• Title/Summary/Keyword: coating area

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Receptor Model(CMB) and Source Apportionments of VOCs in Seoul Metropolitan Area (수용모델(CMB)을 이용한 수도권 VOCs의 배출원별 기여율 추정)

  • Han, Jin-Seok;Hong, Y.D.;Shin, S.A.;Lee, S.U.;Lee, S.J.
    • Journal of Environmental Impact Assessment
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    • v.14 no.4
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    • pp.227-235
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    • 2005
  • Source contribution for VOCs collected in Seoul metropolitan area was conducted using PAMs (Photochemical assessment monitoring system) data and CMB(Chemical Mass Balance) model8.0, in order to estimate spatial and temporal variations of VOCs source contribution in that area, and also to compare with corresponding emission inventory. VOCs data used in model calculation were collected at 6 different sites of PAMs(Seokmori, Guwoldong, Simgokdong, Bulgwangdong, Jeongdong and Yangpyeong) and 22 out of 56 VOCs species were analyzed from June 2002 to march 2003 and used for CMB model estimation. The result showed that vehicle exhaust, coating and energy combustion were important sources of VOCs in Seoul metropolitan area, averaging 32.6%, 25.5% and 25.1%, respectively. In this study as well as other references, it was revealed that vehicle exhaust is the main contributor of urban area VOCs, but there is remarkable contrast between emission inventory and model estimation. Vehicle exhaust portion is seriously underestimated while coating is usually overestimated in emission estimates, compared to CMB results. Therefore, it is considered to assert and confirm the uncertainty of emission estimates and clarify the distinction between two other source apportionment methods.

Preliminary Source Apportionment of Ambient VOCs Measured in Seoul Metropolitan Area by Positive Matrix Factorization (PMF를 이용한 수도권지역 VOCs의 배출원 추정)

  • Han J. S.;Moon K. J.;Kim R. H.;Shin S. A.;Hong Y. D.;Jung I. R.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.85-97
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    • 2006
  • The PAMS data collected at four sites in Seoul metropolitan area in 2004 were analyzed using the positive matrix factorization (PMF) technique, in order to identify the possible sources and estimate their contributions to ambient VOCs. Ten sources were then resolved at Jeongdong, Bulgwang, Yangpyeong, and Seokmo, including vehicle exhaust, LPG vehicle, petroleum evaporation, coating, solvent, asphalt, LNG, Industry & heating, open burning, and biogenic source. The PMF analysis results showed that vehicle exhaust commonly contributed the largest portion of the predicted total VOCs mass concentration, more than $30\%$ at four sites. The contribution of other resolved sources were significantly different according to the characteristics of site location. In the case of Jeongdong and bulgwang located in urban area, various anthropogenic sources such as coating, solvent, asphalt, residual LPG, and petroleum evaporation contributed about $40\%$ of total VOCs mass. On the other hand, at yangpyeong and Seokmo located in rural and remote area, the portion of these anthropogenic sources was reduced to less than $30\%$ and the contribution of natural sources including open burning and biogenic source clearly observed. These results were considerably corresponding to the emission inventory investigated in this region.

Polybenzimidazole (PBI) Coated CFRP Composite as a Front Bumper Shield for Hypervelocity Impact Resistance in Low Earth Orbit (LEO) Environment

  • Kumar, Sarath Kumar Sathish;Ankem, Venkat Akhil;Kim, YunHo;Choi, Chunghyeon;Kim, Chun-Gon
    • Composites Research
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    • v.31 no.3
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    • pp.83-87
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    • 2018
  • An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

Effects of Cobalt Protective Coating Prepared by DC Electroplating on Ferritic Stainless Steel for SOFC Interconnect (직류 전기도금을 이용한 고체산화물 연료전지 금속연결재용 페라이트계 스테인리스 스틸의 코발트 보호막 코팅 효과)

  • Hong, Jong-Eun;Lim, Tak-Hyung;Song, Rak-Hyun;Lee, Seung-Bok;Shin, Dong-Ryul;Yoo, Young-Sung;Lee, Dok-Yol
    • Journal of Hydrogen and New Energy
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    • v.20 no.2
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    • pp.116-124
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    • 2009
  • We investigated the influences of cobalt coating deposited by DC electroplating on the ferritic stainless steel, STS 430, as a protective layer on a metallic interconnect for SOFC applications. Cobalt coated STS 430 revealed a uniform and denser-packing oxide surface and a reduced growth rate of $Cr_2O_3$ scales after oxidation at $800^{\circ}C$in air. Cobalt coating layer was oxidized to $CoCo_2O_4$ and Co containing mixed oxide spinels such as $Co_2CrO_4$, $CoCr_2O_4$, and $CoCrFeO_4$. The area specific resistance value of Co coated sample was $0.020\;{\Omega}cm^2$ lower than that of uncoated at $800^{\circ}C$ in air during 500 h. After 1000 h oxidation, cobalt oxide coating layer suppressed chromium outward diffusion.

Experimental Study on Liquid Desiccant Distribution Characteristics at a Dehumidifier with Extended Surface (확장표면을 적용한 액체식 제습기에서 제습액 분배 특성에 관한 실험적 연구)

  • Lee, Min-Su;Chang, Young-Soo;Lee, Dae-Young
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.645-649
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    • 2009
  • Liquid desiccant cooling technology can supply cooling by using waste heat and solar heat which are hard to use effectively. For compact and efficient design of a dehumidifier, it is important to sustain sufficient heat and mass transfer surface area for water vapor diffusion from air to liquid desiccant on heat exchanger. In this study, the plate type heat exchanger is adopted which has extended surface, and hydrophilic coating and porous layer coating are adopted to enhance surface wettedness. PP(polypropylene) plate is coated by porous layer and PET(polyethylene terephthalate) non-woven fabric is coated by hydrophilic polymer. These coated surfaces have porous structure, so that falling liquid film spreads widely on the coated surface foaming thin liquid film by capillary force. The temperature of liquid desiccant increases during dehumidification process by latent heat absorption, which leads to loss of dehumidification capacity. Liquid desiccant is cooled by cooling water flowing in plate heat exchanger. On the plate side, the liquid desiccant can be cooled by internal cooling. However the liquid desiccant on extended surface should be moved and cooled at heat exchanger surface. Optimal mixing and distribution of liquid desiccant between extended surface and plate heat exchanger surface is essential design parameter. The experiment has been conducted to verify effective surface treatment and distribution characteristics by measuring wall side flow rate and visualization test. It is observed that hydrophilic and porous layer coating have excellent wettedness, and the distribution can be regulated by adopting holes on extended surface.

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Comparison of Coating and Pelleting Technique for Surface Sowing of Orchardgrass and Tall Fescue Seeds (겉뿌림을 위한 오차드그라스와 톨페스큐 종자의 코팅 및 펠렛팅 기술 비교)

  • Kim, Jong-Duk;Kwon, Chan-Ho;Chae, Sang-Heon;Kim, Jong-Kwan;Kim, Byong-Wan;Seo, Sung
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.27 no.4
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    • pp.281-286
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    • 2007
  • Surface sowing method is one of the important methods to establish seeds in mountainous area. Seed-coating technique in the surface sowing method is increasing interest in the world today. An experiment was conducted to develope a technique for pelleting seeds of grass in woodland. Results showed that the seed pelleting was a useful technique than coating seeds because the pelleting reduced coating time and increased amounts of coated seeds per hour. As lowering temperature and reducing time for drying, germinating energy and germination rate of pelleted seeds were improved. And emergence, establishment and early growth of pelleted were also improved in pasture under woodland. Based on this study, we could conclude that the seed pelleting is a useful technique for the establishment and early growth of grass under woodland.

Tailoring of the Chemical Resistance of Chrome Yellow Particles by Silica Coating (안료의 내약품성 향상을 위한 황연입자의 실리카 피복에 관한 연구)

  • Lee, Seewoo;Kim, Seongsoo;Kim, Dong-Uk;Wang, Lin;Choi, Heekyu
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.310-315
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    • 2008
  • Herein, we synthesized silica-coated chrome yellow particles having improved chemical resistance. The intermediate with a good dispersion stability was prepared and the chemical resistance of the final product was investigated. The effects of pH and temperature, as the main parameters influencing the formation of particles, the reduced particle size by homogenizer on the silica coating were investigated. The change in the particle morphology by temperature and pH was also studied. As the results, small and monodisperse particles were achieved at low pH and high temperature. Good silica coating was obtained when used reduced size of the particles by homogenizer. Furthermore, the sufficient silica coating by microencapsulation was obtained at 9~10 pH and the temperature above $90^{\circ}C$.

Recent Progress of Antibacterial Coatings on Solid Substrates Through Antifouling Polymers (박테리아 부착억제 고분자 기반 고체 표면의 항균 코팅 연구 동향)

  • Ko, Sangwon;Lee, Jae-Young;Park, Duckshin
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.371-378
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    • 2021
  • The formation of hydrophilic surface based on polymers has received great attention due to the anti-adhesion of bacteria on solid substrates. Anti-adhesion coatings are aimed at suppressing the initial step of biofilm formation via non-cytotoxic mechanisms, and surfaces applied hydrophilic or ionic polymers showed the anti-adhesion effect for bioentities, such as proteins and bacteria. This is attributed to the formation of surface barrier from hydration layers, repulsions and osmotic stresses from polymer brushes, and electrostatic interactions between ionic polymers and cell surfaces. The antifouling polymer coating is usually fabricated by the grafting method through the bonding with functional groups on surfaces and the deposition method utilizing biomimetic anchors. This mini-review is a summary of representative antifouling polymers, coating strategies, and antibacterial efficacy. Furthermore, we will discuss consideration on the large area surface coating for application to public facilities and industry.

A Study on Residual Stress Reduction Effect of Cold Spray Coating to Improve Stress Corrosion Cracking of Stainless Steel 304L and 316L Welds (STS304L 및 STS316L 용접부의 응력 부식 균열 개선을 위한 저온 분사 코팅의 잔류 응력 감소 효과에 대한 연구)

  • Kwang Yong Park;Deog Nam Shim;Jong Moon Ha;Sang Dong Lee;Sung Woo Cho
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.102-108
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    • 2023
  • A Chloride-induced stress corrosion cracking (CISCC) of austenite stainless steel in dry cask storage system (DCSS) can occur with extending service time than originally designed. Cold spray coating (CSC) not only form a very dense microstructure that can protect from corrosive environments, but also can generate compressive stress on the surface. This characteristic of CSC process is very helpful to increase the resistance for CISCC. CSC with several powders, such as 304L, 316L and Ni can be optimized to form very dense coating layer. In addition, the impact energy generated as the CSC powder collides with the surface of base metal at a speed of Mach 2 or more can remove the residual tensile stress of welding area and serve the compress stress. CSC layers include no oxidation and no contamination with under 0.2% porosity, which is enough to protect from the penetration of corrosive chloride. Therefore, the CSC coating layer can be accompanied by a function that can be disconnected from the corrosive environment and an effect of improving the residual stress that causes CISCC, so the canister's CISCC resistance can be increased.

The design of a single layer antireflection coating on the facet of buried channel waveguide devices using the angular spectrum method and field profiles obtained by the variational method (Variational 방법으로 구한 필드 분포와 Angular Spectrum 방법을 사용한 Buried채널 도파로 소자 단면의 단층 무반사 코팅 설계)

  • 김상택;김형주;김부균
    • Korean Journal of Optics and Photonics
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    • v.13 no.1
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    • pp.51-57
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    • 2002
  • We have calculated the optimum refractive index and normalized thickness of a single layer antireflection coating on the facet of buried channel waveguides as a function of waveguide width for several waveguide depths using the angular spectrum method and field profiles obtained by the effective index method (EIM) and the variational method (VM), respectively, and discussed the results. In the area of large waveguide width, the optimum parameters of a single layer antireflection coating obtained by both methods are almost the same. However, as waveguide width decreases, the parameters obtained by the VM approach those of a single layer antireflection coating between cladding layer and air, while those obtained by the EIM do not approach those, and the difference between the two parameters is large. The tolerance maps of the quasi-TE and quasi-TM modes obtained by the VM for square waveguides are located in almost the same area regardless of refractive index contrast, while those obtained by the free space radiation mode (FSRM) method for refractive index contrast of 10% are located in the different area. Thus, we think that the tolerance maps obtained by the VM are more exact than those obtained by the FSRM method.