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http://dx.doi.org/10.5012/bkcs.2008.29.4.827

A New Diarylethene with Donor-acceptor Group for Reversible Photo-induced Electrochemical Switching  

Kim, Eun-Kyoung (Department of Chemical Engineering, Yonsei University)
Kim, Mi-Young (School of Chemistry and Molecular Engineering, Seoul National University)
Kim, Kyong-Tae (School of Chemistry and Molecular Engineering, Seoul National University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.4, 2008 , pp. 827-832 More about this Journal
Abstract
A new diarylethene compound with donor and acceptor substituent was synthesized from 2,3-bis(2-methylbenzo[b]thiophene-3-yl)hexafluorocyclopentene (BTF) over 5 steps. The donor-acceptor structured BTF compound (TBTFE) showed spectral change to a longer wavelength through photochromism with a high cyclization quantum yield (0.56). The 3,4-ethylenedioxythiophene (T) and carboethoxy (E) groups directly connected to BTF unit promoted electrical change accompanied with the photoisomerization of the BTF unit. Photo-induced electrical switching was achieved from a photocell containing TBTFE doped polymer film, which showed reversible and stable current change over repeated cycles by the alternative UV/Vis irradiation, as estimated by the I-V plot.
Keywords
Photochromism; Diarylethene; Ring cyclization; Ring opening; Photo-electrical switching
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