• Title/Summary/Keyword: coefficient of $CO_2$

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Mechanical Properties Analysis of Epoxy and Polyurethane Adhesive for Accurate Structural Analysis of LNG Cargo Hold (LNG 화물창 정밀 구조해석을 위한 에폭시와 폴리우레탄 접착제 기계적 물성치 분석)

  • Jeong, Yong-Cheol;Jeong, Yeon-Jae;Kim, Jeong-Dae;Park, Seong-Bo;Kim, Yong-Tai;Oh, Hoon-Gyu;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.2
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    • pp.66-72
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    • 2021
  • As the demand for natural gas that satisfies environmental regulations increases, the quantities of natural gas cargo that carrier can load is also increasing. Natural gas is transported in a liquefied state at -163 ℃ to increase loading efficiency. Among several LNG CCS types, MARK-III types are generally adopted in terms of loading efficiency. The secondary barrier adhesives of the MARK-III, nevertheless, is subjected to tensile stress due to thermal contraction and tension in the environment. In terms of these reasons, local analysis of the adhesive to evaluate the stress state must be carried out. According to previous studies, local analysis is unavailable since material properties for secondary barrier adhesives have not been reported. Thus, in this study, the cryogenic tensile test and coefficient of thermal expansion of epoxy and polyurethane (PU15, PU45), which are most widely used at cryogenic temperatures, were experimentally analyzed. At cryogenic temperature, the mechanical behavior of the polyurethane adhesive was better than epoxy of the adhesive. the joint of FSB and epoxy adhesive of the secondary barrier has the maximum coefficient of thermal expansion difference at 25 ℃ and minimum at -150 ℃, respectively.

Evaluation of Parameters in Hydrodynamic Model (동수역학모형의 매개변수 산정)

  • Yun, Tae-Hun;Lee, Jong-Uk;Jagal, Sun-Dong
    • Journal of Korea Water Resources Association
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    • v.33 no.1
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    • pp.39-50
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    • 2000
  • Generally speaking, a hydrodynamic model needs a friction coefficient (Manning coefficient or Chezy coefficient) and eddy viscosity. For numerical solution the coefficients are usually determined by recursive calculations. The eddy viscosity in numerical model plays physical diffusion in flow and also acts as numerical viscosity. Hence its value has influence on the stability of numerical solution and for these reasons a consistent evaluation procedure is needed. By using records of stage and discharge in the downstream reach of the Han river, I-D models (HEC-2 and NETWORK) and 2-D model (SMS), estimated values of Manning coefficient and an empirical equation for eddy viscosity are presented. The computed results are verified through the recorded flow elevation data.n data.

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Analysis of the lateral displacement to the Large Diameter Bored Pile based on the application of the Lateral coefficient of subgrade reaction (수평지반반력계수에 따른 대구경 현장타설말뚝의 수평변위 분석)

  • Chae, Young-Su;Kim, Nam-Ho;Bang, Ei-Souk;Lee, Kyoung-Jea
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.528-535
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    • 2005
  • Using the case of design to the Large diameter Bored Pile, We showed the various method to estimate the Lateral coefficient of subgrade reaction and analyzed the lateral displacement behavior according to the characteristics of sub layer distribution. According to the study, Mutual relation to the N value and the soil modulus of deformation showed 400N to 800N to the fine grained soil and weathered soil. It showed simular tendancy with the proposed expression of Schmertmann. But Weathered rock was over estimated as 4,200N. $k_h$ to the sedimentory soil and weathered rock each showed these orded of Schmertmann-PMT-2,800N and Schmertmann-2,800N-PMT. As the factor($\alpha$) 4 was applied to the estimation in weathered rock, $k_h$ to the PMT was calculate as a big value. If the pile is long and the pile is surpported to the soil, Lateral displacement was in inverse proportion ratio to the value of $k_h$. But the case of shallow soil layer(early bedrock) and the short pile, Lateral displacement was affected by the behavior of socheted pile to the bedrock not by the upper soil layer.

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3D-QSAR Studies on 2-(indol-5-yl)thiazole Derivatives as Xanthine Oxidase (XO) Inhibitors

  • Nagarajan, Santhosh Kumar;Madhavan, Thirumurthy
    • Journal of Integrative Natural Science
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    • v.8 no.4
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    • pp.258-266
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    • 2015
  • Xanthine Oxidase is an enzyme, which oxidizes hypoxanthine to xanthine, and xanthine to uric acid. It is widely distributed throughout various organs including the liver, gut, lung, kidney, heart, brain and plasma. It is involved in gout pathogenesis. In this study, we have performed Comparative Molecular Field Analysis (CoMFA) on a series of 2-(indol-5-yl) thiazole derivatives as xanthine oxidase (XO) inhibitors to identify the structural variations with their inhibitory activities. Ligand based CoMFA models were generated based on atom-by-atom matching alignment. In atom-by-atom matching, the bioactive conformation of highly active molecule 11 was generated using systematic search. Compounds were aligned using the bioactive conformation and it is used for model generation. Different CoMFA models were generated using different alignments and the best model yielded a cross-validated $q^2$ of 0.698 with five components and non-cross-validated correlation coefficient ($r^2$) of 0.992 with Fisher value as 236.431, and an estimated standard error of 0.068. The predictive ability of the best CoMFA models was found to be $r^2_{pred}$0.653. The CoMFA study revealed that the $R_3$ position of the structure is important in influencing the biological activity of the inhibitors. Electro positive groups and bulkier substituents in this position enhance the biological activity.

Ratio-Cum-Product Estimators of Population Mean Using Known Population Parameters of Auxiliary Variates

  • Tailor, Rajesh;Parmar, Rajesh;Kim, Jong-Min;Tailor, Ritesh
    • Communications for Statistical Applications and Methods
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    • v.18 no.2
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    • pp.155-164
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    • 2011
  • This paper suggests two ratio-cum-product estimators of finite population mean using known coefficient of variation and co-efficient of kurtosis of auxiliary characters. The bias and mean squared error of the proposed estimators with large sample approximation are derived. It has been shown that the estimators suggested by Upadhyaya and Singh (1999) are particular case of the suggested estimators. Almost ratio-cum product estimators of suggested estimators have also been obtained using Jackknife technique given by Quenouille (1956). An empirical study is also carried out to demonstrate the performance of the suggested estimators.

Verification and Revision of Empirical Equation for Physical Properties of Inert Gases (불활성 기체들의 물성에 관한 실험식의 검증과 교정)

  • 김재덕;김은철;한순구;노경호
    • Fire Science and Engineering
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    • v.18 no.3
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    • pp.9-17
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    • 2004
  • The values of physical properties of the inert gases of Ar, $N_2$, $CO_2$ were calculated by the empirical equations. The regression coefficients were obtained by the experimental data and the resulting calculated values. For the empirical equation with a lower regression coefficient, a new correlation was suggested. At an atmosphere pressure, the empirical equation was confirmed by the experimental values for the viscosity, density, saturated pressure, and surface tension of Ar, $N_2$, $CO_2$. The correlation coefficients of the empirical equations proposed in this work was higher than 0.99.

The Application of DLC(diamond-like carbon) Film for Plastic Injection Mold by Hybrid Method of RF Sputtering and Ion Source (RF 스퍼터링과 이온소스 복합방식에 의한 플라스틱사출금형(SKD11)의 DLC막 응용)

  • Kim, Mi-Seon;Hong, Sung-Pill
    • Journal of the Korean institute of surface engineering
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    • v.42 no.4
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    • pp.173-178
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    • 2009
  • DLC film was synthesized on plastic injection mold(SKD11, $30\;mm\;{\times}\;19\;mm\;{\times}\;0.5\;mm$) and Si(100) wafer for 2 h at $130^{\circ}C$ under 6 mTorr using hybrid method of rf sputtering and ion source. The obtained film was analysed by Raman spectroscopy, AFM, TEM, Nano indenter and scratch tester, etc. The film was defined as an amorphous phase. In the Raman spectrum, broad peak of $sp^2$-bonded carbon attributed to graphite at $1550\;cm^{-1}$ were observed, and the ratio of ID($sp^3$ diamond intensity)/IG($sp^2$ graphite intensity) was approximately 0.54. The adhesion of DLC film was more than 80 N with scratch tester when $0.2\;{\mu}m$ thickness Cr was coated as interlayer. The micro-hardness was distributed at 35~37 GPa. The friction coefficient was 0.02~0.07, and surface roughness(Ra) was 0.34~1.64 nm. The lifetime of DLC coated plastic injection mold using as a connector part in computer was more than 2 times of non-coated mold.

Estimation of Friction Characteristics of Wet-type Multiple Disc Brakes for Axle of 14 Ton Class Wheel Excavator (14톤급 휠 굴삭기 차축용 습식 다판 디스크 브레이크의 마찰특성 평가)

  • Cho, Yon-Snag;Park, Heung-Sik;Hong, Sung-Jin;Choi, Byeung-Woon;Bae, Myung-Ho
    • Tribology and Lubricants
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    • v.23 no.6
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    • pp.312-317
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    • 2007
  • In general, a brake system of axle for heavy duty machine as a wheel excavator makes use of wet-type multiple disk brakes. These disk bakes are very important parts of heavy duty machine because they are advanced in durability and braking power, and can be designed compactly. Thus, we designed and made wet-type multiple disk brakes of axle for the 14ton class wheel excavator to be localization of these imported all. These disk brakes were made a comparative test with the existing disk brakes by the SAE No.2 dynamometer, and the friction characteristics as dynamic and static friction coefficient and wear depth of friction paper were measured.

Tribological Properties of Co-Sputtered $MoS_2$ Films

  • Sagara, K.;Yamazaki, T.;Nishimura, M.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.145-146
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    • 2002
  • Tribological properties of co-sputtered Molybdenum disulfide $(MoS_2)/Carbon\;(C)$ films were studied and compared with those of sputtered $MoS_2$ films. Friction tests were carried out using pin-on-disk friction testers to evluated their friction and wear behaviors in a vacuum ($10^{-5}Pa$), air and humid air of 30, 50, 80% RH. $MoS_2/C$ (14%) composite films exhibited about 9 times longer wear life in a vacuum and about 6 times longer wear life in dry air than $MoS_2$ films did. They also showed stable low friction coefficient of about 0.02 in a vacuum. In humid air, however, $MoS_2/C$ composite films hardly showed good tribological properties.

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Ligand Based CoMFA, CoMSIA and HQSAR Analysis of CCR5 Antagonists

  • Gadhe, Changdev G.;Lee, Sung-Haeng;Madhavan, Thirumurthy;Kothandan, Gugan;Choi, Du-Bok;Cho, Seung-Joo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2761-2770
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    • 2010
  • In this study, we have developed QSAR models for a series of 38 piperidine-4-carboxamide CCR5 antagonists using CoMFA, CoMSIA and HQSAR methods. Developed models showed good statistics in terms of $q^2$ and $r^2$ values. Best predictions obtained with standard CoMFA model ($r^2$ = 0.888, $q^2$ = 0.651) and combined CoMSIA model ($r^2$ = 0.892, $q^2$ = 0.665) with electrostatics and H-bond acceptor parameter. The validity of developed models was assessed by test set of 9 compounds, which showed good predictive correlation coefficient for CoMFA (0.804) and CoMSIA (0.844). Bootstrapped analysis showed statistically significant and robust CoMFA (0.968) and CoMSIA (0.936) models. Best HQSAR model was obtained with a $q^2$ of 0.662 and $r^2$ of 0.936 using atom, connection, hydrogen, donor and acceptor as parameters and fragment size (7-10) with optimum number of 6 components. Predictive power of developed HQSAR model was proved by test set and it was found to be 0.728.