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Characterizations of Flexible Clay-PVA Hybrid Films: Thermo-optical Properties, Morphology, and Gas Permeability  

Shin, Ji-Eun (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Ham, Mi-Ran (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Kim, Jeong-Cheol (Gwangju R&D Center, Korea Institute of Industrial Technology)
Chang, Jin-Hae (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Publication Information
Polymer(Korea) / v.35, no.5, 2011 , pp. 402-408 More about this Journal
Abstract
To improve $Na^+$-saponite(SPT) film flexibility, we prepared SPT hybrid clay films with various poly(vinyl alcohol) (PVA) concentrations(0~10 wt%) using the solution intercalation method. In this study, we investigated the thermo-optical properties, morphology, and gas permeability of the SPT hybrid films. We also examined the relationship between the film properties and PVA content using wide angle X-ray diffraction measurements(XRD), field emission scanning electron microscopy(FESEM), differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), thermomechanical analysis(TMA), ultraviolet-visible(UV-vis) spectroscopy, and oxygen transmission rate($O_2$TR) testing. The properties of the clay hybrid films were strongly affected by PVA filler content. The presence of a small amount of PVA was sufficient to improve the flexibility of SPT hybrid films.
Keywords
saponite; poly(vinyl alcohol); hybrid; clay film;
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1 N. Ogata, S. Kawakage, and T. J Ogihara, J. Appl. Polym. Sci., 55, 119 (1995).   DOI   ScienceOn
2 G. Legaly, Appl. Clay Sci., 15, 1 (1999).   DOI   ScienceOn
3 A. Usuki, Y. Kojima, M. Kawasumi, A. Okada, Y. Fukushima, T. Kurauchi, and O. Kamigaito, J. Mater. Res., 8, 1179 (1993).   DOI   ScienceOn
4 K. S. Triantafyllidis, P. C. LeBaron, I. Park, and T. J. Pinnavaia, Chem. Mater., 18, 4393 (2006).   DOI   ScienceOn
5 J. W. Gilman, C. L. Jackson, A. B. Morgan, and R. Harris Jr., Chem. Mater., 12, 1866 (2000).   DOI   ScienceOn
6 A. Akelah, P. Kelly, S. Qutubuddin, and A. Moet, Clay Miner., 29, 169 (1994).   DOI   ScienceOn
7 D. J. Chaiko, Chem. Mater., 15, 1105 (2003).   DOI   ScienceOn
8 K. Haraguchi, M. Ebato, and T. Takehisa, Adv. Mater., 18, 2250 (2006).   DOI   ScienceOn
9 R. Vendamme, S.-Y. Onoue, A. Nakao, and T. Kunitake, Nature Mater., 5, 494 (2006).   DOI   ScienceOn
10 T. Ebina and F. Mizukami, Japanese Patent 3,855,003 (2006).
11 L. E. Neilson, J. Macromol. Sci., A1, 929 (1967).
12 J. Jang and D. K. Lee, Polymer, 45, 1599 (2004).   DOI   ScienceOn
13 E. P. Giannelis, Adv. Mater., 8, 29 (1996).   DOI
14 K. E. Strawhecker and E. Manias, Chem. Mater., 2, 2943 (2000).
15 W. Chiang and C. Min, J. Appl. Polym. Sci., 30, 4045 (1985).   DOI   ScienceOn
16 J. Wen, V. J. Vasudevan, and G. L. Wilkes, J. Sol-Gel Sci. Technol., 5, 115 (1995).   DOI   ScienceOn
17 K. Nakane, T. Yamashita, K. Iwakura, and F. Suzuki, J. Appl. Polym. Sci., 74, 133 (1999).   DOI   ScienceOn
18 W.-Y. Chuang, T.-H. Yong, W.-Y. Chiu, and C.-Y. Lin, Polymer, 41, 5633 (2000).   DOI   ScienceOn
19 I. Sakurada and M. Dekker, Poly(vinyl alcohol) fibers, Marcel Dekker, New York, 1985.
20 I. Cendoya, L. Lopez, A. Alegria, and C. J. Mijangos, J. Polym. Sci. Part B: Polym. Phys., 39, 1968 (2001).   DOI   ScienceOn
21 K. Nakane, T. Yamashita, K. Iwakura, and F. Suzuki, J. Appl. Polym. Sci., 74, 133 (1999).   DOI   ScienceOn
22 F. Suzuki, K. Nakane, and J. S. Piao, J. Mater. Sci., 31, 1335 (1996).   DOI   ScienceOn
23 J.-H. Yeun, G.-S. Bang, B. J. Park, S. K. Ham, and J.-H. Chang, J. Appl. Polym. Sci., 101, 591 (1999).
24 I. Cendoya, L. Lopez, A. Alegria, and C. Mijangos, J. Polym. Sci. Part B: Polym. Phys., 39, 1968 (2001).   DOI   ScienceOn
25 F. Suzuki, K. Nakane, and J. S. Piao, J. Mater. Sci., 31, 1335 (1996).   DOI   ScienceOn
26 G. Legaly, Smectitic Clays as Ionic Macromolecules, Elsevier, London, 1986.
27 P. C. LeBaron, Z. Wang, and J. P. Thomas, Appl. Clay Sci., 15, 11 (1999).   DOI   ScienceOn
28 Y. Kojima, A. Usuki, M. Kawasumi, and A. Okada, J. Mater. Res., 8, 1185 (1993).   DOI
29 P. B. Messersmith and E. P. Giannelis, Chem. Mater., 5, 1064 (1993).   DOI   ScienceOn
30 K. Yano, A. Usuki, T. Karauchi, and O. Kamigaito, J. Polym. Sci. Part A: Polym. Chem., 31, 2493 (1993).   DOI   ScienceOn
31 J.-H. Chang, T. G. Jang, K. J. Ihn, W. K. Lee, and G. S. Sur, J. Appl. Polym., Sci., 90, 3208 (2003).   DOI   ScienceOn
32 J. W. Gilman, Appl. Clay Sci., 15, 31 (1999).   DOI   ScienceOn
33 S.-K. Ham, M. H. Jung, and J.-H. Chang, Polymer(Korea), 30, 298, (2006).
34 R. Y. Huang and J. W. Rhim, Polym. Int., 30, 129 (1993).   DOI
35 M. Levine, G. Iikka, and P. Weis, J. Polym. Sci. Part B: Polym. Chem., 2, 915 (1964).   DOI
36 B. S. Dupont and N. Bilow, US Pat. 4,592,925 (1986).
37 T. Ebina and F. Mizukami, Adv. Mater., 19, 2450 (2007).   DOI   ScienceOn
38 H.-J. Nam, R. Ishii, T. Ebina, and F. Mizukami, Mater. Lett., 63, 57 (2009).
39 H. Tetsuka, T. Ebina, T. Tsunoda, H. Nanjo, and F. Mizukami, Surface & Coatings Technology, 202, 2955 (2008).   DOI   ScienceOn
40 H. Tetsuka, T. Ebina, T. Tsunoda, H. Nanjo, and F. Mizukami, Jpn. J. Appl. Phys., 47, 1894 (2008).   DOI
41 A. L. Landis and A. B. Naselow, US Pat. 4,645,824 (1987).
42 K. Higashi and Y. Noda, Eur. Pat. 240249 (1986).
43 T. Matsuura, S. Ando, S. Sasaki, and F. Yamamoto, Electron Lett., 29, 2107 (1993).   DOI   ScienceOn
44 H.-J. Nam, R. Ishii, T. Ebina, and F. Mizukami, Mater. Lett., 63, 57 (2009).
45 J. H. Suh, J. W. Shin, H. K. Kim, H. S. Kim, Y. W. Kim, and H.-J. Kang, Polymer, 34, 564 (2010).
46 W. Zhang, X. Yanga, C. Li, M. Lianga, C. Lu, and Y. Deng, Carbohydr. Polym., 83, 261 (2011).
47 J. Lu, T. Wang, and L. T. Drzal, Composites: Part A, 39, 745, (2008).
48 D. Jarus, A. Hiltner, and E. Baer, Polymer, 43, 2401 (2002).   DOI   ScienceOn
49 C. Joly, M. Smaihi, L. Porcar, and R. D. Noble, Chem. Mater., 11, 2331 (1999).   DOI   ScienceOn
50 T. Ebeling, S. Norek, A. Hasan, A. Hiltner, and E. Baer, J. Appl. Polym. Sci., 71, 1461 (1999).   DOI   ScienceOn
51 D. H. Weinkauf and D. R. Paul, in Effect of Structural Order on Barrier Properties, W. J. Koros, Editor, American Chemical Society, Washington, DC, 1990.