• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.95-102
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• 2015

In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.1
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• pp.25-39
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• 2022

This study was conducted to evaluate the manufacturing process of non-sintered cement for the safe containment of radioactive waste using low level or ultra-low level radioactive waste soil generated from nuclear-decommissioning facilities, clay minerals, and blast furnace slag (BFS) as an industrial by-product recycling and to characterize the products using mineralogical and morphological analyses. A stepwise approach was used: (1) measuring properties of source materials (reactants), such as waste soil, clay minerals, and BFS, (2) manufacturing the non-sintered cement for the containment of radioactive waste using source materials and deducing the optimal mixing ratio of solidifying and adjusting agents, and (3) conducting mineralogical and morphological analyses of products from the hydration reactions of manufactured non-sintered cement solidifier (NSCS) containing waste concrete generated from nuclear-decommissioning facilities. The analytical results of NSCS using waste soil and clay minerals confirmed none of the hydration products, but calcium silicate (CSH) and ettringite were examined as hydration products in the case of using BFS. The compressive strength of NSCS manufactured with the optimum mixing ratio and using waste soil and clay minerals was 3 MPa after the 28-day curing period, and it was not satisfied with the acceptance criteria (3.44 MPa) for being brought in disposal sites. However, the compressive strength of NSCS using BFS was estimated to be satisfied with the acceptance criteria, despite manufacturing conditions, and it was maximized to 27 MPa at the optimal mixing ratio. The results indicate that the most relevant NSCS for the safe containment of radioactive waste can be manufactured using BFS as solidifying agent and using waste soil and clay minerals as adsorbents for radioactive nuclides.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.415-424
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• 2017

The purpose of this study is to investigate the effect of sulfate (${SO_4}^{2-}$) and magnesium ($Mg^{2+}$) ions on sulfate resistance of Alkali-activated materials using Fly ash and Ground granulated blast furnace slag (GGBFS). In this research, 30%, 50% and 100% of GGBFS was replaced by sodium silicate modules ($Ms(SiO_2/Na_2O)$, molar ratio, 1.0, 1.5 and 2.0). In order to investigate the effects of $Mg^{2+}$ and ${SO_4}^{2-}$, compression strength, weight change, lengh expansion of the samples were measured in 10% sodium sulfate ($Na_2SO_4$), 10%, 5% and 2.5% magnesium sulfate ($MgSO_4$), 10% magnesium nitrate ($Mg(NO_3)_2$), 10% [magnesium chloride ($MgCl_2$) + sodium sulfate ($Na_2SO_4$)] and 10% [magnesium nitrate $(Mg(NO_3)_2$ + sodium sulfate ($Na_2SO_4$)] solution, respectively and X-ray diffraction analysis was conducted after each experiment. As a result, when $Mg^{2+}$ and ${SO_4}^{2-}$ coexist, degradation of compressive strength and expansion of the sample were caused by sulfate erosion. It was found that the reaction of $Mg^{2+}$ with Calcium Silicate Hydrate (C-S-H) occurred and $Ca^{2+}$ was produced. Then the Gypsum ($CaSO_4{\cdot}2H_2O$) was formed due to reaction between $Ca^{2+}$ and ${SO_4}^{2-}$, and also Magnesium hydroxide ($Mg(OH)_2$, Brucite) was produced by the reaction between $Mg^{2+}$ and $OH^-$.

• Resources Recycling
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• v.20 no.1
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• pp.37-45
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• 2011

This study was conducted to recycle flotation tailings as non-sintered construction materials considering the economic and eco-friendly treatments. The particle size distribution( median $220\;{\mu}m$) of flotation tailings from Soon-shin mine was confirmed to be larger than that(median $140\;{\mu}m$) of tailings from Sam-kwang mine. Thus we investigated the properties of non-sintered eco-brick producted with the tailings from Sam-kwang mine and non-sintered water permeable block producted with the tailings from Soon-shin mine. Compressive strength of non-sintered water permeable block which was made with less than 25 wt% of tailings from Soon-shin mine was met with products class(over 14.70 MPa) of water permeable concrete(EL 245) from KEITL. Meanwhile, the coefficient of its permeability wasn't met with the products class( over $1.0{\times}10^{-2}\;cm/sec$). The properties of non-sintered eco-brick with less than 40 wt% of tailings from Sam-kwang mine were satisfied with third class in sintered clay brick products standard(KS L 4201). The non-sintered eco-brick as a result of leaching test on heavy metals by KSLT was verified to be environmentally stabile.

• Journal of Conservation Science
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• v.28 no.3
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• pp.235-245
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• 2012

Nondestructive deterioration diagnosis has been carried out for the former ore dressing plant of the Yongwha mine in Yeongyang (Registered Cultural Property No. 255). Deterioration rates about organic contaminant and soil of the upper part (7 to 13 layer) indicate higher than the lower part (1 to 6 layer) of the ore dressing plants. By contrast, deterioration rates such as crack, break out and discoloration of the lower part indicate very higher than the upper part. It is estimated that the plants of the lower part that mechanical and chemical process had been done for flotation were damaged severely by physicochemical weathering with reaction of concrete and chemical solution. As results of ultrasonic velocity measurement, average p-wave velocity of plants were measured 2,462m/s (compressive strength $529kgf/cm^2$). As for the analytical results of surface contaminants and soil compositions using P-XRF, they were identical with major elements (Cu, Zn, Pb, Fe and As) of ore minerals from the Yongwha mine. Therefore, the ore dressing plant should be treated by phytoremediation with conservation because heavy metals could impinged upon plants and natural environment.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.33 no.4
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• pp.263-270
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• 2020

This study evaluates the structural behavior of connected long-span beams applied for excavation in urban areas with a narrow street. Generally, the reliability of the connection is reduced owing to the defect of the upper flange in the connection. An improved connection part was developed to complement the defects in the connected long-span beam. A finite element analysis based on a commercial program, ABAQUS, was employed to evaluate the behavior of the improved connection part. A numerical analysis model was proposed to analyze the high-strength bolt connection and the composite behavior of steel and concrete applied to the improved connection. The suitability of the proposed numerical analysis was verified by comparing the experimental and numerical analysis results of the references. Using the proposed numerical analysis method, the improved and general connections were analyzed and compared with each other. The stress distribution and elastic-plastic behavior of the long-span beam were analyzed numerically. The analysis confirmed that 25% of the compressive stress was improved, resulting in the improvement of structural safety and performance.

• Korean Journal of Construction Engineering and Management
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• v.11 no.6
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• pp.111-121
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• 2010

As the customer's interest for sidewalk block in the street or apartment complex is increasing, the materials of block which had been a concrete block exclusively are varied to clay paver, native rock and wood etc. Especially, the sales volume of clay paver which is environment-friendly and ergonomic is dramatically increasing every year with two digits growth rate, however, many problems like "Edge Cracking" "Freezing Breakage" "Bending Breakage" "Joint Gap" are happening frequently within a couple of hours after installation due to the durabilities. Because of the characteristics of Ceramic products, clay pavers are very easy to be broken when they are bumped against each other. In addition, they are relatively fragile by a freezing expansion breakage when exposed to water due to hydrophilic property as well as the intensity and absorptance of the products are varied with small difference from the production process such as production equipment and process control. Therefore, it costs a lot of money to repair the breakdown unless production and installation is carried out according to the strict criteria of the quality control. In this study, the symptoms of breakdown frequently happened in clay paver are classified by each type and finally the solution for this problem in the production of brick, installation and criteria of quality control through compressive strength and absorptance test is suggested.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.1
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• pp.81-94
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• 2010

This paper deals with the fracture simulation of UHPFRC girder with the interface type model. Based on the existing numerical simulation of quasi-brittle fracture in normal strength concrete, constitutive modeling for UHPFRC I-girder has been improved by including a tensile hardening at the failure surface. The finite element formulation is based on a triangular unit, constructed from constant strain triangles, with nodes along its sides and neither at the vertex nor the center of the unit. Fracture is simulated through a hardening/softening fracture constitutive law in tension, a softening fracture constitutive law in shear as well as in compression at the boundary nodes, with the material within the triangular unit remaining linear elastic. LCP is used to formulate the path-dependent hardening-softening behavior in non-holonomic rate form and a mathematical programming algorithm is employed to solve the LCP. The piece-wise linear inelastic yielding-failure/failure surface is modeled with two compressive caps, two Mohr-Coulomb failure surfaces, a tensile yielding surface and a tensile failure surface. The comparison between test results and numerical results indicates this method effectively simulates the deformation and failure of specimen.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.6
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• pp.195-200
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• 2011

KS F 2782 (for shotcrete accelerators) standard cross-section of tunnel construction or repair is a reinforcement used in the field of shotcrete accelerators as a criterion in assessing shotcrete performance. Thus, KS F 2782 by standard accelerator will determine the nature of the product of concrete accelerators that will be used to record variations in the product roles, through determination of the quality of the experimental method to identify only the quality of the many variables that exist. This evaluation standard has so far distinguished accelerator products in indoor experiments that do not meet quality standards but were mostly for an on-site accelerator mixed with the shotcrete after being quite satisfied with the level of quality in a certain number of products. This observation is derived from the results of an indoor experiment considered to verify whether the site is suitable for indoor experiments, and whether its actual location in the city is relevant to the accelerator quality, to find a way to test if it fits. This study centers on the material conditions of the shotcrete accelerator and a variety of experimental results, and used the Gilmore needle to compare the compressive strength and KS F 2782 specification of the accelerator as a means to ensure product quality conformity analysis and for further research experiments. In conclusion, a portion of KS F 2782 standard that fixes the problems that can be resolved from the ground up as a whole is not a review for the domestic reality. As an indoor experiment to ensure uniformity in the field when applied in a sufficient correlation, complement must be in place.

• Polymer(Korea)
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• v.35 no.4
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• pp.363-369
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• 2011

To study the effect of incorporation of a surface crosslinking layer on a crosslinked poly (sodium acrylate) (cPSA) absorbent with ethylene glycol dimethacrylate CEGDMA), we synthesized several surface crosslinked cPSAs with EGDMA by an inverse emulsion polymerization method to delay the absorption of excess water in concrete, Liquid paraffin was used as a continuous phase. cPSA was synthesized with acrylic acid (AA) neutralized with aqueous 8 M sodium hydroxide solution as a monomer, N,N-methylene bisacrylamide (MBA) as crosslinking agent and ammonium persulfate (APS) and sodium metabisulfite (SMBS) as a redox initiator system by inverse emulsion polymerization. FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with cPSA and cPSA-EGDMAs. The swelling ratios of synthesized absorbents were evaluated from the absorption in deionized water, cement saturated aqueous solution and aqueous solution of calcium hydroxide (pH 12). Equilibrium swelling times for cPSA and surface crosslinked cPSA with EGDMA were 2 and 3 hrs, respectively. We also observed an increase in setting time of the cement and an increase in the compressive strength of mortar by addition of the synthesized cPSA-EGDMA.