• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.175-183
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• 2020

There have rarely been performed for the clay mineralogy of the East Sea sediments except for few studies about paleoenvironmental aspect. This study inferred the provenance of sediments based on the clay mineral characteristics and distribution pattern for the 120 sediment samples collected by the box corer from the Gangneung-Donghae area between 2017-2019. The relative proportions of the four major clay minerals are abundant in the order of illite, chlorite, kaolinite, and smectite. The continental shelf sediments below water depth 150 m have more chlorite and kaolinite content and better illite crystallinity, but less illite and smectite content, and S/I index than those of continental slope sediments. Clay mineral composition of the continental shelf sediments are influenced by the adjacent continental geology, because north site (Gangneung area) has more chlorite but south site (Donghae area) has more kaolinite. These characteristics and distribution pattern of clay minerals indicate that the provenance of sediments are different between continental shelf and continental slop. The continental shelf sediments may be introduced the study area by the adjacent small rivers whereas the continental slope sediment might be supplied by current from the south of the study area.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.4
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• pp.57-62
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• 2018

This study was designed to analyze the chemical composition and antioxidant activity of various vegetable oils (pumpkin seed oil, camellia seed oil, red pepper seed oil and peanut oil) using adsorbents (active carbon, acid clay, kaolin). Their chemical composition was analyzed by GCMS. Their antioxidant activity was evaluated by measuring their DPPH and ABTS radical scavenging activity. After the treatment with the adsorbents, the contents of most of the fatty acids and active ingredients contained in the four kinds of vegetable oils were reduced. After the treatment with the three adsorbents, the linoleic acid and erythrodiol contents of the pumpkin seed oil were reduced. In the case of the camellia seed oil, the fatty acids content was decreased, but there was no loss of vitamin E after the acid clay treatment. The content of the compound capsaicin, which forms part of the spicy component of red pepper seed oil, was reduced by 53.33% after the acid clay treatment. The peanut oil showed the lowest loss of sitosterol compound in the group treated with active carbon. The antioxidant activity was observed to be in the order of pumpkin seed oil (kaolin>acid clay>active carbon), camellia seed oil (acid clay>kaolin>active carbon), red pepper seed oil (kaolin>acid clay>active carbon) and peanut oil (active carbon>acid clay>kaolin).

• Korean Journal of Soil Science and Fertilizer
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• v.4 no.2
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• pp.187-192
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• 1971

This paper deals mainly with the genesis and classification of the Jeonnam series. These soils have brown to dark brown silt loam and silty clay loam A horizon(strong brown or reddish brown where eroded). Argillic B horizons are dominantly red or yellowish red silty clay loam to silty clay with moderately developed subangular blocky structure and with thin clay cutans on the ped faces. The C horizons are strongly and very deeply weathered strong brown, yellowish brown, pale brown and reddish yellow silty clay loam and sandy loam granitic saprolite. Content of clay increases with depth to a maximum between 100cm. Percolating water seems to be responsible for transportation and oriented deposition of clay. Chemically, soil reaction is strongly acid to medium acid throughout the profile. The content of organic matter is 1 to 2 percent, and decreases regularly with depth. Base saturation is low, based on amount of extractable cations. Characterisltically the Jeonnam series are similar to Red-Yellow Podzolic soils of the United States and are similar to Red-Yellow soils of the Japan. In the writer's opinion the Jeonnam soils are classified as Red Yellow soils. According to USDA 7th approximation, this soil can be classified as Typic Hapludults and in the FAO/UNESCO World Soil Map as Helvic Acrisols.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.03b
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• pp.639-646
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• 2000

It is important to estimate the mechanical properties of clay since it is directly related to the design and the construction of geotechnical structures. Site exploration, which is composed of boring, sampling, in-situ, or laboratory tests, is preformed to estimate the mechanical properties. However, mechanical properties of clay measured from laboratory test may be different from in-situ properties due to disturbances occurred during sampling, transportation, storage, and trimming. In this study, the degree of disturbance according to sampling method was estimated with the test results of CK/sub o/U triaxial compression test on Yangsan clay. The soil samples were obtained by three types of sampling method, j.e., 76mm-tube sampler, 76mm-piston sampler, and block sampler. In order to evaluate the quality of samples, volumetric strain, undrained shear strength, secant Young's modulus, and pore pressure coefficient at peak measured from each sample were compared with one another. From the test results, it was observed that mechanical properties of the block and piston samples were more reliable than those of tube samples. But it was observed that the water content of piston was similar to that of tube samples at given depths while the water content of block samples was 14.3∼15.8% smaller than that of piston and tube samples. In addition to the evaluation of the quality of samples, relationship between c/sub u// σ/sub vc/'and OCR was established from the results of the CK/sub o/U triaxial compression tests, which were carried out using SHANSEP method. And also undrained shear strength was analyzed using the in-situ test data such as Cone Penetration Test(CPT), Dilatometer Test(DMT), and Field Vane Test(FVT) and was compared with that evaluated from CK/sub o/U triaxial compression test.

• Polymer(Korea)
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• v.35 no.5
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• pp.402-408
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• 2011

To improve $Na^+$-saponite(SPT) film flexibility, we prepared SPT hybrid clay films with various poly(vinyl alcohol) (PVA) concentrations(0~10 wt%) using the solution intercalation method. In this study, we investigated the thermo-optical properties, morphology, and gas permeability of the SPT hybrid films. We also examined the relationship between the film properties and PVA content using wide angle X-ray diffraction measurements(XRD), field emission scanning electron microscopy(FESEM), differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), thermomechanical analysis(TMA), ultraviolet-visible(UV-vis) spectroscopy, and oxygen transmission rate($O_2$TR) testing. The properties of the clay hybrid films were strongly affected by PVA filler content. The presence of a small amount of PVA was sufficient to improve the flexibility of SPT hybrid films.

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.767-772
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• 2003

The clay which transported into a pond under the high water content condition have no effective stress which develop from the starting point of sedimentation and self-weight consolidation. Since sedimentation and self-weight consolidation dependent on self-weight of solids is made progress over a long time, to accelerating it have many advantages in the economic view In this paper, sand spreading method which is one of sedimentation and self-weight consolidation acceleration method is studied through a series of experiments considering the mixing ratio of sand and clay. The test results show that the mixing ratio of clay and sand of 1:0.2 is the biggest rate of consolidation and the pouring at the end point of sedimentation considerably effects on consolidation rate.

• Journal of the Korean Applied Science and Technology
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• v.20 no.3
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• pp.243-250
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• 2003

Poly(methyl methacrylate)/clay nanocomposite particles with particle size of 275${\sim}$292 nm range were successfully prepared using emulsion polymerization. The content of montmorillonite based on the methyl methacrylate monomer was chosen as 30 wt.%. 2,2-azobis(isobuthylamidine hydrochloride) and n-dodecyltrimethylammonium chloride were used as an initiator and a surfactant in cationic emulsion system. Potassium persulfate and sodium lauryl sulfate were used as an initiator and a surfactant in anionic emulsion system. The evidence of intercalated /exfoliated structure of montmorillonite in the nanocomposite prepared in our experiment was confirmed by wide angle x-ray diffraction patterns of $d_{001}$ plane. Thermal behavior of nanocomposite was traced using DSC and TGA. It was found that the nanocomposite particle prepared by cationic emulsion system showed intercalated structured. We also found that the nanocomposite particle obtained from anionic emulsion system resulted in the fully exfoliated structure.

• Korea-Australia Rheology Journal
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• v.16 no.4
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• pp.193-199
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• 2004

Poly(o-ethoxy)aniline (PEOA)/organoclay nanocomposite was prepared via a solvent intercalation using chloroform as a cosolvent with organically modified montmorillonite (OMMT) clay. The PEOA initially synthesized from a chemical oxidation polymerization in an acidic condition at pH = 1 was intercalated into interlayers of the clay with $25\;wt{\%}$ clay content. Electrical conductivity of the PEOA/OMMT nano­composite was found to be controlled via the intercalating process. The synthesized PEOA/OMMT nano­composite was characterized via an XRD and a TGA, and then adopted as an electrorheological (ER) material. The PEOA/OMMT synthesized with controllable electrical conductivity without a dedoping pro­cess was found to show typical ER characteristics possessing a yield stress from both steady state and dynamic measurements under an applied electric field.

• Macromolecular Research
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• v.8 no.3
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• pp.120-124
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• 2000

Clay-dispersed nanocomposites have been prepared by simple melt-mixing of two components, styrenic polymers with different content of functional groups and two different organophilic clays (Cloisite(R) 25A and Cloisite(R)30A) with a twin screw extruder. Dispersibility of 10-$\AA$-thick silicate layers of clay in the hybrid was investigated by using an X-ray diffraction method and a transmission electron microscope. It was found that if the interaction force between intercalant and matrix polymer is attractive, the matrix polymer intercalates more rapidly into the gallery of silicate layers. The faster intercalation of matrix polymer leads to the better dispersibility of silicate layers in the matrix polymer.

• Korea-Australia Rheology Journal
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• v.19 no.3
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• pp.133-139
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• 2007

Low density polyethylene nanocomposites were prepared by melt intercalating maleic anhydride grafted polyethylene and montmorillonite clay. It has been found that maleic anhydride has promoted strong interactions between polyethylene and montmorillonite, leading to the homogeneous dispersion of clay layers. Rheological experiments revealed that prepared nanocomposites exhibited shear thinning behaviour. Polyethylene nanocomposites exhibited an increase in steady shear viscosities compared to virgin polyethylene owing to strong polymer clay interactions. The tensile strength of nanocomposites was improved but elongation at break decreased considerably. Also, barrier properties improved significantly with montmorillonite content.