• Title/Summary/Keyword: combustion resistance

Search Result 165, Processing Time 0.033 seconds

Synthesis and Characterizations of Mn1+XCo2-XO4 Solid Solution Catalysts for Highly Efficient Li/Air Secondary Battery (고효율의 리튬/공기 이차전지 공기전극용 Mn1+XCo2-XO4 고용체 촉매 합성 및 분석)

  • Park, Inyeong;Jang, Jaeyong;Lim, Dongwook;Kim, Taewoo;Shim, Sang Eun;Park, Seok Hoon;Baeck, Sung-Hyeon
    • Journal of the Korean Electrochemical Society
    • /
    • v.18 no.4
    • /
    • pp.137-142
    • /
    • 2015
  • $Mn_{1+X}Co_{2-X}O_4$ solid solutions with various Mn/Co ratios were synthesized by a combustion method, and used as cathode catalysts for lithium/air secondary battery. Their electrochemical and physicochemical properties were investigated. The morphology was examined by transmission electron microscopy (TEM), and the crystallinity was confirmed by X-ray diffraction (XRD) analyses. For the measurement of electrochemical properties, charge and discharge measurements were carried out at a constant current density of $0.2mA/cm^2$, monitoring the voltage change. Electrochemical impedance spectroscopy (EIS) analyses were also employed to examine the change in charge transfer resistance during charge-discharge process. $Mn_{1+X}Co_{2-X}O_4$ solid solutions showed enhanced cycleability as a cathode of Li/air secondary battery, and the performance was found to be strongly dependent on Mn/Co ratio. Among synthesized catalysts, $Mn_{1.5}Co_{1.5}O_4$ exhibited the best performance and cycleability, due to high charge transfer rate.

Mechanical and Fire Resistance Properties of Surface Preparation Mortar in Buildings Using Expanded Graphite (팽창흑연을 활용한 건축물 외단열 바탕조정재의 역학 및 연소 특성평가)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Song, Sung-Young;Kim, Deuak-Mo
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.7 no.4
    • /
    • pp.395-404
    • /
    • 2019
  • In the case of fire, surface treatment agents used in external insulation finishing methods are substances that are vulnerable to fire due to thin finishes and the combustion of polymers. In this study, it was expected that the performance of surface preparation mortars could be improved by using expandable graphite with excellent thermal performance. Experimental results showed that the mechanical properties of surf ace preparation mortar were improved by using the fly ash and silica fume. Surface treatment materials using expanded graphite have a characteristic of expanding when a fire occurs. It has been shown that heat-swellable surface treatment materials can reduce the penetration of heat sources into the surface of synthetic insulation.

Development of Urban Driving Cycle for Performance Evaluation of Electric Vehicles Part I : Development of Driving Cycle (전기 자동차 성능 평가를 위한 도심 주행 모드 개발 Part I : 주행 모드 개발)

  • Yang, Seong-Mo;Jeong, Nak-Tak;Kim, Kwang-Seup;Choi, Su-Bin;Wang, Maosen;Kim, Hyun-Soo;Suh, Myung-Won
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.22 no.7
    • /
    • pp.117-126
    • /
    • 2014
  • Recently, due to various environmental problems such as global warming, increasing of international oil prices and exhaustion of resource, a paradigm of world automobile market is rapidly changing from vehicles using internal combustion engine to eco-friendly vehicles using electric power such as EV (Electric Vehicle), HEV (Hybrid Electric Vehicle), PHEV (Plug-in Hybrid electric Vehicle) and FCEV (Fuel Cell Electric Vehicle). There are many driving cycles for performance evaluation of conventional vehicles. However there is a lack of researches on driving cycle for EV. This study is composed of part 1 and part 2. In this paper part 1, in order to develop urban driving cycle for performance evaluation of electric vehicles, Gwacheon-city patrol route of police patrol car was selected. Actual driving test was performed using EV. The driving data such as velocity, time, GPS information etc. were recorded. GUDC-EV (Gwacheon-city Urban Driving Cycle for Electric Vehicles) including road gradient was developed through the results of analyzing recorded data. Reliability of the driving cycle development method was substantiated through comparison of electricity performance. In the second part of this study, the developed driving cycle was compared to simulation result of the existing urban driving cycle. Verification of the developed driving cycle for EV performance evaluation was described.

A Study on the Oxidation Behavior of Metal Materials Applicable to Oxidizer Rich Pre-Combustor (산화제 과잉 연소기에 활용 가능한 금속재료의 산화 거동에 관한 연구)

  • Shin, Donghae;Yu, Isang;Shin, Minku;Ko, Youngsung;So, Younseok;Han, Yeoungmin
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.23 no.2
    • /
    • pp.118-125
    • /
    • 2019
  • Metals exposed to high temperature/high pressure/oxidant excess environment of an oxygen excess pre-combustor may undergo rapid oxidation. In this study, the test facility to simulate the high temperature/high pressure/oxidant excess environment was constructed and the oxidation resistance evaluation was carried out for various metal materials. As a result, the discoloration of the metallic materials, the change in the surface roughness and the peeling of the metal surface were observed, and the weight change was also observed. The resulst showed that oxidation-resistant coating of a metal material of the combustor is indispensably required, and the use of XM-19, which has the highest content of Cr and Ni, is expected to provide more structural stability.

Thermo-Fluid Simulation for Flow Channel Design of 7kW High-Voltage Heater for Electric Vehicles (전기차용 7kW급 고전압 히터 유로 형상 설계를 위한 열유동 시뮬레이션)

  • Son, Kwon Joong
    • Journal of the Korea Convergence Society
    • /
    • v.13 no.3
    • /
    • pp.191-196
    • /
    • 2022
  • Unlike an international combustion engine car, a battery-powered electric vehicle requires an additional heat source for its heating system. A high-voltage coolant heater has the advantages of high efficiency and a wide operating temperature range. In its development, the geometry design of the coolant flow path is essential. This paper presents the thermal flow simulations of a 7kW high-voltage heater with symmetric serpentine flow channels arranged parallelly. The heater performance was evaluated from the simulation results in terms of the pressure and temperature differences and the flow uniformity. The proposed design showed a greater flow resistance and similar heat exchanging capability than the existing parallel serpentine design. It has the advantage of a relatively wide low-temperature surface area, where the control circuit board susceptible to high temperatures can be located.

Mo,Cu-doped CeO2 as Anode Material of Solid Oxide Fuel Cells (SOFCs) using Syngas as Fuel

  • Diaz-Aburto, Isaac;Hidalgo, Jacqueline;Fuentes-Mendoza, Eliana;Gonzalez-Poggini, Sergio;Estay, Humberto;Colet-Lagrille, Melanie
    • Journal of Electrochemical Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.246-256
    • /
    • 2021
  • Mo,Cu-doped CeO2 (CMCuO) nanopowders were synthesized by the nitrate-fuel combustion method aiming to improve the electrical and electrochemical properties of its Mo-doped CeO2 (CMO) parent by the addition of copper. An electrical conductivity of ca. 1.22·10-2 S cm-1 was measured in air at 800℃ for CMCuO, which is nearly 10 times higher than that reported for CMO. This increase was associated with the inclusion of copper into the crystal lattice of ceria and the presence of Cu and Cu2O as secondary phases in the CMCuO structure, which also could explain the increase in the charge transfer activities of the CMCuO based anode for the hydrogen and carbon monoxide electro-oxidation processes compared to the CMO based anode. A maximum power density of ca. 120 mW cm-2 was measured using a CMCuO based anode in a solid oxide fuel cell (SOFC) with YSZ electrolyte and LSM-YSZ cathode operating at 800℃ with humidified syngas as fuel, which is comparable to the power output reported for other SOFCs with anodes containing copper. An increase in the area specific resistance of the SOFC was observed after ca. 10 hours of operation under cycling open circuit voltage and polarization conditions, which was attributed to the anode delamination caused by the reduction of the Cu2O secondary phase contained in its microstructure. Therefore, the addition of a more electroactive phase for hydrogen oxidation is suggested to confer long-term stability to the CMCuO based anode.

A Study on Acquisition of Overhead Line Location Information of Pantograph for E-Highway (E-Highway를 위한 팬터그래프의 가공선 위치정보 취득에 관한 연구)

  • Gwang-Cheol Song;Jun-Jae An;Tuan-Vu Le;Seong-Mi Park;Sung-Jun Park
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.26 no.5
    • /
    • pp.915-923
    • /
    • 2023
  • As environmental regulations on carbon emissions are strengthened worldwide, the existing internal combustion engine-centered automobile industry is being reformed. In particular, large buses and large cargo trucks are pointed out as one of the main causes of environmental destruction due to excessive carbon emissions. The E-Highway power collection system, which has recently been proposed as a solution, uses the vehicle's battery as a backup power source or regenerative braking, depending on whether the pan head of the pentograph installed in the vehicle is in contact with the overhead line. It is used to store the excess energy generated. However, wear through contact due to continuous contact reduces the current collection effect and causes failure. In this paper, by using the current difference, the horizontal position information of the panhead in contact with the overhead line is acquired, thereby reducing the abrasion of the conductor and the panhead Make it possible to follow the overhead line. The position estimation method proposed in this paper simply configures a device that can detect the position of the overhead line of the pantograph by the difference in resistance. It is economical and has the advantage of reducing the volume. The characteristics of the pantograph estimating the location of overhead lines were analyzed using the difference between the two currents of the current collector, the feasibility of the positioning estimation system was verified through simulations and experiments.

Heat Exchanging Performance as Affected by Arrangement of Heat Exchanging Pipe (열회수장치의 열교환 파이프배치 형식별 열교환 성능)

  • 윤용철;강종국;서원명
    • Journal of Bio-Environment Control
    • /
    • v.11 no.3
    • /
    • pp.101-107
    • /
    • 2002
  • This study was carried out to improve the performance of heat recovery device attached to exhaust gas flue connected to combustion chamber of greenhouse heating system. Three different units were prepared far the comparison of heat recovery performance; A-type is exactly the same with the typical one fabricated for previous study of analyzing heat recovery performance in greenhouse heating system, other two types (B-type and C-type) modified from the control unit are different in the aspects of airflow direction (U-turn airflow) and pipe arrangement. The results are summarized as follows ; 1. In the case of Type-A, when considering the initial cost and current electricity fee required for system operation, it was expected that one or two years at most would be enough to return the whole cost invested. 2. Type-B and Type-C, basically different with Type-A in the aspect of airflow pattern, are not sensitive to the change of blower capacity with higher than 25m$^3$.min$^{-1}$ . Therefore, heat recovery performance was not improved so significantly with the increment of blower capacity. This was assumed to be that air flow resistance in high air capacity reduced the heat exchange rate as well. Never the less, compared with control unit, resultant heat recovery rate of Type-B and Type-C was improved by about 5% and 13%, respectively 3. Desirable blower capacity of these heat recovery units experimented were expected to be about 25m$^3$.min$^{-1}$ , and at the proper blower capacity, U-turn airflow units showed better heat recovery performance than control unit. But, without regard to the type of heat recovery unit, it was recommended that comprehensive consideration of system's physical factors such as pipe arrangement density, unit pipe length and pipe thickness, etc., was required for the optimization of heat recovery system in the aspects of not only energy conservation but economic system design.

Development of Antifreeze Concentration Control device for Solar Heat Energy System (태양열에너지 시스템용 부동액 농도 제어 장치의 개발)

  • Seo, Choong-Kil;Won, Joung Wun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.4
    • /
    • pp.1-7
    • /
    • 2018
  • The gases emitted from internal combustion engines using fossil fuels are causing many social problems, such as environmental pollution, global warming, and adverse health effects on the human body. In recent years, the demand for renewable energy has increased, and government policy support and research and development are also active. In the collecting part of a solar energy system, which is widely used at home, propylene glycol (PG) (anti-freeze), as a heating medium, is mixed with water at a fixed value of 50%, and the heat is transferred to the collecting part at subzero temperatures. On the other hand, when leakage occurs in the heat medium in the heat collecting part, supplemental water is supplied to the solar heat collecting part due to the characteristics of the solar heat system, so that the concentration of antifreeze in the replenishing water becomes low. As a result, the temperature of the solar heat collecting part is lowered resulting in a frost wave, which causes economic damage. The purpose of this study was to develop a device capable of controlling the antifreeze concentration automatically in response to a temperature drop to prevent freezing of the heat collecting part generated in the solar energy system. The electrical conductivity of the H2O component was larger than that of PG, and the resistance increased with decreasing temperature. The PG concentration control values of 40, 50, and 60% should be controlled through calibration with a PG concentration of 39.6, 50.7, and 60.1%.

Fundamental Heat Analysis about the Thermoelectric Generation System Using the Waste Heat of Exhaust Gas from Ship (선박의 배기가스 폐열을 활용한 열전발전시스템에 관한 기초 열해석)

  • Kim, Myoung-Jun;Ga, Gwang-Jin;Chea, Gyu-Hoon;Kim, In-Seup
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.22 no.5
    • /
    • pp.583-592
    • /
    • 2016
  • IMO (International Maritime Organization) in the UN (United Nations) set up that aim at reducing $CO_2$ emission from ship by up to 30 percent until 2030. The final purpose of this study is the development of marine thermoelectric generation system using waste heat from vessel of internal combustion engines. Before the development of marine thermoelectric generation system, this paper carried out the fundamental heat analysis of marine thermoelectric generation system. It was able to obtain the valuable results about the efficiency improvement of the thermoelectric generation system. The results is as follows : 1) It was confirmed that the efficiency of thermoelectric generation system improves to 8.917 % with increasing the temperature difference of peltier module by reducing the temperature difference between peltier module and heat source at the hot side. 2) System efficiency according to change in the external load resistance was confirmed that the change width of about 6 % which does not significantly occur. 3) System efficiency in the case stainless steel at the same condition is 8.707 %. System efficiency could be confirmed that the stainless steel is higher than duralumin (8.605 %), copper (8.607 %).