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Chemical Forms and Release Potential of Heavy Metals from the Lime Treated Sediments  

Park, Gil-Ok (Department of Environmental Science, Kangwon National University)
Jun, Sang-Ho (Department of Environmental Science, Kangwon National University)
Publication Information
Korean Journal of Ecology and Environment / v.41, no.2, 2008 , pp. 166-173 More about this Journal
Abstract
Chemical forms and release potential of heavy metals were studied in the lime treated sediment of lake Chungcho. Chemical forms of heavy metals were analyzed using a sequential extraction method, and release potential of heavy metals was evaluated by the ratio of the content of labile forms to total metal one. Dominant form of Cd, Cu, Pb, and Zn in the untreated sediments was organic/sulfidic form that is stable in the reducing environment such as the bottom of Lake Chungcho. With liming of the sediment, the chemical forms of studied metals were greatly changed from organic/sulfidic form to adsorbed and reducible form, especially Cd and Cu to adsorbed and reducible form, but Pb and Zn to reducible form. It is believed that increase of unstable form of heavy metals in the sediments by liming was caused by the increase of pH of the pore water at the expense of organic/sulfidic form. Thus, we concluded that the liming approach currently used in the treatment of dredged sediments might cause the increase of labile form which is easily dissolved, and may increase the release of metals from the sediment into overlying water.
Keywords
lime treatment; sediment; sequential extraction method; chemical form distribution; release potential;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 박길옥. 2003. 건조.가열처리 및 석회처리가 청초호 퇴적물 에 포함된 중금속의 존재형태에 미치는 영향. 강원대학교 석사학위논문
2 속초시. 1998. 속초시도시기본계획
3 전상호, 박길옥, 김휘중, 안혜정, 김신희. 2005. 건조.가열처리 가 청초호 퇴적물 중 중금속의 화학적 존재형태에 미치는 영향. 한국육수학회지 38: 334-340   과학기술학회마을
4 허우명, 이상균, 권상용, 김동진, 김범철. 2001. 동해안 석호의 육수학적 조사(1): 청초호. 한국육수학회지 34: 206-214
5 Dillon, P.J. and P.J. Smith. 1984. Trace metal and nutrient accumulation in the sediments of lakes near Sudbury, Ontario, p. 375-416. In: Environmental Impacts of Smelters (Nriagu, J.O., ed.). John Wiley & Sons, Inc.
6 Shepard, F.P. 1954. Nomenclature based on sand-silt-clay ratios. J. Sed. Pet. 24: 151-158
7 Wong, J.W.C., K.M. Lai, D.S. Su and M. Fang. 2001. Availability of heavy metals for Brassica chinensis grown an acidic loamy soil amended with a domestic and an industrial sewage sludge. Water, Air, and Soil Pollution 128: 339-353   DOI   ScienceOn
8 Rogherud, S. and E. Fjeld. 2001. Trace element contamination of Norwegian lake sediments. Ambio 30: 11-19   DOI
9 Emmerich, W.E., L.J. Lund, A.L. Page and A.C. Chang. 1982. Predicted solution phase forms of heavy metals in sewage sludge-treated soils. J. Environ. Qual. 11: 178-182   DOI   ScienceOn
10 전상호, 김휘중. 1990. 경포호의 준설에 의한 수질개선가능성 에 관하여. 한국지구과학회지 11: 174-180
11 Sloan J.J. and N.T. Basta. 1995. Remediation of acid soils by using alkaline biosolids. J. Environ. Qual. 24: 1097- 1103   DOI
12 Goudie, A. (ed). 1981. Geomophological techniques. Allen and Unwin, London. 395 p.
13 Hsiau, P.C. and S.L. LO. 1998. Fractionation and leachability of Cu in lime-treated Sewage Sludge. Wat. Res. 32: 1103-1108   DOI   ScienceOn
14 APHA. 1992. Standard methods for the examination of water and wastewater, 18th ed.
15 Stalika, C.D., G.A. Pilidis and S.M. Tzouwara-Karayanni. 1999. Use of a sequential extraction scheme with data normalization to assess the metal distribution in agricultural soils irrigated by lake water. Sci. Total Environ. 236: 7-18   DOI   ScienceOn
16 Lord, IIIC. J. and T.M. Church. 1983. The geochemistry of salt marshes sedimentary ion diffusion, sulfate reduction, and pyritization. Geochim. Cosmochim. Acta 47: 1381-1391   DOI   ScienceOn
17 Howarth, R.W. and B.B. Jorgensen. 1984. Formation of 35S-labeled elemental sulfur and pyrite in coastal marine sediments (Limfjorden and Kysing Fjord, Denmark) during short term $^{35}SO_4^{2-}$ 2- reduction measurements. Geochim. Cosmochim. Acta 48: 1807-1818   DOI   ScienceOn
18 Nriagu, J.O. and Y.K. Soon. 1985. Distribution and isotopic composition of sulfur in lake sediments of nothern Ontario. Geochim. Cosmochim. Acta 49: 823-834   DOI   ScienceOn
19 Outwater, A.B. 1994. Reuse of sludge and minor wastewater residuals. CRC press, Florida. p. 101-111
20 Friedman, G.M. and J.E. sanders. 1978. Principles of sedimentology. Wiley, New York. 792 p.
21 Saeki, K., M. Okazaki and S. Matsumoto. 1993. The Chemical phase changes in heavy metals with drying and oxidation of the lake sediment. Wat. Res. 27: 1243-1251   DOI   ScienceOn
22 속초시. 1995. 청초호퇴적물준설사업 실시설계보고서
23 전상호, 전방욱, 유성환. 1996. 동해안 자연호수의 수질조사 동 해안 호수 보존 심포지엄. 강릉경제정의실천시민연합, p. 83-118
24 Swedish Environmental Protection Agency. 1997. Biologisk mangfald i kalkade sjoar-utvardering av IKEU-programmets sex forsta ar. Report, 4816 p.
25 Dickson, W., H. Borg, C. Ekstrom, E. Hornstrom and T. Groenlund. 1995. Reliming and reacidification effects on lakewater-chemistry, plankton and macrophytes. Water, Air, and Soil Pollution 85: 919-924   DOI
26 Tessier, P.G.C. Campbell and M. Bisson. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry 51: 844-851   DOI   ScienceOn
27 Xie, Q., X. Zhang, D. Wang, J. Li, Y. Qin and Y. Chen. 2001. Research on the effect of sludge fertilizer on farmland and the safety of heavy metals in a karst area. Env. Geology 41(3/4)
28 전상호. 1991. 호소 퇴적물 준설이 수질에 미치는 영향의 평가 방법에 관한 연구. 한국환경과학연구 협의회. 60 p.
29 전상호. 1996. 한국의 주요 호수 및 강물의 오염 특징과 개선 방안. 국제환경심포지엄. 국제환경포럼, p. 1-14
30 McLaren, T.G. and D.V. Cuawford. 1973. The fractionation of copper in soils. Journal of Soil Science 24: 172-181   DOI
31 Swider, K.T. and J.E. Mackin. 1989. Transformation of sulfur compounds in marsh-flat sediments. Geochim. Cosmochim. Acta 53: 2311-2323   DOI   ScienceOn
32 Goudie, A. (ed). 1981. Geomophological techniques. Allen and Unwin, London. 395 p.
33 황경엽, 박성열, 백원석, 정재호, 김영훈, 신원식, 이남주, 황인성. 2007. 낙동강 퇴적물 내 중금속 존재형태 및 용출 가능성. 상하수도학회지 21(1): 113-122