• Title/Summary/Keyword: composite resins

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Effect of Gamma Ray Irradiation on the Mechanical and Thermal Properties of MWNTs Reinforced Epoxy Resins

  • Shin, Bum Sik;Shin, Jin Wook;Jeun, Joon Pyo;Kim, Hyun Bin;Oh, Seung Hwan;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.137-143
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    • 2011
  • Epoxy resins are widely used as high performance thermosets in many industrial applications, such as coatings, adhesives and composites. Recently, a lot of research has been carried out in order to improve their mechanical properties and thermal stability in various fields. Carbon nanotubes possess high physical and mechanical properties that are considered to be ideal reinforcing materials in composites. CNT-reinforced epoxy system hold the promise of delivering superior composite materials with their high strength, light weight and multi functional features. Therefore, this study used multi-walled carbon nanotubes (MWNT) and gamma rays to improve the mechanical and thermal properties of epoxy. The diglycidyl ether of bisphenol A (DGEBA) as epoxy resins were cured by gamma ray irradiation with well-dispersed MWNTs as a reinforcing agent and triarylsulfonium hexafluoroantimonate (TASHFA) as an initiator. The flexural modulus was measured by UTM (universal testing machine). At this point, the flexural modulus factor exhibits an upper limit at 0.1 wt% MWNT. The thermal properties had improved by increasing the content of MWNT in the result of TGA (thermogravimetric analysis). However, they were decreased with increasing the radiation dose. The change of glass transition temperature by the radiation dose was characterized by DMA (dynamic mechanical analysis).

Studies on Thermal Stability and Cure Behavior of Epoxy Resins using Electron-beam Curing Technique (전자선 경화를 이용한 에폭시 수지의 열안정성과 경화동력학에 관한 연구)

  • 박수진;허건영;이재락
    • Composites Research
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    • v.15 no.2
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    • pp.40-47
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    • 2002
  • The di-functional epoxy resins, i.e., diglycidylether of bisphenol A(DGEBA) and diglycidylethere of bisphenol F(DGEBF) were initiated by cationic catalyst, i.e., benzylquinoxalinium hexafluoroantimonate(BQH) using electron-beam(EB) technique. And the effect of structure of DGEBA and DGEBF on thermal stabilities and cure behaviors was investigated. According to the experimental results, the decomposed activation energy based on Horowitz-Metzger method was higher in the case of DGEBA, but intergral procedural decomposition temperature(IPDT) of DGEBA was lower than DGEBF. This could be interpreted in terms of high crosslink density resulted from hydroxyl bond of DGEBF backbone. It was confirmed in increasing the hydroxyl band at $7000\;cm^{-1}$ and $5235\;cm^{-1}$ using near-infrared spectroscopy(NIRS).

Effects of Ar+ ion Beam Irradiation on the Adhesion Forces between Carbon fibers and Thermosetting Resins (Ar+ 이온 빔 조사가 탄소섬유와 열경화성 수지 간 계면결합력에 미치는 영향)

  • 박수진;서민강;김학용;이경엽
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.718-727
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    • 2002
  • In this work, an Ar+ beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method h single fiber pull-out test was executed to investigate the basic characteristics of the single Carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy as a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.

Experimental Study on Thermal and Mechanical Characteristics of Two Resin Composites Using the Co-Curing Process (동시 경화 제작기법을 적용한 이종 수지 복합재의 열적/기계적 특성에 관한 실험적 연구)

  • Yoon, Jin-Young;Choi, Jiduck;Park, Cheolyong;Kim, Younggyu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.23 no.5
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    • pp.475-484
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    • 2020
  • Individual curing process of each layer in two resin composites can be caused the separation between two layers. In this study, co-curing process for two resin composites is suggested to improve the inter-layer bonding. Glass fiber reinforced composites with phenolic and epoxy resins were manufactured by co-curing process, and several types of glass/phenolic composites were considered to confirm the application on two resin composites. Experiments for smoke resistance, scratch resistance and flexural strength were carried out to verify requirements corresponding to thermal and mechanical environments. It was validated that two resin composites with phenolic resin impregnated prepreg exhibits good thermal and mechanical characteristics, and it can serve as highly effective composite structures in aerospace and many industry areas.

AN EXPERIMENTAL STUDY ON THE CYTOTOXICITY OF SEVERAL COMPOSITE RESINS (수종(數種) 치과(齒科) 수복용(修復用) 복합(複合)레진의 세포독성(細胞毒性)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Myoung, Jae-Keun;Lee, Myoung-Jong
    • Restorative Dentistry and Endodontics
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    • v.14 no.1
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    • pp.25-40
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    • 1989
  • This study was conducted to evaluate the influence of 5 microfilled composite resin to fibroblast cultivated from human pulp (age 13). Each composite resin was manually mixed and filled in cylinder. Resin filled cylinders were placed in dishes (35mm in diameter) containing 3 ml of ${\alpha}$-MEM. Filters (pore size 0.22 ${\mu}m$) to simulate dentin were also placed between the bottom of cylinder and the dish floor. Then stored in 5% $CO_2$ containing incubator for 1 and 2 weeks at the temperature 36.6 C. The results analysed after 1 and 2 weeks were as follows: 1. Experimental group except group 2, 2 weeks incubation cases showed the cytotoxicity compared to the control group in cell count. 2. After 2 week-incubation of group 1 and group 4, cell count was more decreased than 1 week cases and cytotoxicity seemed to be constantly influenced to the cell multiplication. 3. The cell growth rate of 1 week incubation in group 3 and group 5 was similar to the control group and recognized the cytotoxicities of these groups were mild. 4. The cell multiplication rate of 2 week incubation cases in group 2 was greater than control group.

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A Comparison of Design Strength Equations between Steel and Fiber Reinforced Polymer Composites Columns (철골 및 섬유보강 폴리머(FRP) 복합 기둥의 설계강도식에 관한 비교 연구)

  • Choi, Yeol;Pyeon, Hae-Wan
    • Journal of Korean Association for Spatial Structures
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    • v.3 no.3 s.9
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    • pp.85-93
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    • 2003
  • Steel, concrete and their combination materials are the most 6commonly used materials for civil engineering structural systems such as buildings, bridge structures and other structures. Recently, however, fiber reinforced polymer (FRP) composites, a relatively new composite material made of fibers and polymer resins, have been gradually used in structural systems as an alternative structural material. This paper describes a comparison of design strength equations for steel column and FRP composite column based on design philosophies. The safety factors used in allowable stress design (ASD) are relatively higher in FRP structural design than steel structural design. Column critical stress equations of FRP composites column from an experimental study can be represented by Euler elastic buckling equation at the long-range of slenderness, and an exponential form at the short-range of slenderness as defined in Load and Resistance Factor Design (LRFD) of steel column. The column strength of steel and FRP composite columns in large slenderness is independent of material strength, this result verified the elastic buckling equation as derived by Eq. (15) and Eq. (5).

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Mechanical and thermal properties of MWCNT-reinforced epoxy nanocomposites by vacuum assisted resin transfer molding

  • Lee, Si-Eun;Cho, Seho;Lee, Young-Seak
    • Carbon letters
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    • v.15 no.1
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    • pp.32-37
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    • 2014
  • Multi-walled carbon nanotube (MWCNT)/epoxy composites are prepared by a vacuum assisted resin transfer molding (VARTM) method. The mechanical properties, fracture surface morphologies, and thermal stabilities of these nanocomposites are evaluated for epoxy resins with various amounts of MWCNTs. Composites consisting of different amounts of MWCNTs displayed an increase of the work of adhesion between the MWCNTs and the matrix, which improved both the tensile and impact strengths of the composites. The tensile and impact strengths of the MWCNT/epoxy composite improved by 59 and 562% with 0.3 phr of MWCNTs, respectively, compared to the epoxy composite without MWCNTs. Thermal stability of the 0.3 phr MWCNT/epoxy composite increased compared to other epoxy composites with MWCNTs. The enhancement of the mechanical and thermal properties of the MWCNT/epoxy nanocomposites is attributed to improved dispersibility and strong interfacial interaction between the MWCNTs and the epoxy in the composites prepared by VARTM.

Fibre reinforcement in a structurally compromised endodontically treated molar: a case report

  • Soares, Renita;Ataide, Ida de Noronha de;Fernandes, Marina;Lambor, Rajan
    • Restorative Dentistry and Endodontics
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    • v.41 no.2
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    • pp.143-147
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    • 2016
  • The reconstruction of structurally compromised posterior teeth is a rather challenging procedure. The tendency of endodontically treated teeth (ETT) to fracture is considerably higher than vital teeth. Although posts and core build-ups followed by conventional crowns have been generally employed for the purpose of reconstruction, this procedure entails sacrificing a considerable amount of residual sound enamel and dentin. This has drawn the attention of researchers to fibre reinforcement. Fibrereinforced composite (FRC), designed to replace dentin, enables the biomimetic restoration of teeth. Besides improving the strength of the restoration, the incorporation of glass fibres into composite resins leads to favorable fracture patterns because the fibre layer acts as a stress breaker and stops crack propagation. The following case report presents a technique for reinforcing a badly broken-down ETT with biomimetic materials and FRC. The proper utilization of FRC in structurally compromised teeth can be considered to be an economical and practical measure that may obviate the use of extensive prosthetic treatment.

THE ANTICARIOGENIC EFFECT OF F IN PRIMER, BONDING AGENT AND COMPOSITE RESIN IN THE CAVOSURFACE ENAMEDL AREA (Primer Bonding agent, 복합레진 내의 볼소의 법랑질에 대한 항우식 작용)

  • Park, Sung-Ho
    • Restorative Dentistry and Endodontics
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    • v.21 no.2
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    • pp.635-641
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    • 1996
  • This study was designed to evaluate the anti cariogenic effect of F in primers, bonding agents, composite resins or glass ionomer cements in enamel. Twenty-five extracted teeth were selected and a cavity was prepared on either the buccal or the lingual surface of each tooth. After pumicing and etching, the samples were divided into 5 groups. In group A, the samples were primed, bonded and filled with ART bond and Brilliant Enamel (Coltene, Switzerland). Group B composed of Optibond and Herculited XRV (Kerr, USA), group C composed of Syntac and Tetric(Vivadent, Lichtenstein), and group D composed of Scotch-bond Multipurpose and Z 100 (3M, YSA). In group E, the samples were filled with glass ionomer cement (Fuji II LC, Japan), All surfaces except the 2mm beyond the cavosurface margin of the sample were protected, and samples were then put into an acid buffer for 3 days to develop the initial caries. The samples were then sectioned through the filling body into thin wafers and then examined with a polarizing microscope under water imbibition. The fluoride in primer, bonding agent, or composite filling material did not prevent the initial caries in the enamel area adjacent to the filling body whereas the fluoride in the glass ionomer did prevent the initial stage caries.

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Awareness & satisfaction of caregivers on the health insurance coverage of light-curable composite resin restoration (광중합형 복합레진 충전 건강보험 급여화에 대한 보호자의 인식과 만족도)

  • Yu, Sl-A;Lee, Su-Young
    • Journal of Korean society of Dental Hygiene
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    • v.21 no.1
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    • pp.89-98
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    • 2021
  • Objectives: The purpose of this study was to investigate the perception and satisfaction of caregivers and parents after being covered by health insurance for light-curing composite resin fillings, and to contribute to the settlement of the expansion and coverage of health insurance. Methods: A survey was conducted on caregivers who visited two dental institutions in the Gyeonggi-do area, and parents who joined internet cafes (online communities) in the Gyeonggi-do area from June 2 to September 2, 2020. 225 responses were collected eventually, and 212 valid responses were used as analysis data. Results: 67.0% of the study subjects were aware of the permanent teeth resin fillings being covered by health insurance and the satisfaction was relatively high (91.5%). There was a statistically significant difference in the perception of permanent tooth resin filling benefits according to the child's oral condition (p=0.025) and the parents' own interest in oral health (p=0.039). Conclusions: Based on the results of this study, it is necessary to increase the accessibility to the initial treatment for dental care of children through active promotion of detailed items of permanent teeth resin fillings.