• 제목/요약/키워드: compositional characteristics

검색결과 212건 처리시간 0.02초

실리케이트 광물을 이용한 내열충격성 LAS계 세라믹스의 제조에 관한 연구 (III) Eucryptite와 Spondumene 소결특성 (The Study on Fabrication of LAS System Ceramics for Thermal Shock Resistance from Silicate Minerals (III) Sintering Characteristics of Eucryptite and Spodumene)

  • 박한수;조경식;문종수
    • 한국세라믹학회지
    • /
    • 제32권2호
    • /
    • pp.171-182
    • /
    • 1995
  • Five eucryptite and ten spodumene compositional powders were syntehsized from three sillimanite group, two kaolin group, and five pyrophyllite group silicate minerals. Those powders were isotatically pressed and fired at 1200~135$0^{\circ}C$ for 2 hrs, and then the sintered bodies were characterized. Silicate minerals with molar ratio of Al2O3 to SiO2 correspond to those of eucryptite and spodumene are kaolin and pyrophyllite group silicate minerals, respectively. Sintering characteristics of eucryptite from kaolin group and spodumene from pyrophyllite group mineral were superior to those from other silicate minerals. Eucryptite sintered bodies with 95~97% relative densities and densified microstructures can be obtained using Hadong pink kaolin as starting materials by sintering over broad temperature zone(1250~135$0^{\circ}C$). The eucryptite sintered bodies which were fired at 130$0^{\circ}C$ for 2hrs, from Hadong pink kaolin had within 3.0wt% microstructural compositional variations compaired with stoichiometric compound, and had good negative thermal expansiion property with -3.55$\times$10-6/$^{\circ}C$ thermal expansion coefficient. Spodumene sintered bodies which were prepared from pyrophyllite group silicate minerals, had dense microstructures and high densities by densification through liquid phase sintering with enlarged temperature range. The specimens which were fired at 130$0^{\circ}C$ for 2 hrs from Gusipyrophillite, had dense microstructure with crystallines mainly, and low thermal expansion property with 0.62$\times$10-6/$^{\circ}C$ thermal expansion coefficient. The porous texture and residual glass phase in LAS system ceramics which were prepared from silicate minerals, tend to increase the thermal expansion properties of sintered bodies to positive direction.

  • PDF

Effect of Compositional Parameters on the Characteristics of C-SiC-$B_4C$ Composites

  • Aggarwal, R.K.;Bhatia, G.B.;Saha, M.;Mishra, A.
    • Carbon letters
    • /
    • 제5권4호
    • /
    • pp.164-169
    • /
    • 2004
  • Carbon-ceramic composites refer to a special class of carbon based materials which cover the main drawbacks of carbon, particularly its proneness to air oxidation, while essentially retaining its outstanding properties. In the present paper, the authors report the results of a systematic study made towards the development of C-SiC-$B_4C$ composites, which involves the effects of compositional parameters, namely, carbon-to-ceramic and ceramic-to-ceramic ratios, on the oxidation behaviour as well as other characteristics of these composites. The C-SiC-$B_4C$ composites, heat-treated to $1400^{\circ}C$, have shown that their oxidation behaviour at temperatures of 800~$1200^{\circ}C$ depends jointly on the total ceramic content and the SiC : $B_4C$ ratio. Good compositions of C-SiC-$B_4C$ composites exhibiting zero weight loss in air at temperatures of 800~$1200^{\circ}C$ for periods of 4~9 h, have been identified. Composites with these compositions undergo a weight gain or a maximum weight loss of less than 3% during the establishment of a protective layer at the surface of carbon in a period of 1~6 h. Significant improvement in the strength of C-SiC-$B_4C$ composites has been observed which increases with an increase in the total ceramic content and also with an increase in the SiC : $B_4C$ ratio.

  • PDF

제주도 용암 해수로 대량배양한 미세조류 멜로시라(Melosira nummuloides)의 성분 특성 (Compositional Characteristics of the Microalga Melosira nummuloides Mass-cultured Using Jeju Lava Seawater)

  • 김윤영;신현아;최정우;김미연;고경민
    • 한국수산과학회지
    • /
    • 제55권2호
    • /
    • pp.91-101
    • /
    • 2022
  • In this study, we analyzed the compositional characteristics of Melosira nummuloides mass-cultured using Jeju lava seawater. M. nummuloides showed the highest growth rate when cultured for 14 days at 17-20℃ and 15,000 lx. Proximate composition of raw-material (RM) and freeze-dried M. nummuloides (FM) showed high ash content (65-72%), while ethanol-extracted M. nummuloides (EM) had low ash and high lipid contents. The predominantly occurring mineral, Si, was 334 g/kg in RM and 269 g/kg in FM, but EM contained only 1.97 g/kg. The ratio of essential amino acids was similar in RM (38.93%) and FM (36.89%) lower in EM (17.83%), but branched chain amino acids required for muscle metabolism was high (63.40%). The polyunsaturated fatty acids of EM (34.74%) was 11% more than that in RM (23.81%), and the ratio of omega-6 to omega-3 fatty acids was 1:3.6. Furthermore, the concentration of total chlorophyll was higher by 5.15 times (62.32 mg/g) and that of fucoxanthin by 7.06 times (11.02 mg/g) in EM than in RM (12.11, 1.56 mg/g, respectively). The mass cultivation and filtration of M. nummuloides using lava seawater has high prospects of commercialization as a competitive bio silica, cosmetic and healthy functional food material.

동해남부 대마난류계에서의 염소화 Biphenyls의 분포특성 (Distribution Chara Cteristics of Polychlorinated Biphenyls in the Southern Korea)

  • 이동인;옥곤;양한섭;장윤석
    • 한국수산과학회지
    • /
    • 제30권4호
    • /
    • pp.679-686
    • /
    • 1997
  • 본 연구조사는 동해남부 대마난류계에서의 PCBs의 분포특성을 파악하기 위하여 1996년 8월과 10월에 걸쳐 5개 정점을 선정하여 각 정점의 수심별의 수온, 염분 및 용존산소를 측정하여 수괴 분석을 실시하였으며, 또한, 각 정점별, 수심별의 PCBs의 분석을 실시하였다. 수괴의 분포특성을 조사한 결과 수온 및 염분약층은 수심 30m부분에 존재하고 있었으며, 대마난류 중층수는 30m이하로 간주되었으며, 대마난류의 표층수는 한국근해에서 대마도쪽으로 확장되는 양상을 보였다. PCBs의 분석결과 표층수는 8월의 경우 대마도쪽으로 갈수록 농도가 약간 낮아지는 경향을 보이다가, 대마도쪽에서 다시 약간의 증가경향이 관찰되었다. 표층 해수중에서의 PCBs의 평균농도는 $0.29\;ng/\ell$정도 였으며, 중층에서의 평균농도는 $0.31\;ng/\ell$정도로 표층에 비교하여 중층에서의 농도가 약간 증가하는 것으로 나타났다. 해수중 PCBs의 농도는 부유물질의 농도변화 경향과 유사성을 나타났으며, 농도의 수평 및 연직변화는 그다지 크게 나타나지 않아 비교적 균일한 농도분포를 나타내고 있었다. 해수의 수심별 PCBs의 상대농도 조성비는 표층에서 Di- 및 Tri-PCBs의 비율이 높았지만, 심층으로 갈수록 Peta-PCBs의 상대농도 조성비율이 높은 것으로 나타나, 수심의 변화에 따른 PCBs의 구성비와 소실에 차이가 있는 것으로 사료된다.

  • PDF

스토커형 소각로의 연소특성 및 연소 모델에 관한 연구 (The study on the combustion model and combustion characteristics for stoker type incinerator)

  • 김호영;황호영;전철균
    • 대한기계학회논문집B
    • /
    • 제22권5호
    • /
    • pp.627-639
    • /
    • 1998
  • A combustion model for the incineration of municipal solid waste(MSW) in the stoker type incinerator was developed by considering the variation of physical composition of MSW. Theoretical analysis and numerical simulation for the combustion characteristics in incinerator were conducted by using the present model and the effects of compositional variation on the incineration characteristics of MSW was examined theoretically. It is found that large excess air enhances drying, but depresses volatilization. For the large value of moisture content, pyrolysis is fast but drying is slow. As the value of plastic content increases, devolatilization becomes slower. Larger amount of primary air supply to the rear side of stoker leads to increase the possibility of delaying the combustion.

양동마을 향단에 있어서 칸의 구축성 (Tectonic Characteristics of 'KAN' in Hyangdan(香壇) at Yang-Dong Village)

  • 장선주;한조동;이강훈
    • 한국농촌건축학회논문집
    • /
    • 제4권2호
    • /
    • pp.27-37
    • /
    • 2002
  • From the point of tectonic manner which is 'how to build a house' this study considers the characteristics of Kan in Hyangdan(香壇) at Yang-Dong Village. It was analysed with primary elements such as Kan, condition of a site, module, structural system, roofing system and their relationships in spatial and formal composition. Through the analysis, findings were achieved that characteristics of Kan to form a rectangle of 1 to root 2 proportion plan, enable irregularity in usage and regularity in compositional aspect and structural system to achieve intended roof design. In addition, Kan as a module is found to have a relative value that also regulates the whole in structural and aesthetical aspects.

  • PDF

죠르죠 그라씨 건축형태 구성원리에 관한 연구 (A Study on the architectural composition of Giorgio Grassi)

  • 곽기표
    • 한국실내디자인학회논문집
    • /
    • 제32호
    • /
    • pp.13-20
    • /
    • 2002
  • This study is purposed to find fundamental characteristics in Grassi's architecture which has architectural principles in architecture itself and in the general frame of the historical facts of architecture. His architectural theories can be explained for rationality, historicity, universality. The method of architectural composition can be divided into urban morphological characteristic and compositional characteristic of architecture. The characteristics of the former are the reconstruction of the urban structure by the readjustment of an urban axis which is based on historical continuity of the city, the open court which is a passage transformed from colonnade that is the historical vernacular type and the respect for the city-line which goes with historical context. The characteristics of the latter are the use transformed of nine square which gives consideration to centrality and typology at the same time and the hierarchic division of the principal space and the subordinate space for the functional typical purpose. This analysis shows that Grassi's architecture is on the base of historical continuity and urban reality and for him architectural work is mental work which conflict with the real world for the reconstruction of the city.

DNA and DNA-CTMA composite thin films embedded with carboxyl group-modified multi-walled carbon nanotubes

  • Dugasani, Sreekantha Reddy;Gnapareddy, Bramaramba;Kesama, Mallikarjuna Reddy;Ha, Tai Hwan;Park, Sung Ha
    • Journal of Industrial and Engineering Chemistry
    • /
    • 제68권
    • /
    • pp.79-86
    • /
    • 2018
  • Although the intrinsic characteristics of DNA molecules and carbon nanotubes (CNT) are well known, fabrication methods and physical characteristics of CNT-embedded DNA thin films are rarely investigated. We report the construction and characterization of carboxyl (-COOH) group-modified multi-walled carbon nanotube (MWCNT-COOH)-embedded DNA and cetyltrimethyl-ammonium chloride-modified DNA (DNA-CTMA) composite thin films. Here, we examine the structural, compositional, chemical, spectroscopic, and electrical characteristics of DNA and DNA-CTMA thin films consisting of various concentrations of MWCNT-COOH. The MWCNT-COOH-embedded DNA and DNA-CTMA composite thin films may offer a platform for developing novel optoelectronics, energy harvesting, and sensing applications in physical, chemical, and biological sciences.

경상분지 남서부 와룡산 일대에 분포하는 백악기 화강암류에 관한 암석학적 연구: 마그마 불균질 혼합에 의한 화강암류의 조성변화 (Petrological Study of Cretaceous Granitic Recks in the Waryongsan Area, Southwestern Gyeongsang Basin: Compositional Change of Granitic Rocks by Magma Mingling)

  • 김건기;김종선;좌용주
    • 암석학회지
    • /
    • 제14권1호
    • /
    • pp.12-23
    • /
    • 2005
  • 와룡산 일대에 암주상으로 분포하는 백악기 화강암류는 고도에 따른 수직적인 조성변화를 보인다. 이들 화강암류 내에는 다양한 크기와 형태의 염기성 미립 포유암들이 산출되며, 과냉각대, 망토조직, 그리고 벡베이닝 등과 같은 마그마 혼합의 뚜렷한 증거들이 나타난다. 화강암류는 암석기재적 특징과 모드분석결과로부터 반상화강암, 반상화강섬록암, 그리고 세립질화강암으로 세분되며, 염기성 미립 포유암은 석영섬록암, 석영몬조섬록암, 그리고 토날라이트 조성을 가진다. 화강암류 내에 염기성 미립 포유암의 분포 면적비는 반상화강암이 10∼15%, 세립질화강암이 약 20%, 그리고 반상화강섬록암이 약 50% 정도로 반상화강섬록암에 집중되어 분포한다. 화강암류 주성분 원소 분석결과를 하커변화도에 도시해 보면 반상화강섬록암에서 세립질화강암으로 가면서 선적인 변화경향을 보이며, SiO₂ 함량은 61.2∼72.0wt.%의 조성변화를 보이며, 반상화강섬록암은 평균 61.7wt.%, 반상화강암은 평균 68.6wt.%, 그리고 세립질화강암은 71.9wt.%의 조성을 가진다. 이와 같은 조성의 변화는 마그마 불균질 혼합에 의한 것으로 매픽 마그마의 양적인 비율에 따른 혼합 정도의 차이에 기인하는 것으로 생각된다. 매픽 마그마의 양이 많은 부분에서는 열적 평형에 빨리 도달하여 화학적 혼합에 의한 반상화강섬록암의 조성이 우세하고, 매픽 마그마의 양이 적은 부분은 기계적인 혼합에 의한 반상화강암과 세립질화강암의 조성이 우세한 것으로 고찰할 수 있다. 따라서 와룡산 일대 화강암류는 화강암질 마그마가 어느 정도 결정분화된 단계에서 보다 매픽한 마그마의 주입으로 인해 마그마 불균질 혼합이 발생하게 되었으며, 혼합된 두 마그마의 양적인 비율에 의해 화강암류의 조성이 변화된 것으로 판단된다.

건축형태구성에 있어 보편성 원리와 표현특성에 관한 연구 (A Study on the Characteristics of expression and formal principle of universalism it Architectural Composition)

  • 이승우
    • 한국실내디자인학회논문집
    • /
    • 제16호
    • /
    • pp.175-181
    • /
    • 1998
  • The purpose of this study was to analyze the characteristics of expression and formal principle of universalism in Architectural Composition. Theorical category is to find universal system with the connection between idea of society and tradition in compositional frame the results were as follows : First it is the pursuit of divine. Through Middle Age and Renaissance universalism of principles in Architectural Composition is appeared a numerical order and human proportion with applying of cosmology. Second it is the pursuit of schema. With the simplicity of formal image it represented to the geometrical form for its clearness. Third it is the pursuit of typology. As to play a role of decisive factor in formal construction type represented the model with abstraction of shape.

  • PDF