maintains its stability and sensitivity for up to 50 d, signifying its potential for advanced ion sensing. Additionally, integration with a mobile wireless data system highlights the versatility of the sensor for health applications.

Dynamic intelligent control of composite buildings by using M-TMD and evolutionary algorithm

  • Chen, ZY;Meng, Yahui;Wang, Ruei-Yuan;Peng, Sheng-Hsiang;Yang, Yaoke;Chen, Timothy
    • Steel and Composite Structures
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    • v.42 no.5
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    • pp.591-598
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    • 2022
  • The article deals with the possibilities of vibration stimulation. Based on the stability analysis, a multi-scale approach with a modified whole-building model is implemented. The motion equation is configured for a controlled bridge with a MDOF (multiple dynamic degrees of freedom) Tuned Mass Damper (M-TMD) system, and a combination of welding, excitation, and control effects is used with its advanced packages and commercial software submodel. Because the design of high-performance and efficient structural systems has been of interest to practical engineers, systematic methods of structural and functional synthesis of control systems must be used in many applications. The smart method can be stabilized by properly controlling the high frequency injection limits. The simulation results illustrate that the multiple modeling method used is consistent with the accuracy and high computational efficiency. The M-TMD system, even with moderate reductions in critical pressure, can significantly suppress overall feedback on an unregulated design.

Silver nanoparticles in endodontics: recent developments and applications

  • Aysenur Oncu;Yan Huang ;Gulin Amasya ;Fatma Semra Sevimay;Kaan Orhan;Berkan Celikten
    • Restorative Dentistry and Endodontics
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    • v.46 no.3
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    • pp.38.1-38.13
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    • 2021
  • The elimination of endodontic biofilms and the maintenance of a leak-proof canal filling are key aspects of successful root canal treatment. Several materials have been introduced to treat endodontic disease, although treatment success is limited by the features of the biomaterials used. Silver nanoparticles (AgNPs) have been increasingly considered in dental applications, especially endodontics, due to their high antimicrobial activity. For the present study, an electronic search was conducted using MEDLINE (PubMed), the Cochrane Central Register of Controlled Trials (CENTRAL), Google Scholar, and EMBASE. This review provides insights into the unique characteristics of AgNPs, including their chemical, physical, and antimicrobial properties; limitations; and potential uses. Various studies involving different application methods of AgNPs were carefully examined. Based on previous clinical studies, the synthesis, means of obtaining, usage conditions, and potential cytotoxicity of AgNPs were evaluated. The findings indicate that AgNPs are effective antimicrobial agents for the elimination of endodontic biofilms.