• 생태와환경
• /
• 제41권4호
• /
• pp.441-448
• /
• 2008

The purpose of this study was to analyze chemical water quality, fish trophic guilds, tolerance indicators, and fish community conditions in the Gap Stream and to compare the stream conditions between the unimpacted site and impacted site. This study was conducted in the physically stable season (May 2008) to minimize physical impacts such as flow and hydrological disturbance, and applied the study in the Gap Stream with two sites of unimpacted upstream site (Unim-S), mainly surrounded by forested area and impacted site (Im-S), influenced by the wastewater disposal plants and industrial complex in the urban region. Chemical data analysis showed that the degree of organic matter pollution, based on BOD, and COD, was $2{\sim}3$ fold greater in the Im-S than the Unim-S, and that TP, as eutrophication indicators, was 4.7 fold greater in the Im-S. Also, $NH_3-N$ was in 8.2 fold greater in the Im-S ($6.25\;mg\;L^{-1}$) than the Unim-S ($0.76\;mg\;L^{-1}$), indicating a massive influence of wastewater from the disposal plant. Similar results were found in other chemical parameters. Thus, chemical impacts in the Im-S were evident, compared to the unimpacted site. Evaluations of tolerant indicator species indicated that sensitive species were dominant in the Unim-S (23.9%) and tolerant species were dominant (97.8%) in the Im-S. Condition factor (CF) was averaged 0.95 ($0.68{\sim}1.18$) in the Unim-S and 1.08 ($0.93{\sim}1.22$) in the Im-S. Fish community in the Unim-S and Im-S was categorized as Zacco-community and Hemibarbus-community, respectively, and the community diversity index (H') was significantly (p<0.05) higher in the Unim-S (0.810) than the Im-S (0.466). Overall, our results suggest that the comparison approach of various chemical and ecological indicators provide important information in identifying multiple stressors in the stream ecosystems.

• Journal of Ecology and Environment
• /
• 제38권2호
• /
• pp.195-211
• /
• 2015

The objectives of this research were to determine mean and maximum tolerance ranges of Carassius auratus ($C_a$) and Cyprinus carpio ($C_c$) populations on various physico-chemical parameters and ecological indicator metrics. Little is known about chemical tolerance ranges of the two species, even though these species are widely distributed species in aquatic ecosystems. Maximum tolerance ranges of $C_a$-population to total nitrogen (TN) and total phosphorus (TP) were $20.3mgL^{-1}$ and $2.0mgL^{-1}$, respectively. Optimal ranges of TN and TP in the $C_a$-population were $1.7-5.0mgL^{-1}$ and $0.06-0.30mgL^{-1}$, respectively. Such nutrient regimes of the $C_a$-population were evaluated as hypereutrophy, indicating high tolerance limits. The $C_c$-population had similar ecological characteristics to $C_a$-population, but the mean tolerance ranges of TN, TP, BOD, and COD were significantly (p < 0.05) greater than the $C_a$-population. Ecological patterns of trophic composition and tolerance guilds in the $C_a$-population were similar to those of the $C_c$-population. The model value of Index of Biological Integrity (IBI) of the habitat where C. auratus and C. carpio co-occurred averaged $15.0{\pm}4.3$ and $12.9{\pm}3.6$, respectively. Based on the modified criteria of the United States Environmental Protection Agency (Klemm et al. 1993), it indicated poor ecological health of both species. These results suggest that both species are highly tolerant to chemical and physical habitat conditions of waterbodies, and that the chemical tolerance range of $C_c$-population was higher than $C_a$-population.

• Asian-Australasian Journal of Animal Sciences
• /
• 제22권4호
• /
• pp.520-527
• /
• 2009

Alfalfa (Medicago sativa L) is a high-quality forage for ruminants and the main stem is the dominant morphological component contributing to the forage nutritive value in mature alfalfa forage. Shearing force, a fracturing property of plant stem, is an important indictor of forage value. The objectives of this study were to investigate the effects of morphological characteristic on shearing force, the relationship between shearing force and chemical composition, and the relationship between shearing force and in situ digestibility of alfalfa stem. The results showed that linear density (weight per unit length of stem) was more important than chemical composition in affecting shearing force. There was a positive relationship between lignin content and shearing force (r = 0.78). Correlations were not found between shearing force and other chemical components such as neutral detergent fiber (NDF), acid detergent fiber (ADF), cellulose and hemicelluloses. In situ digestibility (of dry matter and NDF) was related to shearing force. A negative correlation was found between shearing force and dry matter (DM) digestibility (r = -0.70), and there was also a negative correlation between shearing force and NDF digestibility (r = -0.87). When shearing force was standardized for stem diameter or stem linear density, the relationship between shearing force and digestibility was consistent regardless of stem diameter and stem linear density. Shearing force was significantly correlated with lignin content and in situ digestibility (of DM and NDF), and was a more direct indicator for estimating forage nutritive value related to animal performance, so it can be used to predict the forage value of alfalfa.

• 한국근적외분광분석학회:학술대회논문집
• /
• 한국근적외분광분석학회 2001년도 NIR-2001
• /
• pp.1610-1610
• /
• 2001

Microbiological examination of silage is of little value in gauging the outcome of silage, and so chemical analysis is more reliable and meaningful indicator of quality. On the other hand chemical assessments of the principal fermentation products provide an unequivocal basis on which to judge quality. Livestock require energy, protein, minerals and vitamins from their food. While fresh forages provide these essential items, conserved forages on the other hand may be deficient in one or more of them. The aim of the conservation process is to preserve as many of the original nutrients as possible, particularly energy and protein components (Woolford, 1984). Silage fermentation is important to preservation of forage with respect of feeding value and animal performance. Chemical and bacteriological changes in the silo during the fermentation process can affect adversely nutrient yield and quality (Moe and Carr, 1984). Many of the important chemical components of silage must be assayed in fresh or by extraction of the fresh material, since drying either by heat or lyophilisation, volatilises components such as acids or nitrogenous components, or effects conversion to other compounds (Abrams et al., 1987). Maize silage dorms the basis of winter rations for the vast majority of dairy and beef cattle production in Uruguay. Since nutrient intake, particularly energy, from forages is influenced by both voluntary dry matter intake and digestibility; there is a need for a rapid technique for predicting these parameters in farm advisory systems. Near Infrared Reflectance Spectroscopy (NIRS) is increasingly used as a rapid, accurate method of evaluating chemical constituents in cereals and dried forages. For many years NIRS was applied to assess chemical composition in dry materials (Norris et al., 1976, Flinn et al., 1992; Murray, 1993, De Boever et al., 1996, De la Roza et al., 1998). The objectives of this study were (1) to determine the potential of NIRS to assess the chemical composition of dried maize samples and (2) to attempt calibrations on undried samples either for farm advisory systems or for animal nutrition research purposes in Uruguay. NIRS were used to assess the chemical composition of whole - plant maize silage samples (Zea mays, L). A representative population of samples (n = 350) covering a wide distribution in chemical characteristics were used. Samples were scanned at 2 nm intervals over the wavelength range 400-2500 nm in a NIRS 6500 (NIRSystems, Silver Spring, MD, USA) in reflectance mode. Cross validation was used to avoid overfitting of the equations. The optimum calibrations were selected on the basis of minimizing the standard error of cross validation (SECV). The calibration statistics were R$^2$ 0. 86 (SECV: 11.4), 0.90 (SECV: 5.7), 0.90 (SECV: 16.9) for dry matter (DM), crude protein (CP), acid detergent fiber (ADF) in g kg$\^$-1/ on dry matter, respectively for maize silage samples. This work demonstrates the potential of NIRS to analyse whole - maize silage in a wide range of chemical characteristics for both advisory farm and nutritive evaluation.

• 대한화학회지
• /
• 제42권2호
• /
• pp.197-202
• /
• 1998

1-(2-Pyridylazo)-2-Naphthol (PAN)은 많은 금속이온들과 착색된 착물을 형성함으로 분광시약 또는 금속지시약으로 널리 사용된다. 본 연구는 PAN을 이동상에 첨가하여 Cu(II), Ni(II) , Zn(II), Co(II) , 및 Fe(III)이온들과 착물을 형성시켜 역상 액체크로마토그래피법으로 분리하였다. 이들 금속착물들은 570nm에서 분광광도 검출기로 검출되었고, 이들 금속이온의 머무름을 조사하기 위하여 이동상의 pH, 이온세기 및 유기용매 조성의 변화에 따른 크로마토그램과 용량인자를 측정하였다. 이상의 실험결과에서 얻은 최적조건하에서 금속이온을 분리한 결과 좋은 크로마토그램을 얻었으며, 검출한계(S/N)도 ppb단위까지 검출이 가능함을 알 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제26권11호
• /
• pp.1738-1742
• /
• 2005

In this study a novel triiodide ion-selective electrode based on a charge transfer complex of iodine and Bis(2-hydroxyacetophenone)butane-2,3-dihydrazone (ICT), as a membrane carrier was prepared. The electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-2}$ and 5.0 ${\times}$ $10^{-7}$ M, with a Nernstian slope of 58. 99 ${\pm}$ 0.3 mV $decade^{-1}$ and detection limit of 3.0 ${\times}$ $10 ^{-7}$ M. The potentiometric response of the proposed sensor is independent of the pH of the solution in the pH range of 3.0-10.0. The electrode possesses the advantages of short conditioning time, fast response time, and especially, very good selectivity over a large number of common organic and inorganic anions. The electrode can be used for at least 6 months without any considerable divergences in the potentials. It was used as an indicator electrode in potentiometric titration of triiodide ion with thiosulfate.

• Bulletin of the Korean Chemical Society
• /
• 제27권9호
• /
• pp.1418-1422
• /
• 2006

In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

• Bulletin of the Korean Chemical Society
• /
• 제25권2호
• /
• pp.177-181
• /
• 2004

A PVC membrane electrode for silver ion based on a new cone shaped calix[4]arene (CASCA) as membrane carrier was prepared. The electrode exhibits a Nernstian response for $Ag^+$ over a wide concentration range ($1.0{\times}10^{-1}-8.0{\times}10^{-6}$M) with a slope of 58.2 {\pm}$ 0.5 mV per decade. The limit of detection of the sensor is $5.0{\times}10^{-6}$M. The sensor has a very fast response time (~5 s) in the concentration range of ${\leq}=1.0{\times}10^{-3}$ M, and a useful working pH range of 4.0-9.5. The proposed sensor displays excellent discriminating ability toward $Ag^+$ ion with respect to common alkali, alkaline earth, transition and heavy metal ions. It was used as an indicator electrode in potentiometric titration of $Ag^+$ with EDTA and in direct determination of silver ion in wastewater of silver electroplating.

• Bulletin of the Korean Chemical Society
• /
• 제25권2호
• /
• pp.172-176
• /
• 2004

A highly selective membrane electrode based on1,3,5-triphenylpyrylium perchlorate (TPPP) is presented. The proposed electrode shows very good selectivity for sulfate ions over a wide variety of common inorganic and organic anions. The sensor displays a nice Nernstian slope of -29.7 mV per decade. The working concentration ranges of the electrode is 1.0{\times}10^{-1}-6.3{\times}10^{-6} $M with a detection limit of $4.0{\times}10^{-6}$ M (480 ng per mL). The response time of the sensor in whole concentration ranges is very short (< 6 s). The response of the sensor is independent on the pH range of 2.5-9.5. The best performance was obtained with a membrane composition of 32% PVC, 59% benzyl acetate, 5% TPPP and 4% hexadecyltrimethylammonium bromide. It was successfully used as an indicator electrode for titration of sulfate ions with barium ions. The electrode was also applied for determination of salbutamol sulfate and paramomycine sulfate.

• 분석과학
• /
• 제9권1호
• /
• pp.91-97
• /
• 1996

수계에서 화학물질의 독성에 대한 humic acid(HA)의 영향을 예측하기 위하여 HA와 화학물질간의 결합상수($K_B$)를 equilibrium dialysis를 이용하여 cartap, diazinon, fenobucarb, pentachlorophenol, P,P'-DDT를 대상으로 측정하였다. $K_B$의 실험치 및 옥탄올/물 분배계수를 이용한 예측치로부터 대상 화합물 중 P,P'-DDT를 제외하고는 HA에 의해 수계 독성에 영향을 줄만한 농도의 감소는 없을 것으로 추정되었다. 실제 자연환경에서는 $K_B{\geq}10^5$ 또는 $K_{ow}{\geq}10^6$ (log $K_{ow}{\geq}6$)인 화학물질에 대해서만 HA에 의한 독성감소 효과를 기대할 수 있는 것으로 생각 되었다.