• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.606-611
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• 2018

City natural gas is classified flammable hazardous gas and should be secured according to explosion risk assessment determined by Industrial Standard KS C IEC. In this study, leak size, ventilation grade and effectiveness were adopted to the KS C IEC for risk assessment in natural gas supply system. To evaluate the applicability of the computational fluid dynamics (CFD), the risk assessment was studied for four different conditions using hypothetical volume($V_z$) valuesfrom gas leak experiments, KS C IEC calculation, and CFD simulation.

• Journal of the Korea Safety Management & Science
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• v.20 no.1
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• pp.1-9
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• 2018

As the chemical industry becomes more advanced, the awareness of chemical accidents is rising, and legal systems for chemical safety management are strengthened. In this study, quantitative risk assessment of liquid chlorine leak was conducted. Risk assessment was performed in the order of frequency analysis, consequence analysis, and risk calculation. The individual risk was presented in the form of contour lines. The social risk was expressed by the FN curve. The risk of day and night was in an unacceptable area, so it was required to mitigate risk. Therefore in-building, which could trap the pool, was selected as a risk mitigation measure. As a result of the cost benefit analysis, it was concluded that this measure should be reasonably implemented.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.1-9
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• 2021

The process and facilities of modern chemical plants are becoming increasingly complex, there is possibility of potential risk. Internal chemicals generate stress concentration when operated due to turbulence, laminar flow, pressure, temperature, friction, etc. It causes cumulative fatigue damage, which can damage or rupture chemical facilities and devices. The statistics of chemical accidents found that the highest rate of occurrence was in summer, and in the last five years statistics on chemical accidents, leakage incidents make up a decent percentage of accidents. Chemical leaks can cause serious human damage and economic damage, including explosions and environmental pollution. In this study, based on the leak accident of chemical plant, the risk analysis, and damage effects assessment were estimated using a 3D scanner and FLACS. As a result, if chemicals leak in summer, the risk is higher than in other seasons, the seasonal safety management measures, and countermeasure were estimated.

• Nuclear Engineering and Technology
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• v.55 no.7
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• pp.2373-2379
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• 2023

In sodium systems, leakage is one of the safety concerns; it can cause chemical reactions, which may result in fires. There are contact and non-contact types of leak detectors, and the conventional method of non-contact type detection is by gas sampling. Because of the complexity of this method, there has always been a need for a simple gas sensor, and the resistive-type nanostructure ZnO sensor is a promising option with various advantages. In this study, a ZnO sensor was fabricated, and the concept was tested as a leak detector using a dedicated experiment facility. The experiment results showed distinctive changes in resistance with the presence of sodium aerosol under various conditions. Replacing the conventional gas sampling with the ZnO sensors is expected to enable identification of the leakage location if used as a point-wise instrumentation and to greatly reduce the total cost, making the system simple, light, and effective. For further study, more tests will be performed to evaluate the sensitivity of key parameters under various conditions.

• Fire Science and Engineering
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• v.28 no.1
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• pp.12-19
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• 2014

Workplaces handling hazardous chemicals are scattered, because of old-aging facilities are have been operating for more than 20 years, there is still has the risk of an accident. Advanced countries including the UN and strengthen regulation of chemicals, but the frequent leak accidents have become a big issue socially. In the case of subsequent domestic accidental chemical accident, the government and related departments for the overall prevention, preparedness, response system has been checked and improved. In this study, improvements of the related system and the plan of safety management for on the prevention of accidents and the initial response were suggested throughout the analysis of problems on the actual condition of safety management and such as standard of the related systems for handling, management for occurring the main cause of the leak and chemical accidents from hazardous chemicals handling in the workplace.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1080-1087
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• 2019

For a risk analysis in a chemical process, it is important to reflect correctly the characteristic properties of the target process. In this study, computational fluid dynamics (CFD) was adopted for the advanced risk analysis in a residual hydro desulfurization (RHDS) process by considering operation condition, layout of instruments and facilities, atmospheric condition, and wind direction. Release and explosion simulations for the RHDS by using FEA (Finite Element Analysis) and CFD showed the applicability of 3D scanning methods for estimation of release hole size and release amount.

• The Korean Journal of Emergency Medical Services
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• v.3 no.1
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• pp.7-19
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• 1999

Background : We are in the edge of some human made disasters such as hazardous materials and air pollution, for example, the world news reported that the city of Bhopal, India had serious victims related with a leaking out of the chemical materials, Methyl Isocyanate and many people in India were killed by. These situations many people who live in this world are world are worrying about are not others, but just ours and people consider about that kind of the disasters are the possible situation to happen to all the people. Therefore, we performed this basic study to recognize the risk of Methyl Isocyanate leak accident and to prepare local disaster plan with EMS system. Method : Trace 8.0, a simulation software made by the U.S. company Safer System was used as a tool to estimate the diffusion distance, area and its victims at the concentrations of 0.02ppm, 0.2ppm 5ppm respectively for an assumed B-city of 2 hundred thousands population count in which was presumed 500kg Methyl Isocyanate gas to leak out. Results : 1. During 1 hour, maximum diffusion distances of 0.02ppm 0.2ppm and 5ppm were 5.41km, 1.61km and 0.29km respectively on the plume impact. 2. Maximum population counts influenced by Methyl Isocyanate gas at the concentrations of 0.02ppm 0.2ppm and 5ppm were 40838, 4346 and 222 on the plume impact, while those were 138238, 17261 and 1588 on the vulnerability impact, respectively. 3. Therefore, 17261 persons must put on respiratory device and 138283 persons must be evacuated to safety place within 1 hour. Conclusions : Only small amount leak of Methyl Isocyanate may cause tremendous chemical disaster in urban area, so its disaster plan must be prepared with an accident simulation program and Material Safety Data Sheets(MSDS). Especially, nearby emergency center of an industrial complex must have a strong position about preparation of chemical disaster plan and perform a disaster dill of hazardous material accident annually.

• Journal of the Korean Institute of Gas
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• v.20 no.5
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• pp.9-16
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• 2016

Buried pipe system is subject to leak or rupture due to internal and external defects with age. Especially, if the pipeline is designed for pressurized gas, the leak can wreak a devastating on its surrounding area. The current method of setting up underground gas pipeline is based on OGP criteria of applying one tenth of the inner pipe pressure. The criteria is applied irrespective of their burial depth or pipe's properties. At times, even the whole safety measures are totally ignored. Considering the magnitude of possible damage from a gas leakage, a precise analytical tool for the risk assessment is urgently needed. The study was conducted to assess possible scenarios of gas accidents and to develop a computer model to minimize the damage. The data from ETA was analyzed intensively, and the model was developed. The model is capable of predicting jet fire influence area with comprehensive input parameters, such as burial depth. The model was calibrated and verified by the historic accident data from Edison Township, New Jersey, the United States. The statistical model was also developed to compare the results of the model in this study and the existing OGP model. They were in good agreement with respect to damage predictions, such as radiation heat coming from 10 meters away from the heat source of gas flame.

• Korean Journal of Materials Research
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• v.31 no.3
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• pp.122-131
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• 2021

In the fabrication of joined materials between anodized aluminum alloy and polymer, the performance of the metal-polymer joining is greatly influenced by the chemical properties of the oxide film. In a previous study, the dependence of physical joining strength on the thickness, structure, pore formation, and surface roughness of films formed on aluminum alloys is investigated. In this study, we investigated the effect of silane coupling treatment on the joining strength and sealing performance between aluminum alloy and polymer. After a two-step anodization process with additional treatment by silane, the oxide film with chemically modified nanostructure is strongly bonded to the polymer through physical and chemical reactions. More specifically, after the two-step anodization with silane treatment, the oxide film has a three-dimensional (3D) nanostructure and the silane components are present in combination with hydroxyl groups up to a depth of 150 nm. Accordingly, the joining strength between the polymer and aluminum alloy increases from 29 to 35 MPa, and the helium leak performance increases from 10-2-10-4 to 10-8-10-9 Pa ㎥ s-1.

• Elastomers and Composites
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• v.42 no.4
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• pp.232-237
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• 2007

We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.