• Title/Summary/Keyword: chemical light

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Long-Term Shelf Lifetime of Polymer:Nonfullerene Solar Cells Stored under Dark and Indoor Light Environment

  • Lee, Sooyong;Kim, Hwajeong;Kim, Youngkyoo
    • Current Photovoltaic Research
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    • v.8 no.4
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    • pp.107-113
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    • 2020
  • Here we report the long-term stability of polymer:nonfullerene solar cells which were stored under dark and indoor light condition. The polymer:nonfullerene solar cells were fabricated using bulk heterojunction (BHJ) layers of poly[(2,6-(4,8-bis(5-(2-ethylhexyl) thiophen-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(6-methyl-2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). To investigate their long-term stability, the PBDB-T:IT-M solar cells were stored in an argon-filled glove box. One set of the fabricated solar cells was completely covered with an aluminum foil to prevent any effect of light, whereas another set was exposed to indoor light. The solar cells were subjected to a regular performance measurement for 40 weeks. Results revealed that the PBDB-T:IT-M solar cells underwent a gradual decay in performance irrespective of the storage condition. However, the PBDB-T:IT-M solar cells stored under indoor light condition exhibited relatively lower power conversion efficiency (PCE) than those stored under the dark. The inferior stability of the solar cells under indoor light was explained by the noticeably changed optical absorption spectra and dark spot generation, indicative of degradations in the BHJ layers.

Solution-processible corrugated structure and scattering layer for enhanced light extraction from organic light-emitting diodes

  • Hyun, Woo Jin;Im, Sang Hyuk;Park, O Ok;Chin, Byung Doo
    • Journal of Information Display
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    • v.13 no.4
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    • pp.151-157
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    • 2012
  • A simple method of fabricating out-coupling structures was demonstrated via solution-processing to enhance light extraction from organic light-emitting diodes (OLEDs). Scattering layers were easily obtained by spin-coating an $SiO_2$ sol solution that contained $TiO_2$ particles. By introducing the scattering layer and the solution-processible corrugated structure as internal and external extraction layers, the OLEDs showed increased external quantum efficiency without a change in the electroluminescence spectrum compared to conventional devices. Using these solution-processible out-coupling structures, nearly all-solution-processed OLEDs with enhanced light extraction could be fabricated. The light extraction enhancement is attributed to the suppression by the out-coupling structures of the light-trapping that arose at the interface of the glass substrate and the air.

Effect of Water Addition on the Conversion of Dimethyl Ether to Light Olefins over SAPO-34 (SAPO-34 촉매상에서 디메틸에테르로부터 경질올레핀 제조 및 물의 첨가 효과)

  • Baek, Seung-Chan;Lee, Yun-Jo;Jun, Ki-Won
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.345-349
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    • 2006
  • Conversion of DME (dimethyl ether) or methanol to light olefins (ethylene, propylene, butenes) over SAPO-34 were systematically studied, where it was observed that DME was dehydrated to light olefins and partially converted to by-products such as CO and $CO_2$ at various reaction temperatures on the time-on-stream. SAPO-34 catalyst during the DTO (dimetyl ether-to-olefins) reaction was significantly deactivated compared with MTO (methanol-toolefins) reaction. By addition of water to the reaction feed, the yield to light olefins was not only increased, but the life time of the catalyst was also prolonged by the suppression of the coke formation by steam.

Improvement of the LED Performance Using Mg Delta-doing in p Type Cladding Layer for Sensor Application (p 형 반도체 층의 Mg 델타 도핑을 이용한 센서 광원 용 LED의 성능 향상)

  • Kim, Yukyung;Lee, Seungseop;Jeon, Juho;Kim, Mankyung;Jang, Soohwan
    • Journal of Sensor Science and Technology
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    • v.31 no.1
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    • pp.31-35
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    • 2022
  • The efficacy improvement of the light emitting diode (LED) was studied for the realization of small-size, low power consumption, and highly sensitive bio-sensor instrument. The performance of the LED with Mg delta-doping at the interface of AlGaN/GaN super-lattice in p type cladding layer was simulated. The device with Mg delta-doping showed improved current, radiative recombination rate, electroluminescence, and light output power compared to the conventional LED structure. Under the bias condition of 5 V, the improved device exhibited 20.8% increase in the light output power. This is attributed to the increment of hole concentration from stable ionization of Mg in p type cladding layer. This result is expected to be used for the miniaturization, power saving, and sensitivity improvement of the bio-sensor system.

High Efficiency and Long Lifetime for Organic Light-Emitting Diode Using New Electron Transport Materials

  • Tanaka, Tsuyoshi;Sato, Masaru;Aihara, Hidenori;Yanai, Naoko;Yamakawa, Tetsu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.625-627
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    • 2007
  • We demonstrated high power efficiency and long lifetime in organic light-emitting diode (OLED) using new electron transport materials (ETMs). Electroluminescent device with these ETMs showed lower driving voltage than that with $Alq_3$. The device lifetime with a new ETM was 2 times longer than that with $Alq_3$.

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High Cell Density Culture of Anabaena variabilis with Controlled Light Intensity and Nutrient Supply

  • Yoon, Jong-Hyun;Shin, Jong-Hwan;Ahn, Eun-Kyung;Park, Tai-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.18 no.5
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    • pp.918-925
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    • 2008
  • Controlling the light energy and major nutrients is important for high cell density culture of cyanobacterial cells. The growth phase of Anabaena variabilis can be divided into an exponential growth phase and a deceleration phase. In this study, the cell growth in the deceleration phase showed a linear growth pattern. Both the period of the exponential growth phase and the average cell growth rate in the deceleration phase increased by controlling the light intensity. To control the light intensity, the specific irradiation rate was maintained above $10\;{\mu}mol/s/g$ dry cell by increasing the incident light intensity stepwise. The final cell density increased by controlling the nutrient supply. For the control of the nutrient supply, nitrate, phosphate, and sulfate were intermittently added based on the growth yield, along with the combined control of light intensity and nutrient concentration. Under these control conditions, both final cell concentration and cell productivity increased, to 8.2 g/l and 1.9 g/l/day, respectively.

Multistage Operation of Airlift Photobioreactor for Increased Production of Astaxanthin from Haematococcus pluvialis

  • Choi, Yoon-E;Yun, Yeoung-Sang;Park, Jong-Moon;Yang, Ji-Won
    • Journal of Microbiology and Biotechnology
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    • v.21 no.10
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    • pp.1081-1087
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    • 2011
  • An internally radiating photobioreactor was applied for the production of astaxanthin using the unicellular green alga Haematococcus pluvialis. The cellular morphology of H. pluvialis was significantly affected by the intensity of irradiance of the photobioreactor. Small green cells were widespread under lower light intensity, whereas big reddish cells were predominant under high light intensity. For these reasons, growth reflected by cell number or dry weight varied markedly with light conditions. Even under internal illumination of the photobioreactor, light penetration was significantly decreased as algal cells grew. Therefore, we employed a multistage process by gradually increasing the internal illuminations for astaxanthin production. Our results revealed that a multistage process might be essential to the successful operation of a photobioreactor for astaxnthin production using H. pluvialis.

Improvement In recombination at a two-emission-layers interface For White-light-emitting organic electroluminescent device

  • Song, Tae-Joon;Ko, Myung-Soo;Lee, Gyu-Chul;Cho, Sung-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.928-931
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    • 2003
  • In order to realize full color display, two approaches were used. The first method is the patterning of red, green, and blue emitters using a selective deposition. Another approach is based on a white-emitting diode, from which the three primary colors could be obtained by micro-patterned color filters. White-light-emitting organic light emitting devices (OLEDs) are attracting much attention recently due to potential applications such as backlights in liquid crystal displays (LCDs) or other illumination purposes. In order for the white OLEDs to be used as backlights in LCDs, the light emission should be bright and have Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.33, 0.33). For obtaining white emission from OLEDs, different colours should be mixed with proper balances even though there are a few different methods for mixing colors. In this study, we will report a white organic electroluminescent device using exciton diffusion length concept.

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