• Title/Summary/Keyword: contact angles

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Water Contact Angles of Graphene Transferred by Wet and Dry Transfer Methods (전사 방법에 따른 그래핀의 물 접촉각 변화)

  • Yoon, Min-Ah;Kim, Chan;Jung, Hyun-June;Kim, Jae-Hyun;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.34 no.2
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    • pp.60-66
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    • 2018
  • Graphene is a monolayer of carbon atoms (approximately 0.34 nm), arranged in a honeycomb network. It has been hailed as a next-generation flexible and transparent material because it has high electrical and thermal conductivities, excellent mechanical properties, as well as flexible and transparent properties. The wettability of graphene alters its adhesion or surface energy, and it is therefore an important parameter influencing its application in the fabrication of next-generation flexible and transparent electronics. Studies on the wettability of graphene are numerous and various opinions exist. However, almost all of these studies use the wet transfer method to transfer the graphene. In this study, therefore, we investigated the effect of wet and dry transfer methods on water contact angles of graphene on a substrate. The contact angles of substrates vary depending on the type of substrate. It was found that after graphene is transferred to the substrate, regardless of transfer method, the graphene/substrate contact angle increases to a value. The contact angle of graphene transferred using the dry transfer method is higher than the contact angle of graphene transferred using wet transfer methods. The wet transferred graphene is affected by the poly(methyl methacrylate) (PMMA) residue and the polar surface of substrate. The dry transferred graphene is influenced by the conformal contact between graphene and substrate.

Characterization of Fluorocarbon Thin Films deposited by PECVD (PECVD로 증착된 불화 유기박막의 특성 평가)

  • 김준성;김태곤;박진구;신형재
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.2
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    • pp.31-36
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    • 2001
  • Teflon-like fluorocarbon thin film was deposited by using difluoromethane$(CH_2F_2$) added with Ar, $O_2$, and $CH_4$ on Si, $SiO_2$, TEOS, and Al substrate. The deposited thin film was characterized by static contact angles for measuring hydrophobicity in various additive gas ratio. temperature, and working pressure. In case of addition with Ar, the static contact angles decreased as additive gas ratio and power increased. But the static contact angles increased as working pressure increased. Specially, super-hydrophobic surface was obtained using the powder-like fluorocarbon thin film above 2 Torr. Added with $O_2$, the static contact angles decreased as the $O_2$ ratio and working pressure increased. And the static contact angles did not change in 100W, but hydrophilic surface was obtained at 200W. In case of addition of CE$_4$, static contact angles dramatically increased in $CH_4/CH_2F_2$ ratio 5. And continuous static contact angles obtained above ratio 5. As compare with previous experiments by thermal evaporation, the fluorocarbon thin film by plasma polymerization was obtained very low hysteresis. This results shows more homogenous surface by plasma polymerization than thermal evaporation process.

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The Effect of Water Contact Angles of the Fin Surfaces of the Fin-and-Tube Heat Exchangers on the Water Hold-up (핀-관 열교환기에서의 핀의 물 접촉각이 응축잔수량에 미치는 영향)

  • 신종민;이남교;한성주;하삼철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.6
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    • pp.490-496
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    • 2001
  • An experimental study on the behavior of the water hold-up by condensation of a fin-and-tube heat exchanger with regard to the surface characteristics, i.e., contact angle, was conducted. The static and dynamic contact angles were measured, and condensation experiments were conducted. Flow patterns on the fins with different surface characteristics were visualized. Results showed that the static contact angle is proportional to the dynamic contact angle within the range of this study. The water hold-up of the heat exchanger increases as the static or dynamic contact angle of its surfaces increases. Existence of transition of flow patterns was found as the static or dynamic angle increase. Due to the transition in the flow patterns, changes in the gradient of the water hold-up is occurred around the static angle of 8$0^{\circ}C$.

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Two-dimensional Numerical Simulation of the Contact Angle and the Bubble Necking Using the Two Phase Lattice Boltzmann Method (2상 격자 볼츠만 방법을 이용한 접촉각과 Bubble Necking 2차원 수치 모사)

  • Ryu, Seung-Yeob;Kim, Jae-Yong;Ko, Sung-Ho
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.3
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    • pp.10-17
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    • 2011
  • Free energy based lattice Boltzmann method (LBM) has been used to simulate the contact angle and the bubble necking with large density ratio. LBM with the proper contact angle model is able to reduce the spurious currents and eliminate the singularity in the contact lines. The numerical results of the contact angles are satisfied with the Youngs law. For bubble necking flows, simulations are executed for various viscosities and contact angles. The phenomena of the bubble necking are simulated successfully and the subsequent results are presented. The present method is also applicable to the nucleate boiling flows.

Kinematical Investigation and Geometry Modeling of the Perfect Involute Bevel Gearsets (완전한 인볼류트 베벨기어쌍의 기구학적 고찰 및 형상 모형화)

  • Park, N.G.
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.5
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    • pp.46-56
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    • 1995
  • As demands on the precision bevel gears are increased in the related industry, the exact kinematical investigations of a pair of spherical involute bevel gears are required for the computer aided design. The exact angular velocity ratio based on the characteristics of the spherical involute tooth is derived and verified from the relationship between rotational angles. Elementary kinematics of the gearsets is investigated by applying the transformation of the coordinate systems. The tooth contact lines based on logarithmic tooth-wise curve are examines in three dimentional space. Contact ratio is formulated and simulated according to the system parameters such as shaft angles, pressure angle, and spiral angles. The condition of teeth interference is dervied and the critical numbers of gear teeth are calculated. The whole surface geometry of a spiral bevel gearsets are discretized and visualized by a computer graphic tool.

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Conditions for Moire Free Contact-Type 3 Dimensional Displays

  • Song, Yoon-Chul;Saveljev, Vladimir V.;Son, Jung-Young;Yeom, Seok-Won;Vashpanov, Yu. A.
    • Journal of the Optical Society of Korea
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    • v.12 no.2
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    • pp.93-97
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    • 2008
  • The superposing angle of the viewing zone forming optics and the display panel in the contact type 3 dimensional imaging systems for minimizing $moir{\acute{e}}s$ is found for a rectangular shape pixel with different aspect ratios. The angles are $26.2609^{\circ}$ for square shape pixels and $13.9858^{\circ}$ for the rectangular with aspect ratio 2. These angles result in the $moir{\acute{e}}s$ with the smallest period for the respective aspect ratio. The effectiveness of the angles is also experimentally demonstrated.

Studies on the Surface Properties of PMMA after Accelerated Weathering

  • Kwon, Young Bum;Ha, Jin Uk;Hwang, Ye Jin;Oh, Jeong Seok
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.350-354
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    • 2016
  • The surface properties of poly(methyl methacrylate) (PMMA) were investigated after accelerated weathering. Glossinesses, contact angles, surface free energies, thermal stability, and mechanical properties were investigated. The glossiness of the weathered PMMA was decreased with increasing exposure time. Contact angles and surface free energies were not overtly changed because the amount of oxygen on the surface was remained. PMMA was compounded with anti-block and antistatic agents using a co-rotating twin screw extruder to improve the durability. The PMMA composites showed better glossinesses after accelerated weathering while maintaining the contact angles, surface energy, thermal stability, and mechanical properties without significant changes.

Experimental and numerical analyses on determination of indirect (splitting) tensile strength of cemented paste backfill materials under different loading apparatus

  • Komurlu, Eren;Kesimal, Ayhan;Demir, Serhat
    • Geomechanics and Engineering
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    • v.10 no.6
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    • pp.775-791
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    • 2016
  • The indirect tensile strengths (ITSs) of different cemented paste backfill mixes with different curing times were determined by considering crack initiation and fracture toughness concepts under different loading conditions of steel loading arcs with various contact angles, flat platens and the standard Brazilian test jaw. Because contact area of the ITS test discs developes rapidly and varies in accordance with the deformability, ITSs of curing materials were not found convenient to determine under the loading apparatus with indefinite contact angle. ITS values increasing with an increase in contact angle can be measured to be excessively high because of the high contact angles resulted from the deformable characteristics of the soft paste backfill materials. As a result of the change of deformation characteristics with the change of curing time, discs have different contact conditions causing an important disadvantage to reflect the strength change due to the curing reactions. In addition to the experimental study, finite element analyses were performed on several types of disc models under various loading conditions. As a result, a comparison between all loading conditions was made to determine the best ITSs of the cemented paste backfill materials. Both experimental and numerical analyses concluded that loading arcs with definite contact angles gives better results than those obtained with the other loading apparatus without a definite contact angle. Loading arcs with the contact angle of $15^{\circ}$ was found the most convenient loading apparatus for the typical cemented paste backfill materials, although it should be used carefully considering the failure cracks for a valid test.

Numerical Study of Droplet Motion in a Microchannel with defferent contact angles (접촉각에 따른 마이크로채널 내에서의 액적 거동에 대한 수치적 연구)

  • Choi, Ji-Young;Son, Gi-Hun
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.656-657
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    • 2008
  • The droplet dynamics in a hydrophilic/hydrophobic microchannel, which is applicable to a typical proton exchange membrane fuel cell (PEMFC), is studied numerically by solving the equations governing conservation of mass and momentum. The liquid-gas interface or droplet shape is determined by a level set method which is modified to treat contact angles. The matching conditions at the interface are accurately imposed by incorporating the ghost fluid approach based on a sharp-interface representation. The effects of contact angle, inlet flow velocity, droplet size and side wall on the droplet motion are investigated parametrically. Based on the numerical results, the droplet dynamics including the sliding and detachment of droplets is found to depend significantly on the contact angle. Also, a droplet removal process is demonstrated on the combination of hydrophilic and hydrophobic surfaces.

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A Study for the Water Droplet on a Stripe-patterned Surface (주기적 줄무늬 구조물 위의 물 액적에 관한 연구)

  • Choi, Ho-Jin;Hong, Seung-Do;Ha, Man-Yeong;Yoon, Hyun-Sik
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.2
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    • pp.64-69
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    • 2010
  • We investigated the variation in contact angle of a nano-sized water droplet on a nano stripe-patterned surface using molecular dynamics simulation. By changing the height and width of the stripe pillar, and the gap width of the stripes, we observed the contact angle of water droplet in equilibrium. When the surface energies were 0.1 and 0.3 kcal/mol, the calculated contact angles were in good agreement with the Cassie and Baxter equation. However, when the surface energy is 0.5 kcal/mol, the contact angles are observed to be perturbed along the Cassie and Baxter equation.