• Title/Summary/Keyword: chemical weathering

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Long Term Stability of Slopes Excavated in Weathered Granite Rock Masses Subjected to Extreme Climatic Conditions (극한 기후 조건하에서 풍화된 화강암반 절취사면에 대한 장기적 안정성 연구)

  • Yang, Kwang-Yong;Park, Yeon-Jun;You, Kwang-Ho;Woo, Ik;Park, Chan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.655-662
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    • 2003
  • Slope stability is an important issue ill civil engineering works or in open pit mines where both economy and efficiency is required. These are the long-term stability problems which depend on the change of physical properties under a certain weather condition. These can also result in progress of weathering which can change mechanical or hydro-geological properties of rock mass considerably. In this study, weathering in nature was simulated by freeze-thaw test and Soxhlet test which represent mechanical and chemical weathering respectively. Measured were elastic wave velocities, absorption rate, volume change. Uniaxial compression strengths before and after the weathering tests were also measured. The change in weight and volume of the specimens were not clearly related to the weathering process, but P, S wave velocities were clearly decreased as weathering progresses. For some class of rocks, P-wave velocity was increased probably because of the saturation due to improved connectivity of the pre-existing pores. Based on the test results, stability of the slopes were analyzed using FLAC$\^$2D/. Due to the reduced strength parameters, the factors of safety were decreased for the selected sites.

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A Case Study on Geotechnical Properties and Weathering Degree of Weathered Granite Rock (화강 풍화암의 지반특성 및 풍화도 평가에 대한 사례 연구)

  • Lee, Seung-Hwan;Yoo, Byeong Soo;Chung, Choong-Ki
    • Journal of the Korean Geotechnical Society
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    • v.33 no.12
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    • pp.127-139
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    • 2017
  • Site investigation including boring and various in-situ borehole test (Pressuremeter test, Borehole shear test, Downhole test, Suspension PS logging, Density logging) and X-ray fluorescence analysis for rock core sample were performed to estimate geotechnical properties and weathering degree of weathered granite rock in Goyang. Deformation modulus, shear strength parameter and shear wave velocity estimated through in-situ borehole test had a tendency to increase with depth. And several chemical weathering indices evaluated by X-ray fluorescence analysis had a general tendency of reducing weathering degree in accordance with depth. Also, relationship between VR determined as a representative weathering index and the geotechnical properties was analyzed.

Outcomes and Tasks of the Research on Weathering pitsin Korea - The Case of Tafoni and Gnamma - (한국의 풍화혈 연구 성과와 과제 - 타포니·나마를 중심으로 -)

  • Park, Ji-Sun;Kwon, Dong-Hi
    • Journal of The Geomorphological Association of Korea
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    • v.20 no.4
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    • pp.37-50
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    • 2013
  • This study analyzes results of published studies of weathering pits in Korea focusing on tafoni and gnamma and it suggests new types of weathering pits and next subjects through the analysis. 34 papers, published between 1978 and February 2012, have been analyzed and the following are details of the analysis. In terms of the study results, weathering pits are commonly developed on coarse-grained rocks such as granite, but also found on various rocks. Multiple reasons including mechanical, chemical and salt weathering create weathering pits and they are closely related to the geological structure. Weathering pits are classified as tafoni and gnamma but the forms have not been verified. In the future, quantitative analysis must be conducted find the factors influencing creation, forms and development of weathering pits.

Modeling of Geochemical Variations and Weathering Depth on the Surface of Pelitic Rocks in Periodical Submerging Zone: Bangudae Petroglyphs (주기적 침수구역 이질암 표면의 지구화학적 변화와 풍화심도 모델링: 반구대 암각화)

  • Chan Hee Lee;Yu Gun Chun
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.583-596
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    • 2022
  • The rock surface of Bangudae petroglyphs is mainly dark brown hornfelsified shales by contact metamorphism. The surface form a weathered layer of a invariable depth, and there is a difference with mineral and chemical composition between weathered and non-weathered layers. Surface of the petroglyphs has been discolored to light brown over the face due to biological and chemical weathering. As the measuring chromaticity based on the non-weathered layer, the whiteness and yellowness increased in the weathered layer, and the color difference (ΔE) was 5.54 to 36.89 (mean 17.26). In the weathered layer of the petroglyph surface, the CaO content was reduced by about 90% compared to the non-weathered layer, and Sr also showed the same trend. In particular, the mean porosity of the non-weathered layer was 0.4%, but it was estimated as 25.0% in the weathered layer. This is interpreted as the fact that calcite reacts with water, and forms a weathered layer from the surface as it is eluted. Based on the weathering depth modeling of the petroglyphs using the penetration characteristics of X-rays, the weathering depth of rock faces was found to be 1 to 2mm. However, the area classified as 2mm or more estimated to be a maximum of 3 to 4mm, considering the weathering depth around the petroglyphs surface.

Variations of Clay Mineral Assemblage, Colour, and Microfossil Abundance in the Tertiary Sediments from the Pohang Area During Chemical Weathering (포항지역(浦項地域) 제(第)3기층(紀層) 퇴적암(堆積岩)중 화학적풍화작용(化學的風化作用)이 결토광물조성(結土鑛物組成), 화학조성(化學組成), 암색(岩色) 및 미화석(微化石) 산출빈도(産出頻度)에 미치는 영향)

  • Moon, Hi-Soo;Yun, Hyesu;Min, Kyung Duck;Lee, Hyun Koo;Lee, Jong Chun
    • Economic and Environmental Geology
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    • v.23 no.2
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    • pp.201-213
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    • 1990
  • Mineralogy, chemistry, physical property, and fossil abundance have been studied for the samples collected from three weathering profiles, two from the Duho Formation and one from the Hagjeon Formation in the Tertiary sediments in the Pohang area. The mineralogy of the samples from the Duho Formation shows somewhat different from that of the Hagjeon Formation. Kaolinite is more abundant and shows higher crystallinity in samples from the Duho Formation than those in the Hagjeon Formation, but clay mineral assemblage in each weathering profile remain fairly constant with depth. This difference in mineral distribution seems to be inherited from original source materials. It indicates that little or not severe leaching has been taking place in these three weathering profiles. Weathering indicies indicate different degrees of susceptibility to chemical weathering in these two formations. The Duho Formation has a higher degree of susceptibility to weathering than that of the Hagjeon Formation which is mainly due to differences in clay mineral assemblages in both formations. A noticeble colour difference between oxidized and unoxidized zones in each profile can be easily recognized which is definetely due to different decomposition rate organic carbon by various oxidation state from surface to bottom of the profile. Weathering process have also intensively influenced microfossil preservation about up to 7-10 m in depth in the Duho Formation. Consequently, characteristics observed at weathering surface should be used as a subsidiary tool in setting geologic boundary or establishing formation. Great care must be taken to choose sampling site for microfossil study.

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Effects of Evaporation on the Weathering Rate and Chemical Composition of Iranian Heavy Crude Oil (이란산 원유의 증발에 따른 풍화율 및 화학적 성상 변화)

  • Kim, Beom;Kim, Gi-Beum;Sim, Won-Joon;Yim, Un-Hyuk
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.3
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    • pp.238-246
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    • 2012
  • Once oil is spilled into marine environment, it experiences various weathering processes among which evaporation is the most dominant process in the initial stage of weathering. This study aimed to elucidate the effects of evaporation on the physicochemical properties of spilled oil using standardized laboratory experiments. Laboratory evaporation process was successfully reproduced using controlled rotary evaporation method. In case of Iranian Heavy crude (IHC), evaporation rate after 48 hours was $29.3{\pm}0.4%$ (n=40, p<0.001). Evaporation was simulated using ADIOS2 weathering model and the result was in agreement with laboratory experiment. Chemical composition changes of petroleum hydrocarbons including alkanes, polycyclic aromatic hydrocarbons (PAHs) and biomarkers by evaporation rate were also analyzed. As oil evaporated, low molecular weight alkanes and PAHs decreased, while biomakers showed conservative characteristics. Among biomarkers, $17{\alpha}(H)$, $21{\beta}(H)$-hopane was used for calculation of weathering rates, which matched with evaporative mass losses. Weathering rate calculation using hopane showed that stranded oils of weathering stage I (28.9%) and mesocosm oil weathering experiment till 5 days (26.5%) were mainly affected by evaporation process.

Petrological Studies of the Buddha Image Carved on Rock Surface at the Gyeongju Namsan Area, Korea - A Case Study of the Seated Buddha Image Carved on Rock Surface of Yuneulgok in Bae-ri, Gyeongju - (경주 남산 마애불 암석의 물리적 특성연구 - '경주배리윤을곡마애불좌'을 중심으로 -)

  • Song, Chi-young;Han, Min-su;Lee, Jang-jon;Jun, Byung-kyu
    • 보존과학연구
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    • s.28
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    • pp.39-58
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    • 2007
  • The Seated Buddha image carved on rock surface of Yuneulgok in Bae-ri, Gyeongju constituted of alkali feldspar granite. There is surface weathering by abrasion, exfoliation and break out. As a result various experiment was carried out testing rock material property to quantitatively grade weathering. Besides, this study is focused on properties of rock and correlation between things. Additionally, comparison of chemical properties to nondestructive weathering grade in the buddha image carved on rock. This result utilized on important resource for scientific conservation system compared with weathering appearance.

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Weathering Sensitivity Characterization for Rock Slope, Considering Time Dependent Strength Changes (시간에 따른 강도변화를 고려한 암반사면의 풍화민감특성 분석)

  • Lee Jeong-Sang;Bae Seong-Ho;Yu Yeong-Il;Oh Joung-Bae;Lee Du-Hwa;Park Joon-Young
    • Tunnel and Underground Space
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    • v.16 no.2 s.61
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    • pp.109-134
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    • 2006
  • Rocks undergo weathering processes influenced by changing in pressure-temperature condition, atmosphere, underground water, and rainfall. The weathering processes change physical and chemical characteristics of the rocks. Once the rocks are weathered, the characteristics of them are changed and, because of the changing, several disadvantages such as rock slope failures and underground water spouts are can occur. Before we cut a large rock slope, therefore, we must analyze current weathering conditions of rocks and predict weathering processes in the future. Through the results of such analyses, we can judge reinforcement works. In order to comply with such requests, chemical weathering sensitivity analysis which was analyzed from chemical weathering velocities and other characteristics of rocks has been applied in several prior construction works in Korea. But, It is defective to use directly in engineering fields because it was developed for soils(not rocks), it has too mny factors must be considered and the relationships between the factors are not clear, and it is hard to explain the weathering processes in engineering time range. Besides above, because it has been used for isotropic rocks, this method is hard to apply to anisotropic rocks such as sedimentary rocks. Acceding to studies from morphologists (e.g. Oguchi et al., 1994; Sunamura, 1996; Norwick and Dexter, 2002), time dependent strength reduction influenced by weathering shows a negative exponential function form. Appling this relation, one can synthesize the factors which influence the weathering processes to the strength reduction, and get meaningful estimates in engineering viewpoint. We suggest this weathering sensitivity characterization method as a technique that can explain time dependent weathering sensitivity characteristics through strength changes and can directly applied the rock slope design.

The Weatherability and Chemical Resistance of CFRP (탄소섬유판 복합재료의 내후성/내화학성에 관한 연구)

  • 최영철;윤희석
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.151-154
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    • 2002
  • The durability of two kinds of CFRP plates, carbon/UP and carbon/V, was studied under severe environmental conditions. Immersion into the chemical solutions and accelerated weathering were executed on the CFRP plates and the weight change under each condition was measured. After those treatments, the plates were tested by tensile testing machine to measure the mechanical properties and observed by SEM to find the damage behaviour of the surface. Comparing the virgin plates and the chemically exposed plates, both plates show severe deterioration of the mechanical properties. But, the plates subjected to alkali solution show much larger reduction than those of acidic solution and carbon/V has better chemical resistance than carbon/UP. The material properties of CFRP plate exposed to the weathering were deteriorated linearly proportional to the exposure time.

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The Study on Weathering Hollows Developed on the Coast of Dapyeong-ri, Sacheon-si (사천시 다평리 해안에서 발달한 풍화혈에 관한 연구)

  • Tak, Hanmyeong
    • Journal of the Korean Geographical Society
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    • v.50 no.5
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    • pp.459-472
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    • 2015
  • Weathering hollows which develop on various rocks are the terrain whose lithological characteristics and formation of the bed rock is under active discussion. The shore in Dapyeong-ri, Sacheon-si has alternation of strata of pelite and sandstone, and the weathering hollows develop on the shore platform and the sea cliff where sandstone is exposed. To analyze the development characteristics of weathering hollows by development of joints, interpenetration of veins and physical and chemical features of the stone, the study conducted a topographic investigation, XRD analysis and an observation using a polarizing microscope. As the result of the investigation and analysis, tafoni and gnamma are spread in the same area and new tafoni is being formed as the existing weathering hollows are destroyed by the expansion and growth of the joint. The vein, which was found to be a quartz vein, may accelerate the development of weathering hollows combining with the joint but may also hamper their growth if the veins are penetrating perpendicularly. It is generally known that weathering hollows develop regardless of the type of rocks, however, the analysis on the lithological features show that the development is limited on the fractured and broken rocks.

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