• 제목/요약/키워드: chemical damage

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현장 중심의 화학테러·사고 대응을 위한 피해 영향 범위 평가 개선 방안 연구 (A Study on Improvement of Damage Impact Range Assessment for Field-Based Response Against Chemical Terrorism and Accidents)

  • 이덕재;송창근
    • 융합정보논문지
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    • 제10권8호
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    • pp.127-136
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    • 2020
  • 화학물질을 이용한 화학테러·사고는 국내·외에서 지속해서 발생, 시도되는 추세이다. 국내의 경우, 환경부 화학물질안전원에서 CARIS(Ver. 2018)를 화학테러·사고 발생지역의 피해 영향 범위 평가 용도로 제공하여 현장 대응에 활용하고 있다. 하지만 현행 CARIS는 실내, 지하 등과 같은 폐쇄된 공간에 대한 영향을 고려하지 못하여 현장에서 요구하는 정밀한 피해 영향 범위 평가 결과를 제공하는데 어려우며 제공되는 정보도 제한적이다. 본 연구에서는 CARIS(Ver. 2018)를 구동하여 획득한 피해 영향 범위 평가 결과와 국내·외 문헌 자료를 비교, 검토하여 제한사항과 개선 방향을 제시하였다. 또한 지하, 실내 등 특수 지점, 지역에 대한 구동 모델 구축의 필요성과 현장 대응 요원 등 포함한 주민에게 제공되는 정보의 방향성을 제안하였다. CARIS의 보완과 수정에 있어 본 연구에서 제안한 방법이 반영된다면 더욱 진보된 화학테러·사고 현장 대응 역량 체계 구축이 될 것으로 기대한다.

화학제염공정에서 환원공정조건에 따른 Inconel 600의 부식손상 특성 (Corrosion Damage Characteristics of Inconel 600 with Reduction Conditions in Chemical Decontamination Process)

  • 한민수;정광후;양예진;박일초;이정형;김성종
    • 한국표면공학회지
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    • 제50권5호
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    • pp.332-338
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    • 2017
  • In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.

DNA Damage Effect of Botanical Insecticides Using Chinese Hamster Lung Cells

  • Kim, Areumnuri;Jeong, Mihye;Park, Kyung-Hun;Chon, Kyongmi;Cho, Namjun;Paik, Min Kyoung
    • 한국환경농학회지
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    • 제34권4호
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    • pp.350-354
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    • 2015
  • BACKGROUND: Botanical insecticides, especially Azadirachta Indica extract (AIE) and Sophorae radix extract (SRE) are widely used in Agriculture field. In our previous studies on genotoxicity test of AIE and SRE samples, a suspicious clastogenic properties was shown. Herein, we investigated the DNA damage effect of these botanical insecticide samples through the in vitro comet assay. METHODS AND RESULTS: Chinese hamster lung (CHL) fibroblast cell line was used, and methyl methanesulphonate was as positive control. Respective two samples of AIE and SRE were evaluated using Single Cell Gel Electrophoresis (Comet) assay and measured as the Olive tail moment (OTM). Results from this study indicated that all tested AIE and SRE samples did not show DNA damage in comet assay using CHL cells, compared with control. CONCLUSION: AIE and SRE samples used in this study were not cause genetic toxicity and are suitable for use as organic materials.

모바일 어플리케이션을 이용한 재난상황 발생 시 최적 대피경로 설정 (A Mobile Application for Navigating the Optimal Escape Route in Accidents and Emergency Situations)

  • 조성현;주기돈;강훈;박교식;신동일
    • 한국위험물학회지
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    • 제3권1호
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    • pp.28-36
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    • 2015
  • In early 2011, the Fukushima nuclear power plant had greater damage due to earthquake in Japan, and the awareness of safety has increased. In particular, special response systems should be required to handle disaster situations in plant sites which are likely to occur for large disasters. In this study, a program is designed to set up optimum escape routes, by a smart phone application, when a disaster situation occurs. This program could get information of the cumulative damage from sensors and display the escape route of the smallest damage in real-time on the screen. Utilizing our application in real-time evacuation has advantage in reducing cumulative damage. The optimal evacuation route, focusing on horizontal path, is calculated based on getting the data of fire, detected radioactivity and hazardous gas. Thus, using our application provides information of optimal evacuation to people who even can not hear sensor alarms or do not know geography, without requiring additional costs except fixed sensors or server network deployment cost. As a result, being informed of real-time escape route, the user could behave rapidly with suitable response to individual situation resulting in improved evacuation than simply reacting to existing warning alarms.

Shear induced damage of red blood cells monitored by the decrease of their deformability

  • Lee, Sung Sik;Ahn, Kyung Hyun;Lee, Seung Jong;Sun, Kyung;Goedhart, Petrus T.;Hardeman, Max. R.
    • Korea-Australia Rheology Journal
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    • 제16권3호
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    • pp.141-146
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    • 2004
  • Shear-induced damage of Red Blood Cell (RBC) is an imminent problem to be solved for the practical application of artificial organs in extra corporeal circulation, as it often happens and affects physiological homeostasis of a patient. To design and operate artificial organs in a safe mode, many investigations have been set up to correlate shear and shear-induced cell damage. Most studies were focused on hemolysis i.e. the extreme case, however, it is important as well to obtain a clear understanding of pre-hemolytic mechanical damage. In this study, the change in deformability of RBC was measured by ektacytometry to investigate the damage of RBC caused by shear. To a small magnitude of pre-shear, there is little difference, but to a large magnitude of pre-shear, cell damage occurs and the effect of shear becomes significant depending on both the magnitude and imposed time of shearing. The threshold stress for cell damage was found to be approximately 30 Pa, which is much less than the threshold of mechanical hemolysis but is large enough to occur in vitro as in the extra corporeal circulation during open-heart surgery or artificial heart. In conclusion, it was found and suggested that the decrease of deformability can be used as an early indication of cell damage, in contrast to measuring plasma hemoglobin. As cell damage always occurs during flow in artificial organs, the results as well as the approach adopted here will be helpful in the design and operation of artificial organs.

반도체 실리콘의 웨이퍼링 및 정밀연삭공정후 잔류한 기계 적 손상에 관한 연구 (Silicon Wafering Process and Fine Grinding Process Induced Residual Mechanical Damage)

  • 오한석;이홍림
    • 한국정밀공학회지
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    • 제19권6호
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    • pp.145-154
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    • 2002
  • CMP (Chemical mechanical polishing) process was used to control the fine grinding process induced mechanical damage of Cz Silicon wafer. Characterization of mechanical damage was carried out using Nomarski microscope, magic mirror and also using angle lapping and lifetime scanner evaluation after heat treatment. Magic mirror and lifetime scanner were very useful for the residual damage pattern characterization and CMP process was effective on the reduction of fine grinding induced mechanical damage.

화학공장의 사고피해 최소화 대책수립을 위한 영향범위 평가 (Estimation of Effect Zone for the Establishment of Damage-Minimizing Plan of Chemical Plants)

  • 이헌창;한성환;조지훈;신동일;김태옥
    • 한국가스학회지
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    • 제15권2호
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    • pp.69-74
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    • 2011
  • 화학공장에서 현실적인 사고피해 최소화 대책수립 방법을 제시하기 위하여 API-581 절차를 이용하여 누출 시 나리오를 설정하고, 정량적 원인분석이 가능한 한국형 위험기반검사(KS-RBI) 프로그램을 사용하여 사고 영향범위를 산출하였다. 그리고 위험성 평가를 실시하였다. 그 결과, 화학공장의 사고피해를 최소화하기 위해서는 4가지 누출공의 크기(소, 중, 대 및 파열)와 검출 및 차단 시스템의 등급에 따른 누출시간을 사용하고, 고장빈도에 의한 가중평균과 최악의 누출의 경우를 동시에 고려한 피해면적을 산출하여 비상조치계획을 수립하는 것이 바람직하였다.

Monitoring Failure Behaviour of Pultruded CFRP Composites by Electrical Resistance Measurement

  • Mao, Yaqin;Yu, Yunhua;Wu, Dezhen;Yang, Xiaoping
    • Carbon letters
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    • 제5권1호
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    • pp.18-22
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    • 2004
  • The failure behaviours of unidirectional pultruded carbon fiber reinforced polymer (CFRP) composites were monitored by the electrical resistance measurement during tensile loading, three-point-bending, interlaminar shear loading. The tensile failure behaviour of carbon fiber tows was also investigated by the electrical resistance measurement. Infrared thermography non-destructive evaluation was performed in real time during tensile test of CFRP composites to validate the change of microdamage in the materials. Experiment results demonstrated that the CFRP composites and carbon fiber tows were damaged by different damage mechinsms during tensile loading, for the CFRP composites, mainly being in the forms of matrix damage and the debonding between matrix and fibers, while for the carbon fiber tows, mainly being in the forms of fiber fracture. The correlation between the infrared thermographs and the change in the electrical resistance could be regarded as an evidence of the damage mechanisms of the CFRP composites. During three-point-bending loading, the main damage forms were the simultaneity fracture of matrix and fibers firstly, then matrix cracking and the debonding between matrix and fiber were carried out. This results can be shown in Fig. 9(a) and (b). During interlaminar shear loading, the change in the electrical resistance was related to the damage degree of interlaminar structure. Electrical resistance measurement was more sensitive to the damage behaviour of the CFRP composites than the stress/time curve.

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Chemistry Study on Protective Effect against·OH-induced DNA Damage and Antioxidant Mechanism of Cortex Magnoliae Officinalis

  • Li, Xican;Fang, Qian;Lin, Jing;Yuan, Zhengpeng;Han, Lu;Gao, Yaoxiang
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.117-122
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    • 2014
  • As a Chinese herbal medicine used in East Asia for thousands years, Cortex Magnoliae Officinalis (CMO) was observed to possess a protective effect against OH-induced DNA damage in the study. To explore the mechanism, the antioxidant effects and chemical contents of five CMO extracts were determined by various methods. On the basis of mechanistic analysis, and correlation analysis between antioxidant effects & chemical contents, it can be concluded that CMO exhibits a protective effect against OH-induced DNA damage, and the effect can be attributed to the existence of phenolic compounds, especially magnolol and honokiol. They exert the protective effect via antioxidant mechanism which may be mediated via hydrogen atom transfer (HAT) and/or sequential electron proton transfer (SEPT). In the process, the phenolic-OH moiety in phenylpropanoids is oxidized to the stable quinine-like form and the stability of quinine-like can be ultimately responsible for the antioxidant.