• Title/Summary/Keyword: chemical form distribution

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Development and Estimation of a Burden Distribution Index for Monitoring a Blast Furnace Condition

  • Chu, Young-Hwan;Choi, Tai-Hwa;Han, Chong-Hun
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.1830-1835
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    • 2003
  • A novel index representing burden distribution form in the blast furnace is developed and index estimation model is built with an empirical modeling method to monitor inner condition of the furnace without expensive sensors. To find the best combination of index and modeling method, two candidates for the index and four modeling methods have been examined. Results have shown that 3-D index have more resolution in describing the distribution form than 1-D index and ANN model produces smallest RMSE due to nonlinearity between the indices and charging mode. Although ANN has shown the best prediction accuracy in this study, PLS can be a good alternative due to its advantages in generalization capability, consistency, simplicity and training time. The second best result of PLS in the prediction results supports this fact.

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ON LIGHTLIKE HYPERSURFACES OF COSYMPLECTIC SPACE FORM

  • Ejaz Sabir Lone;Pankaj Pandey
    • Communications of the Korean Mathematical Society
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    • v.38 no.1
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    • pp.223-234
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    • 2023
  • The main purpose of this paper is to study the lightlike hypersurface (M, $\overline{g}$) of cosymplectic space form $\overline{M}$(c). In this paper, we computed the Gauss and Codazzi formulae of (M, $\overline{g}$) of cosymplectic manifold ($\overline{M}$, g). We showed that we can't obtain screen semi-invariant lightlike hypersurface (SCI-LH) of $\overline{M}$(c) with parallel second fundamental form h, parallel screen distribution and c ≠ 0. We showed that if second fundamental form h and local second fundamental form B are parallel, then (M, $\overline{g}$) is totally geodesic. Finally we showed that if (M, $\overline{g}$) is umbilical, then cosymplectic manifold ($\overline{M}$, g) is flat.

Chemical Forms and Release Potential of Heavy Metals from the Lime Treated Sediments (석회 처리에 의한 오염 퇴적물 내 중금속의 형태 변화 및 용출 가능성)

  • Park, Gil-Ok;Jun, Sang-Ho
    • Korean Journal of Ecology and Environment
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    • v.41 no.2
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    • pp.166-173
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    • 2008
  • Chemical forms and release potential of heavy metals were studied in the lime treated sediment of lake Chungcho. Chemical forms of heavy metals were analyzed using a sequential extraction method, and release potential of heavy metals was evaluated by the ratio of the content of labile forms to total metal one. Dominant form of Cd, Cu, Pb, and Zn in the untreated sediments was organic/sulfidic form that is stable in the reducing environment such as the bottom of Lake Chungcho. With liming of the sediment, the chemical forms of studied metals were greatly changed from organic/sulfidic form to adsorbed and reducible form, especially Cd and Cu to adsorbed and reducible form, but Pb and Zn to reducible form. It is believed that increase of unstable form of heavy metals in the sediments by liming was caused by the increase of pH of the pore water at the expense of organic/sulfidic form. Thus, we concluded that the liming approach currently used in the treatment of dredged sediments might cause the increase of labile form which is easily dissolved, and may increase the release of metals from the sediment into overlying water.

Calculation of the Entropies and Chemical Potentials of Hard-Sphere Solutes Solvated in Hard-Sphere Solids Using the Radial Free-Space Distribution Function

  • 윤병집
    • Bulletin of the Korean Chemical Society
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    • v.20 no.10
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    • pp.1209-1212
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    • 1999
  • The entropies and chemical potentials of hard-sphere solutes solvated in hard-sphere solids were calculated by Monte Carlo method using the radial free-space distribution function. This method is based on calculating the entropy by comparing the free volume of a molecule with that of an ideal gas, and is applicable even when the size of solute is very large and the solvent is a solid. When the diameter of hard-sphere solute is small the solute molecule behaves as like as a fluid in solid structures, but when the diameter of solute becomes large, a fluid-to-solid phase transition takes place. The fluid-to-solid phase transition occurs at the region of the smaller size of solute with the more increase of solvent density. The least square fit values of analytical form of the radial free-space distribution functions of solute molecules are presented for future uses.

A Study on Separation of Benzoic Acid and Its Derivatives by Anion Exchange Chromatography (음이온 교환크로마토그래피에 의한 벤조산 및 그 유도체들의 분리에 관한 연구)

  • Kang Sam Woo
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.358-362
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    • 1974
  • The anion exchange separation of a number of benzoic acid and its derivatives has been studied in various concentrations of $NiCl_2-methanol$ solvent medium. The volume distribution coefficients with Amberlite CG-400, $Cl^-$form have been measured in these medium. Several synthetic mixtures of organic acids were separated quantitatively by elution with a suitable concentration of $NiCl_2-MeOH$ solution suggested by the distribution data. The concentration of organic acids were determined by UV spectrophotometry.

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Surface Finishability of Concrete According to Degree of Damage and the Number of Uses of the Aluminum Form

  • Noh, Sang-Kyun;Lee, Seung-Hoon;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.6
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    • pp.522-529
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    • 2013
  • As concrete forms, panel forms made of plywood used to be widely used, but recently a system form made of aluminum has been broadly adopted because of the advantages it offers in terms of constructability and economy. However, an aluminum form reacts with concrete, which is alkali, and creates hydrogen gas. As a result, air pockets occur on the concrete's surface, and its finishability deteriorates. Therefore, this research analyzed the relationship between the distribution of voids and surface roughness and the damage degree and number of uses of the aluminum form. The analysis of the distribution of voids shows that the number of voids of 0.1~1 mm, which are considered to have occurred because of chemical reaction, was 200~500 on the coating plywood, but was 1 500~2 000 on the aluminum form after 3 uses, and impossible to count after a higher number of uses. Surface roughness was $1.7{\sim}3.2{\mu}m$ on the coating plywood form, but was about $2.6{\mu}m$ after the first use and about $6.8{\mu}m$ after 10 uses, a 2.6-fold increase. Distribution of voids did not show a particular tendency depending upon the degree of damage to the concrete form, but surface roughness showed an increasing tendency as the degree of damage grows. Therefore, when using aluminum forms, surface maintenance should be carried out completely, such as prevention of damages to the form surface coating materials and spreading of separating materials on forms.

Use of MAAP in Generating Accident Source Term Parameters

  • Kim, Jong-Wok;Yun, Joeng-Ik;Kang, Chang-Sun
    • Nuclear Engineering and Technology
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    • v.30 no.3
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    • pp.235-244
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    • 1998
  • The parametric model method determines the accident source term which is Presented by a set of source term parameters. In this method, the cumulative distribution of each source term parameter should be derived for its uncertainty analysis. This paper introduces a method of generating the parameters in the form of cumulative distribution using MAAP version 4.0. In MAAP, there are model parameters which could incorporate uncertain physical and/or chemical phenomena. In general, the model parameters do not have a point value but a range. In this paper, considering that, the input values of model parameters influencing each parameter are sampled using LHS. Then, the computation results are shown in cumulative distribution form. For a case study, the CDFs of FCOR and WES of Kori Unit 1 are derived. The target scenarios for the computation are the ones whose initial events are large LOCA, small LOCA and transient, respectively. It is found that the computed CDF's in this study are consistent to those of NUREG-1150 and the use of MAAP is proven to be adequate in assessing the parameters of the severe accident source term.

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Ionic Equilibria and Ion Exchange of Molybdenum(VI) from Strong Acid Solution

  • Lee, Man-Seung;Sohn, Seong-Ho;Lee, Myung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3687-3691
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    • 2011
  • Ion exchange experiments of molybdenum(VI) from strong HCl and $H_2SO_4$ solution have been done to investigate the existence of anionic complexes. The concentration of HCl and $H_2SO_4$was changed from 1 to 9 M. From the data on the complex formation of molybdenum in aqueous solution, a new distribution diagram of Mo(VI) was constructed in the pH range from zero to 10. AG 1 X-8, an anion exchange resin, and Diphonix, a cation exchange resin were used in the loading experiments. Ion exchange results indicate that anionic complexes of Mo(VI) begins to form from 3 M HCl and 1 M $H_2SO_4$ solution and the tendency to form anionic complexes is stronger in HCl than in $H_2SO_4$ solution. Our results can be utilized in the analysis of Mo(VI) in strong acid solution and in the design of a process to separate Mo(VI).

Preparation and Reconstitution of Core-shell Type Nanoparticles of Poly(ε -caprolactone)/Poly(ethyleneglycol)/Poly(ε -caprolactone) Triblock Copolymers

  • Jeong, Young-Il;Ryu, Jae-Gon;Kim, Young-Hoon;Kim, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.872-879
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    • 2002
  • One of the improtant characteristics of core-shell type nanoparticles is the long-term storage and reuse as an aqueous injection solution when required. For this reason, reconstruction of lyophilized core-shell type nanoparticles is considered to be essential . BAB type triblock copolymers differ from AB type diblock copolymers, which contain the A block as a hydrophilic part and the B block as a hydrophobic part. by not being easily redistributed into phosphate-buffered saline (PBS, pH 7.4, 0.1 M). Therefore, lyophilized core-shell type nanoparticles of CEC triblock copolymer were reconstituted using a somication process with a bar-type sonicator in combination with a freezing-thawing process. Soncation for 30s only resuspended CEC nanoparticles in PBS; their particle size distribution showed a monomodal pattern with narrow size distribution. The bimodal size distribution pattern and the aggregates were reduced by further sonication for 120 s but these nanoparticles showed a wide size distribution. The initial burst of drug release was increased by reconstitution process. The reconstitution of CEC core-shell type nanoparticles by freezing-thawing resulted in trimodal distribution pattern and formed aggregates, although freezing-thawing process was easier than sonication . Drug release form CEC nanoparticles prepared by freezing-thawing was slower than from the original dialysis solution. Although core-shell typenanoparticles of CEC triblock copolymers were not easily performed. Cytotoxicity testing of core-shell type nanoparticles of CEC-2 triblock copolymers containing clonazepam (CNZ) was performed using L929 cells. Cytotoxicity of CNZ was decreased by incorporation into nanoparticles.

Estimate of Current Density Distribution in Electroforming Process Using Finite Element Analysis (유한요소해석을 이용한 전주공정에서의 전류밀도 분포 예측)

  • 강대철;김헌영;전병희
    • Transactions of Materials Processing
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    • v.13 no.3
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    • pp.279-284
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    • 2004
  • Electroforming is the highly specialized use of electrodeposition for the manufacture of metal parts and basically a specialized form of electroplating. So, we can apply electrochemical system analysis for electroforming process. Electrochemical systems are concerned with the interplay between electricity and chemistry, namely the measurements of electrical quantities, such as current density, potential, and charge, and their relationship to chemical parameters. This paper based on the basic equations of electrics and electrochemical kinetics, was employed for a theoretical explanation of the current density distribution on electroforming process. We calculated current density distribution and potential distribution on cathode. Also, calculated current density distribution of vertical direction. It was shown that current density is related with distance of between anode and cathode and mass transfer process.