• Title/Summary/Keyword: citric acid solution

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Reinforcement of Calcium Phosphate-Calcium Sulfate Injectable Bone Substitute Using Citric Acid and Hydroxypropyl-Methyl-Cellulose

  • Thai, Van Viet;Kim, Min-Sung;Song, Ho-Yeon;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.45.1-45.1
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    • 2009
  • In this study, we investigated a calcium phosphate-calcium sulfate injectable bone substitute (IBS) with organic reinforcement of chitosan, citric acid and hydroxypropyl-methyl-cellulose (HPMC). The powder component of IBS consisted of tetra calcium phosphate (TTCP), dicalcium phosphate dihydrate (DCPD) and calcium sulfate dihydrate (CSD). The liquid component was a solution of citric acid and chitosan. The effect of HPMC in terms of setting time, compressive strength and apatite forming ability on this IBS was investigated. The mass content of HPMC in liquid phase was varied in array of 0%, 2%, 3% and 4%. The setting times obtained between 20 and 45 minutes. Compressive strength was achieved over 20 MPa after incubation at 370C and in 100% humidity for 28 days. Porosities were evaluated in relation with compressive strength. Elastic moduli of the 28 days after-incubation IBS were obtained around 4GPa

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Effects of Some Organic Acids on Shelf Life and Textural Properties of Cooked Noodle (유기산이 숙면의 저장성 및 물성에 미치는 영향)

  • Cha, Wook-Jin;Kim, Kong-Hwan
    • Applied Biological Chemistry
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    • v.41 no.2
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    • pp.166-174
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    • 1998
  • The effects of some organic acids on the shelf life of cooked noodle and the change in textural properties were studied. Organic acids used were vinegar, lactic, citric and malic acid. The pH of noodle was adjusted to $4.7{\pm}0.25$ by dipping it in each solution for 30 seconds. Total microbial count and turbidity of the treated samples were measured storage for 4 days at $15^{\circ}C$. The total count was high in order of control, malic, citric, lactic acid and vinegar. High turbidity was observed in order of control, lactic, malic, citric acid and vinegar. Hardness, adhesiveness, cohesivenes and springiness were measured for 30 days at $35^{\circ}C$ using Rheometer along with concurrent sensory evaluation. The acid treated samples showed higher values in hardness and cohesiveness than control but lower in adhesiveness and springiness. After 30 days storage, the malic or citric acid treated sample led to a somewhat higher gumminess than control. Based on the sensory evaluation the malic acid treated noodle significantly exhibited the highest score followed by citric, lactic acid, control and vinegar.

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Recovery of Cu and Sn from the Bioleaching Solution of Electronic Scrap (전자(電子)스크랩의 미생물(微生物) 침출액(浸出液)으로부터 구리 및 주석의 회수(回收)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Kim, Meong-Woon;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.15 no.6 s.74
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    • pp.41-47
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    • 2006
  • A study for recovering of copper and lead from electronic scraps has been carried out using a combination of bioleaching and solvent extraction. It was found that the citric acid generated by Aspergillus niger could be an imporant leaching agent acting in the solubilization of copper, iron, lead and tin from the electronic scrap. Copper could be selectively extracted by 10% LIX84 from the leaching solution and it recoved 99.9% of metallic copper by electrowinning process. Tin and iron were extracted from the remaining solution by 10% Alamine336 and stripped by NaCl solution. Finally, tin could be recovered as a metallic precipitates from the mixed solution of tin and iron by cementation with iron powder.

Characteristics of Semi-Aqueous Cleaning Solution with Carboxylic Acid for the Removal of Copper Oxides Residues (산화구리 잔유물 제거를 위한 카르복시산 함유 반수계 용액의 세정특성)

  • Ko, Cheonkwang;Lee, Won Gyu
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.548-554
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    • 2016
  • In this study, semi-aqueous solutions containing carboxylic acids such as oxalic acid (OA), lactic acid (LA) and citric acid (CA) were formulated for the removal of copper etching residues produced at the interconnection process, and their characteristics were analyzed. Carboxylic acids in the solutions were apt to form various copper complexes according to the value of pH. Semi-aqueous solution containing 10 wt% CA showed the lowest etching rate of copper in the range from pH2 to pH7 and the highest selectivity in the range of pH 2 to pH 4. However, the cleaning solution containing 10 wt% LA revealed the superior selectivity at the range from pH 5 to pH 7. Appropriate selection of carboxylic acid should be required to improve the performance of cleaning solution. In the case of CA, the etching selectivity of copper oxide complex to copper was increased with the concentration of CA in the solution, when the solutions contain over 5 wt% CA, the copper interconnection layer has a metallic copper surface more than 88% in the area. The result shows that CA contained semi-aqueous solution has a relatively good cleaning ability.

Quality Characteristics of Minimally Processed Sweet-pumpkin during Storage (최소가공 단호박 (Cucurbita maxima Duchesne) 제품의 저장 중 품질 특성)

  • 이진숙;박연주;황태영;김인호;김수일;문광덕
    • Food Science and Preservation
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    • v.10 no.1
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    • pp.6-10
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    • 2003
  • The objective of this study was to investigate the effect of browning inhibitor and vacuum packaging on minimally processed sweet pumpkin. The browning inhibitor were lo/e of ascorbic acid, citric acid, NaCl, MgCl$_2$and their combination. For the minimal processing, sweet pumpkin was sliced and strip-cut followed by dipping in the solution of browning inhibitor. Effective browning inhibitors fer slice sweet pumpkin were ascorbic acid, NaCl and MgC1$_2$, and those fer thin strip were combination and ascorbic acid. The hardness of minimally processed sweet-pumpkin repeated increasing and decreasing and decreased in the final of storage. However the change pattern of hardness was different according to cutting method. Magnesium chloride treatment was generally high grade on sensory characteristics. Sweet pumpkin treated with citric acid was distinguished on carbon dioxide generation and oxygen exhaustion.

Effect of Ferric and Ferrous Iron Irrigation on Brown-Colored Symptom of Leaf in Panax ginseng C. A. Meyer (산화철과 환원철이 인삼의 갈반형 황증 발생에 미치는 영향)

  • Lee, Sung Woo;Park, Kee Choon;Lee, Seung Ho;Jang, In Bok;Park, Kyung Hoon;Kim, Mi Lan;Park, Jin Myeon;Kim, Ki Hong
    • Korean Journal of Medicinal Crop Science
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    • v.22 no.1
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    • pp.32-37
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    • 2014
  • To study the cause of physiological disorder in leaf of ginseng cultivated at paddy soil, the degree of brown-colored symptom (BCS) and the contents of inorganic matter in leaf were investigated by irrigating the solution of ferric and ferrous iron of 0.1 ~ 2.0%, and citric acid of 1.0 ~ 4.0% on bed soil, respectively. Ratio of BCS by variety was as high as 85.0% in Yoenpoong, while it was as low as 5.4%, 7.5% in Chunpoong and Hwangsook, respectively. The contents of inorganic matter of leaf in Yoenpoong were lower in $P_2O_5$, Ca, and Mg, while it were higher in K, Fe, and Mn than other variety. Iron solution caused BCS more distinctly when each ferric and ferrous iron were dissolved with 1.0% citric acid than when each iron was dissolved without citric acid. Ferric iron caused BCS more effectively than ferrous iron. BCS occurred in 4.0% citric acid was as same as 2.0% ferric iron mixed with 1.0% citric acid. Low $P_2O_5$ and high Fe content in leaf appeared in both of artificial and natural symptoms. We concluded that excessive Fe uptake caused BCS to leaf because the solubility of iron was increased in condition of low soil pH.

Citric Acid Production from Glucose and Pumpkin by Using Immobilized Bead of Aspergillus niger (고정화 Aspergillus niger Bead를 이용한 포도당과 호박으로부터 구연산 생성)

  • 방병호
    • The Korean Journal of Food And Nutrition
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    • v.13 no.4
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    • pp.328-333
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    • 2000
  • The spore of Aspergillus niger KCTC-6144 was immobilized on alginate gel beads. When pumpkin powder was used with glucose for a medium of citric acid fermentation by Aspergillus niger beads, the beaded Aspergilus niger grew up inside the bead and mycelia penetrated through the pore of the bead membrane. The bead size became largely from 2.0∼2.5mm to 6∼8mm after growing at 30$\^{C}$ for 4 days. Studies of optimum culture conditions on citric acid fermentation using Aspergillus niger beads on pumpkin medium (pumpkin powder 1% +glucose 7%, pH 6.0) were carried out in submerged cultures on 250m1 Erlenmeyer flask. As a result, it was found that to reinforce 12% as carbon source was good for citric acid production and that 1% pumpkin powder was good as nitrogen and mineral source in orbital shaker (150rpm) at 30$\^{C}$ for 5 days. The optimum initial pH on citric acid production was pH 6.0 and it was found that 100 beads of immobilized Aspergillus niger was adequate for citric acid production in a 250ml Erlenmeyer flask containing 50m3 of pumpkin medium solution with orbital shaker at 30$\^{C}$ for 5 days. We also found that maximal production of citric acid was 23.5g/ℓ at optimal condition (at 30$\^{C}$ for 5 days, pH 6.0, and 100 beads and medium containing 1% pumpkin powder plus 12% glucose).

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The effects of tetracycline gel with and without citric acid on periodontally diseased root surface - in vitro study (테트라싸이클린 젤 및 구연산함유 테트라싸이클린 젤의 도포가 치주염에 이환된 치근표면에 미치는 영향에 관한 실험 연구)

  • Choi, Kwang-Choon
    • Journal of Periodontal and Implant Science
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    • v.23 no.2
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    • pp.219-227
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    • 1993
  • The purpose of the present study was to evaluate the effects of 5% tetracycline(Tc) with or without citric acid on periodontally diseased root surfaces. Six single-rooted teeth extracted from one patient was selected and received thorough scaling and root planning, followed by saline irrigation. Each one tooth was divided into eight fragments with a thin separating disc. Total 48 fragments were prepared and setted into 4 groups for this study. Group I (control group)were treated with saline. Group II were treated with 5% Tc gel. Group III were treated with 33% citric acid-5% Tc gel. Group IV were treated with Tc solution. All the specimens are evaluated under Scanning Electron Microscope(SEM). Group I showed large amount of debris in spite of thorough scaling and root planing, but Group II, III & IV showed clean and soft root surface texture. In higher magnification(x3, 000), Group II, III & IV showed nunmerous dentinal tubules, especially Group IV showed collagen fibrils. In the present study, Tc gel and Tc gel with citric showed clinically successful result when treated on periodontally diseased root surface, in vitro.

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The Effect of Citric Acid and Sodium Chlorite Mixtures on the Growth of Microorganisms from Broiler Thigh Surface (구연산과 아염소산나트륨 혼합물이 육계 넓적다리 표면의 미생물 증식에 미치는 영향)

  • 김태현;이영현
    • Food Science of Animal Resources
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    • v.22 no.1
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    • pp.44-49
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    • 2002
  • The effect of citric acid and sodium chlorite(NaClO$_2$) mixtures at 100, 200 and 500 ppd(w/v) on the growth of microorganisms from broiler thigh surface was investigated. Absorbance and aerobic plate counts(APC) of inoculated nutrient broth refrigerated storage at 4∼5$^{\circ}C$ were measured after each additive was added. APC on thigh surface after immersion in each selected solution was enumerated during storage at 4∼5$^{\circ}C$ Absorbance of all citric acid and sodium chlorite mixture(0:100, 25:75, 50:50, 75:25 and 100:0, w/w) except 200 and 500 ppm of 100:0 at Day 0 were lower than the control during storage (p<0.05). And higher concentration of mixture tended to have lower absorbance. APC on thigh surface treated with 500 ppm citric acid and sodium chlorite mixture at 50 : 50 and 75 : 25 ratio were lower than others (p<0.05). Similar antimicrobial activity of additives was found in nutrient broth and on broiler thigh surface.

Studies on the Combustion of Anthracite (III). Studies on the Utilization of the Anthracite Ash (無煙炭 燃燒에 對한 硏究 (第3報). 灰分의 利用에 對한 硏究)

  • Shin Byung-Sik;Shin SeI-Kun
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.252-257
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    • 1975
  • This experimental study was carried out to examine the utilization of the anthracite ash as a fertizer. It was found that the ash had very small amount of the soluble matters in 2% citric acid solution therefore it is proved ineffective as a fertilizer. When the small amount of calcinated dolomite was added to the anthracite, it was observed that the resulting ash showed much increased solubility of magnesium, calcium, sulfur and silica etc in the citric acid solution. So it is concluded that the ash of the mixture of anthracite and calcinated dolomite would be one of the useful soil-conditioner and supplyer of nutrients.

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