• 제목/요약/키워드: compound unit

검색결과 275건 처리시간 0.032초

Importance of the Role of Flexible Spacers in Liquid Crystal Formation by Bent Dimesogenic and Star-Shaped Trimesogenic Compounds

  • Jung-Il Jin;Bong Young Chung;Jae-Kon Choi;Byung-Wook Jo
    • Bulletin of the Korean Chemical Society
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    • 제12권2호
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    • pp.189-193
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    • 1991
  • A series of compounds that contain varying numbers of the same mesogenic structure, biphenyl p-oxybenzoate unit, attached through a pentamethylene spacer to the central benzene ring were prepared and their liquid crystallinity was studied. The mesophase-forming ability of a dimesogenic compound was found to be greatly dependent on whether or not its geometric shape is linear and also on the existence of the pentamethylene spacer between the mesogen and the central core. The presence of the spacer enhanced the capacity of a compound to form a mesophase. In the trimesogenic compound the mesogens were linked to the 1,3,5-positions of the core benzene ring through the spacer. The compound was found to be enantiotropically nematic.

A New Diarylethene with Donor-acceptor Group for Reversible Photo-induced Electrochemical Switching

  • Kim, Eun-Kyoung;Kim, Mi-Young;Kim, Kyong-Tae
    • Bulletin of the Korean Chemical Society
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    • 제29권4호
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    • pp.827-832
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    • 2008
  • A new diarylethene compound with donor and acceptor substituent was synthesized from 2,3-bis(2-methylbenzo[b]thiophene-3-yl)hexafluorocyclopentene (BTF) over 5 steps. The donor-acceptor structured BTF compound (TBTFE) showed spectral change to a longer wavelength through photochromism with a high cyclization quantum yield (0.56). The 3,4-ethylenedioxythiophene (T) and carboethoxy (E) groups directly connected to BTF unit promoted electrical change accompanied with the photoisomerization of the BTF unit. Photo-induced electrical switching was achieved from a photocell containing TBTFE doped polymer film, which showed reversible and stable current change over repeated cycles by the alternative UV/Vis irradiation, as estimated by the I-V plot.

PARABOLIC MARCINKIEWICZ INTEGRALS ASSOCIATED TO POLYNOMIALS COMPOUND CURVES AND EXTRAPOLATION

  • Liu, Feng;Zhang, Daiqing
    • 대한수학회보
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    • 제52권3호
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    • pp.771-788
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    • 2015
  • In this note we consider the parametric Marcinkiewicz integrals with mixed homogeneity along polynomials compound curves. Under the rather weakened size conditions on the integral kernels both on the unit sphere and in the radial direction, the $L^p$ bounds of such operators are given by an extrapolation argument. Some previous results are greatly extended and improved.

수지매트를 이용한 바닥타일 건식공법 시스템에 관한 연구 (The Study on the Dry Floor Tile Unit System used Resin Mat)

  • 김성식;임남기;정병훈;정재영;정상진
    • 한국건축시공학회지
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    • 제1권2호
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    • pp.185-190
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    • 2001
  • The purpose of this study is the development of practical Dry floor tile unit method that settle the defect of a wet method and designed for resin mat. With use of PE resin which is confirmed the basic property, it is developed that resin mat, joint-sealing compound with fixed form and space management to Dry floor tile unit method. The result of this study is below. 1) To acquire above the 4kgf/$\textrm{cm}^2$ - construction specification criterion, the bonding space that between resin mat and tile has to occupy the 50% of resin mat module space(10,000$\textrm{cm}^2$). 2) Criteria of bonding part plane is below. simpleness of metal form. productivity, uniform quality after injection molding cooling, easy cutting for remain space management, adhesive property, construction ability, transformation of a severed piece under pressure and so on. 3) To get the shape that could protect the interfacial breakdown, it is designed that resin mat and tile are unified after the bond input. 4) Adapted joint-sealing compound is the material of urethane kinds wedge form. Resin mat has the water passageway that could drain the water. 5) To manage the severed piece of tile, the resin mat is likely to divide the half and the quarter and the plastic drainage is developed in the severed piece.

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Noun Sense Identification of Korean Nominal Compounds Based on Sentential Form Recovery

  • Yang, Seong-Il;Seo, Young-Ae;Kim, Young-Kil;Ra, Dong-Yul
    • ETRI Journal
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    • 제32권5호
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    • pp.740-749
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    • 2010
  • In a machine translation system, word sense disambiguation has an essential role in the proper translation of words when the target word can be translated differently depending on the context. Previous research on sense identification has mostly focused on adjacent words as context information. Therefore, in the case of nominal compounds, sense tagging of unit nouns mainly depended on other nouns surrounding the target word. In this paper, we present a practical method for the sense tagging of Korean unit nouns in a nominal compound. To overcome the weakness of traditional methods regarding the data sparseness problem, the proposed method adopts complement-predicate relation knowledge that was constructed for machine translation systems. Our method is based on a sentential form recovery technique, which recognizes grammatical relationships between unit nouns. This technique makes use of the characteristics of Korean predicative nouns. To show that our method is effective on text in general domains, the experiments were performed on a test set randomly extracted from article titles in various newspaper sections.

산업폐수에 대한 이화학적 분석과 물벼룩 생태독성의 비교 (Comparison between Ecotoxicity using Daphnia magna and Physiochemical Analyses of Industrial Effluent)

  • 이선희;이학성
    • 한국환경과학회지
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    • 제23권7호
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    • pp.1269-1275
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    • 2014
  • Ecotoxicity assessments with the physiochemical water quality items and the bioassay test using Daphnia magna were conducted for 18 selected effluents of 6 industrial types (metal processing, petroleum refining, synthetic textile manufacturing, plating, alcohol beverage manufacturing, inorganic compound manufacturing) being detected toxicity from industrial effluent in Ulsan city, and the interrelationship between total toxic unit (${\Sigma}TU$) and concentrations of Water Quality Conservation Act in Korea were investigated. The average toxic unit(TU) of effluents for 6 industrial types displayed the following ascending order: petroleum refining (0.2) < synthetic textile manufacturing (0.6) < alcohol beverage manufacturing (0.9) < metal processing (1.3) ${\leq}$ inorganic compound manufacturing (1.3) < plating (3.0). These values were less than effluent permission standard. Based on the result of substances causing ecotoxicity, the correlation analysis was not easy because most of heavy metals were not detected or were less than effluent permission standard. Toxicological assessment of industrial effluent was suitable for the evaluation of the mixture toxicity for pollutant. The whole effluent toxicity test using a variety of species was needed for the evaluation of industrial wastewater.

인간동력항공기의 항력저감 및 동력증강 설계 (Drag Reduced and Power Increased Design of Human Powered Aircraft)

  • 신병준;조영희;김학윤
    • 항공우주기술
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    • 제12권2호
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    • pp.221-229
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    • 2013
  • 인간동력항공기의 개념을 분석하여 최고 성능의 인간동력항공기 개발을 위하여 필요시되는 동력증강 및 항력감소 설계에 대하여 연구하였다. 2012년 인간동력항공기 시범경진대회에 출전하기 위하여 유선형 동체 채택에 의한 항력저감 및 팔과 다리 힘 동시사용에 의한 동력증강개념을 제시하였으며 개념 확인을 위하여 동체의 전산해석 및 동력장치 설계를 수행하였다. 유선형 동체의 효과를 최대한 이용하기 위해서는 동체형상 설계가 중요하며 팔의 동력을 이용하기 위해서는 조종 장치의 설계가 중요하고 비행실험이 요구된다.

근위축성 측삭 경화증에서의 Statistical Motor Unit Number Estimate 재연성: Size-and Number-Weighted Modifications간의 비교 (Reproducibility of Statistical Motor Unit Number Estimate in Amyotrophic Lateral Sclerosis: Comparisons between Size-and Number-Weighted Modifications)

  • 권오현;이광우
    • Annals of Clinical Neurophysiology
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    • 제5권1호
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    • pp.27-33
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    • 2003
  • Background: Motor unit number estimation (MUNE) can directly assess motor neuron populations in muscle and quantify the degree of physiologic and/or pathologic motor neuron degeneration. A high degree of reproducibility and reliability is required from a good quantitative tool. MUNE, in various ways, is being increasingly applied clinically and statistical MUNE has several advantages over alternative techniques. Nevertheless, the optimal method of applying statistical MUNE to improve reproducibility has not been established. Methods: We performed statistical MUNE by selecting the most compensated compound muscle action potential (CMAP) area as a test area and modified the results obtained by weighted mean surface-recorded motor unit potential (SMUP). Results: MUNE measures in amyotrophic lateral sclerosis (ALS) patients showed better reproducibility with sizeweighted modification. Conclusions: We suggest size-weighted MUNE testing of "neurogenically compensated"CMAP areas present an optimal method for statistical MUNE in ALS patients.

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Two Flavonoid-Based Compounds from Murraya paniculata as Novel Human Carbonic Anhydrase Isozyme II Inhibitors Detected by a Resazurin Yeast-Based Assay

  • Sangkaew, Anyaporn;Samritsakulchai, Nawara;Sanachai, Kamonpan;Rungrotmongkol, Thanyada;Chavasiri, Warinthorn;Yompakdee, Chulee
    • Journal of Microbiology and Biotechnology
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    • 제30권4호
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    • pp.552-560
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    • 2020
  • Human carbonic anhydrase (CA) isozyme II has been used as protein target for disorder treatment including glaucoma. Current clinically used sulfonamide-based CA inhibitors can induce side effects, and so alternatives are required. This study aimed to investigate a natural CA inhibitor from Murraya paniculata. The previously developed yeast-based assay was used to screen 14 compounds isolated from M. paniculata and identified by NMR analysis for anti-human CA isozyme II (hCAII) activity. Cytotoxicity of the compounds was also tested using the same yeast-based assay but in a different cultivation condition. Two flavonoid candidate compounds, 5, 6, 7, 8, 3', 4', 5'-heptamethoxyflavone (4) and 3, 5, 7, 8, 3', 4', 5'-heptamethoxyflavone (9), showed potent inhibitory activity against hCAII with a minimal effective concentration of 10.8 and 21.5 μM, respectively, while they both exhibited no cytotoxic effect, even at the highest concentration tested (170 μM). The results from an in vitro esterase assay of the two candidates confirmed their hCAII inhibitory activity with IC50 values of 24.0 and 34.3 μM, respectively. To investigate the potential inhibition mechanism of compound 4, in silico molecular docking was performed using the FlexX and SwissDock software. This revealed that compound 4 coordinated with the Zn2+ ion in the hCAII active site through its methoxy oxygen at a distance of 1.60 Å (FlexX) or 2.29 Å (SwissDock). The interaction energy of compound 4 with hCAII was -13.36 kcal/mol. Thus, compound 4 is a potent novel flavonoid-based hCAII inhibitor and may be useful for further anti-CAII design and development.

Synthesis and Characterization of Organosilane Electrolyte Containing Silphenylene

  • Kim, Jongjun;Sohn, Honglae
    • 통합자연과학논문집
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    • 제10권4호
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    • pp.197-201
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    • 2017
  • Organosilicon compound containing silphenylene unit as an eletrolyte for the application of lithium-ion batteries was synthesized by hydrosilylation method between 1,4-bis(dimethylsilylhydro)benzene and 3-[2-(2-methoxyethoxy)ethoxy]-1-propene. As-prepared new organosilicon compounds containing spacer such as propyl group with ethylene glycol are synthesized to improve thermal stability and to promote conductivity. The products are characterized by spectroscopic analysis.