Browse > Article
http://dx.doi.org/10.13160/ricns.2017.10.4.197

Synthesis and Characterization of Organosilane Electrolyte Containing Silphenylene  

Kim, Jongjun (Department of Chemistry, Chosun University)
Sohn, Honglae (Department of Chemistry, Chosun University)
Publication Information
Journal of Integrative Natural Science / v.10, no.4, 2017 , pp. 197-201 More about this Journal
Abstract
Organosilicon compound containing silphenylene unit as an eletrolyte for the application of lithium-ion batteries was synthesized by hydrosilylation method between 1,4-bis(dimethylsilylhydro)benzene and 3-[2-(2-methoxyethoxy)ethoxy]-1-propene. As-prepared new organosilicon compounds containing spacer such as propyl group with ethylene glycol are synthesized to improve thermal stability and to promote conductivity. The products are characterized by spectroscopic analysis.
Keywords
Silane; Silphenylene Unit; Electrolyte; Lithium Ion Battery;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 S. S. Zhang, "A review on electrolyte additives for lithium-ion batteries", J. Power Sources, Vol. 162, pp. 1379-1394, 2006   DOI
2 B. Scrosati, " History of lithium batteries", J. Solid State Electrochem.,Vol. 15, pp. 1623-1630, 2011.   DOI
3 M. Lewin, in: M. Le Bras, G. Camino, S. Bourbigot, R. Delobel (Eds.), "Fire Retardancy of Polymers: The Use of Intumescence", Tyne and Wear: Athenaeum Press, p. 3, 1998.
4 S. L. Levan and J. E. Winandy, "Effects of Fire Retardant Treatments on Wood Strength: A Review", Word Fiber Science, Vol. 22, pp. 113-131, 1990.
5 X. Wang, E. Yasukawa, and S. Kasuya, "Nonflammable trimethyl phosphate solvent-containing electrolytes for lithium-ion batteries: I. fundamental properties", J. Electrochem. Soc., Vol. 148, pp. A1058- A1065, 2001.   DOI
6 X. Wang, E. Yasukawa, and S. Kasuya, "Nonflammable trimethyl phosphate solvent-containing electrolytes for lithium-ion batteries: II. the use of an amorphous carbon anode", J. Electrochem. Soc., Vol. 148, pp. A1066-A1071, 2001.   DOI
7 Y. E. Hyung, D. R. Vissers, and K. Amine, "Flameretardant additives for lithium-ion batteries", J. Power Sources, Vol. 119-121, pp. 383-387, 2003.   DOI
8 M. S. Ding, K. Xu, and T. R. Jow, "Effects of tris(2,2,2-trifluoroethyl) phosphate as a flameretarding cosolvent on physicochemical properties of electrolytes of LiPF6 in EC-PC-EMC of 3:3:4 weight ratios", J. Electrochem. Soc., Vol. 149, pp. A1489-A1498, 2002.   DOI
9 Q. Wang, J. Sun, X. Yao, and C. Chen, "4-isopropyl phenyl diphenyl phosphate as flame-retardant additive for lithium-ion battery electrolyte", Electrochemical and Solid-State Letters, Vol. 8, pp. A467- A470, 2005.   DOI
10 X. L. Yao, S. Xie, C. H. Chen, Q. S. Wang, J. H. Sun, Y. L. Li, and S. X. Lu, "Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries", J. Power Sources, Vol. 144, pp. 170-175, 2005.   DOI
11 K. Xu, S. S. Zhang, J. L. Allen, and T. R. Jow, "Evaluation of fluorinated alkyl phosphates as flame retardants in electrolytes for Li-ion batteries: II. performance in cell", J. Electrochem. Soc., Vol. 150 pp. A170-A175, 2003.   DOI
12 K. Xu, M. S. Ding, S. S. Zhang, J. L. Allen, and T. R. Jow, "Evaluation of fluorinated alkyl phosphates as flame retardants in electrolytes for Li-ion batteries: I. physical and electrochemical properties", J. Electrochem. Soc., Vol. 150, pp. A161-A169, 2003.   DOI
13 U. Lauter, S. W. Kantor, K. Schmidt-Rohr, and W. J. MacKnight, "Vinyl-substituted silphenylene siloxane copolymers: novel high-temperature elastomers", Macromolecular, Vol. 32, pp. 3426-3431, 1999.   DOI
14 M. S. Ding and T. R. Jow, "Physicochemical properties of non-aqueous solvents and electrolytes for lithium battery applications", ECS Trans., Vol. 16, pp. 183-214, 2009.
15 N. A. A. Rossi and R. West, "Silicon-containing liquid polymer electrolytes for application in lithium ion batteries", Polym. Int., Vol. 58, pp. 267-272, 2009.
16 K. Amine, Q. Wang, D. R. Vissers, Z. Zhang, N. A. Rossi, and R. West, "Novel silane compounds as electrolyte solvents for Li-ion batteries", Electrochem. Commun., Vol. 8, pp. 429-433, 2006.   DOI
17 K. Koh and H. Sohn, "New synthetic method of perfluoro-silanes for the stable electrolyte of lithium ion battery application", J. Chosun Natural Sci., Vol. 10, pp. 171-174, 2017.
18 X. Zuo, J. Chen, X. Zhao, S. Yang, and L. Fan, "Synthesis and characterization of siloxane resins derived from silphenylene-siloxane copolymers bearing benzocyclobutene pendant groups", J. Poly. Sci. A Polym. Chem., Vol. 46, pp. 7868-7881, 2008   DOI
19 X. Yang X. Zhao, Y. Zhang, W. Huang, and Y. Yu, "Synthesis and properties of silphenylene-containing epoxy resins with high UV-stability, Journal of Macromolecualr Science Part A: Pure and Applied Chemistry, Vol. 48, pp. 692-700, 2011.   DOI
20 M. Sajjad, B. Feichtenschlager, S. Pabisch, J. Svehla, T. Koch, S. Seidler, H. Peterlik, and G. Kickelbick, Study of the effect of the concentration, size and surface chemistry of zirconia and silica nanoparticle fillers within an epoxy resin on the bulk properties of the resulting nanocomposites", Polym. Int., Vol. 61, pp. 274-285, 2012.   DOI