• Title/Summary/Keyword: chemical damage

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Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel (자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석)

  • Lee, Sung-Hee;Kim, M.Y.;Kim, T.G.;Yun, H.Y.;Kang, S.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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Particle Tracking Microrheology and its application to dilute viscoelastic materials (입자추적 미세유변학의 묽은 점탄성 물질에 대한 응용)

  • Yim Yoon-Jae;Lee Sung-Sik;Ahn Kyung-Hyun;Lee Seung-Jong
    • Proceedings of the Korean Society of Rheology Conference
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    • 2006.06a
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    • pp.61-64
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    • 2006
  • Soft materials, such as polymer solutions, gels and filamentous protein materials in cells, show complicated behavior due to their complex structures and dynamics with multiple characteristic time and length scales. Several complementary techniques have been developed to measure viscoelastic of soft materials. Especially, particle tracking microrheology, using the Brownian motion of particles in a medium to get rheological properties, has recently been improved both theoretically and experimentally. Compared to other conventional methods, video particle tracking microrheology has some advantages such as small sample volume, detecting spatial variation of local rheological properties, and less damage to sample materials. With these advantages, microrheology is more suitable to measure the properties of complex materials than other mechanical rheometries.

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A Study on the Physical Property and Damage Index of Decrepit Concrete Materials (노후 콘크리트 재료의 물성 및 손상도에 관한 연구)

  • Song, Jeong-Un;Park, Hoon;Kim, Seung-Kon
    • Explosives and Blasting
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    • v.28 no.2
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    • pp.59-68
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    • 2010
  • Building demolition and blasting work in urban areas has a possibility which has an effect on the structural stability of nearby structures. In this study, the compressive strength and chemical composition of decrepit concrete materials were estimated by Schmidt rebound test and XRD phase analysis. The damage index of the concrete materials was calculated by measured P-wave velocities. It was revealed that the constituents of the concrete materials affect on the compressive strength. The damage index decreases with increasing compressive strength and decreasing impact energy.

Evaluation of Genotoxicity in Blood Cells of a Polychaetous Worm (Perinereis aibuhitensis), Using Comet Assay (Comet assay를 이용한 갯지렁이 (Perinereis aibuhitensis)의 혈구세포에 대한 유전독성 평가)

  • Seo Jin Young;Sung Chan Gyoung;Choi Jin Woo;Lee Chang Hoon;Ryul Tae Kwon;Han Gi Myung;Kim Gi Beum
    • Environmental Analysis Health and Toxicology
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    • v.20 no.4 s.51
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    • pp.333-341
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    • 2005
  • In order to know whether polychaetes could be used as an appropriate organism for the detection of genotoxicity, DNA strand breaks were evaluated in blood cells of a nereidae worm (Perinereis aibuhitensis) exposed to various aquatic chemical pollutants (e.g. Cd, Pb, Pyrene, Benaor[a]pyrene). Hydrogen peroxide increased DNA strand breaks up to the highest concentration (10 $\mu$M). Higher concentration than 0.1 $\mu$M showed a significantly more DNA damage than control. Cadmium and lead also showed higher DNA damage than control, over 1.0 and 1 $\mu$g/L, respectively. In case of pyrene, DNA damage was detected even at 0.001 $\mu$g/L. However, DNA damage decreased due to apoptosis at the highest concentration of pyrene and Pb. This study suggested that the polythaetous blood cells could be used effectively for screening genotoxic contaminants in the environment.

Recovery of Etching Damage of Etched PZT Thin Film by Inductively Coupled Plasma (유도결합 플라즈마에 의해 식각된 PZT 박막의 식각 Damage 개선)

  • 강명구;김경태;김창일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.7
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    • pp.551-556
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    • 2001
  • In this work, the recovery of etching damage in the etched PZT thin film with $O_2$ annealing has been studied. The PZT thin films were etched as a function of Cl$_2$/Ar and additive CF$_4$ into Cl$_2$(80%) /Ar(20%). the etch rates of PZT thin films were 1600$\AA$/min at Cl$_2$(80%)/Ar(20%) and 1970 $\AA$/min at 30% additive Cf$_4$ into Cl$_2$(80%)/Ar(20%). In order to recover the characteristics of etched PZT thin films, the etched PZT thin films were annealed in $O_2$ atmosphere at various temperatures. From the hysteresis curves, ferroelectrical properties are improved by $O_2$ annealing process. The improvement of ferroelectric behavior is consistent with the increase of the (100) and (200) PZT phase revealed by x-ray diffraction (XRD). From x-ray photoelectron spectroscopy (XPS) analysis, intensities of Pb-O, Zr-O and Ti-O peak increase and the chemical residue peak is reduced by $O_2$ annealing. From the atomic force microscopy (AFM) images. it shows that the surface morphology of re-annealed PZT thin films after etching is improved.

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The influences of laser-induced damage threshold by the post-processing of $Al_2O_3$ thin films ($Al_2O_3$ 박막의 후처리 효과가 Laser-Induced Damage Threshold에 미치는 영향)

  • 유연석;이성훈
    • Korean Journal of Optics and Photonics
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    • v.8 no.5
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    • pp.387-394
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    • 1997
  • The influences of laser-induced damage threshold by the after-processing of $Al_2O_3$ thin films was investigated. The samples were fabricated at the substrate temperature of $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$ and $350^{\circ}C$ respectively, and the LIDT were measured by using Nd:YAG laser. After the processing with baking and laser conditioning of the samples, the variation of LIDT was measured. It was found that LIDT was enhanced twice by laser-conditioning process and 1.5 times by baking process. In addition, we measured the chemical properties of the thin film structure before and after the processing by using XPS.

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Role of oxygen in plasma induced chemical reactions in solution

  • Ki, Se Hoon;Uhm, Han Sup;Kim, Minsu;Baik, Ku Youn;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.208.2-208.2
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    • 2016
  • Many researchers have paid attention to the studies on the interaction between non-thermal plasma and aqueous solutions for biomedical applications. The gas composition in the plasma is very important. Oxygen and nitrogen are the main gases of interest in biological applications. Especially, we focus on the oxygen concentration. In this experiment, we studied the role of oxygen concentration in plasma induced chemical reactions in solution. At first, the amount of ions are measured according to changing the oxygen concentration. And we checked the relationship between these ions and pH value. Secondly, when the oxygen concentration is changed, it identified the type and amount of radical generated by the plasma. In order to confirm the effect of these chemical property change to biological material, hemoglobin and RBCs are chosen. RBCs are one of the common basic biological cells. Thirdly, when plasma treated according to oxygen concentration in nitrogen feeding gas, oxidation of hemoglobin and RBC is checked. Finally, membrane oxidation of RBC is measured to examine the relation between hemoglobin oxidation and membrane damage through relative hemolysis and Young's modulus. Our results suggest that reactive species generated by the plasma differsdepending on the oxygen concentration changes. The pH values are decreased when oxygen concentration increased. OH decrease and NO increase are also observed. These reactive species makes change of chemical properties of solution. We also able to confirm that the difference in these reactive species to affect the oxidation of the Hb and RBCs. The Hb and RBCs are more oxidized with the high oxygen concentration conditions. But membrane is damaged more by plasma treatment with only nitrogen gas. It is shown that red blood cells membrane damage and oxidation of hemoglobin are not directly related.

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A Review on Transfer Process of Two-dimensional Materials

  • Kim, Chan;Yoon, Min-Ah;Jang, Bongkyun;Kim, Jae-Hyun;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.36 no.1
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    • pp.1-10
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    • 2020
  • Large-area two-dimensional (2D) materials synthesized by chemical vapor deposition on donor substrates are promising functional materials for conductors, semiconductors, and insulators in flexible and transparent devices. In most cases, 2D materials should be transferred from a donor substrate to a target substrate; however, 2D materials are prone to damage during the transfer process. The damages to 2D materials during transfer are caused by contamination, tearing, and chemical doping. For the commercialization of 2D materials, a damage-free, large-area, and productive transfer process is needed. However, a transfer process that meets all three requirements has yet to be developed. In this paper, we review the recent progress in the development of transfer processes for 2D materials, and discuss the principles, advantages, and limitations of each process. The future prospects of transfer processes are also discussed. To simplify the discussion, the transfer processes are classified into four categories: wet transfer, dry transfer, mechanical transfer, and electro-chemical transfer. Finally, the "roll-to-roll" and "roll-to-plate" dry transfer process is proposed as the most promising method for the commercialization of 2D materials. Moreover, for successful dry transfer of 2D materials, it is necessary to clearly understand the adhesion properties, viscoelastic behaviors, and mechanical deformation of the transfer film used as a medium in the transfer process.

Chemical Control of Grape Phylloxera, Daktulosphaira vitifoliae (Homoptera: Phylloxeridae) and Its Damage in Grapevine Yards (포도뿌리혹벌레(Daktulosphaira vitifoliae)약제방제 효과 및 피해)

  • 김동순;조명래;나승용;이준호;전흥용;임명순;최용문
    • Korean journal of applied entomology
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    • v.41 no.2
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    • pp.137-143
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    • 2002
  • Grape phylloxera, Daktulosphaira vitifoliae(Fitch), is a destructive grape insect pest because it forms root galls and kills the plant by directly destroying root system. The effects of insecticide treatments were examined to establish the chemical control system of phylloxera, and the damage by this insect was investigated in grapevine yards. The treatments of 40kg carbofuran 3GR per ha and carbosulfan 20WP of 10$\ell$ (1,000$\times$) per tree successfully reduced phylloxera densities. After the insecticide treatments in early season, the phylloxera population rebuilt up again at harvest season. In a grapevine yard where two times of carbofuran treatment (mid-May and post-harvest treatment) were applied a year from 1998 to 2000, total yield per ha in 2000 showed an increase of 30% over that of 1998. But the yield in 2000 was low 20% compared to the average standard yield of Korean grapevine yards. In a grapevine yard without chemical treatment during the same years, total yield per ha in 2000 showed 53% reduction compared to that of 1998. Also, damaged vines by phylloxera abruptly increased from 3% in 1998 to 50% in 2000.

Quantitative Risk Assessment of the Chemical Facilities by KS-RBI Program (위험기반검사 프로그램에 의한 화학설비의 정량적 위험성 평가)

  • Kim, Tae-Ok;Lee, Hern-Chang;Choi, Sung-Kyu;Jo, Ji-Hoon;Ham, Byeong-Ho
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.23-28
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    • 2007
  • Damage ranges of accidents of the chemical facilities were estimated by the KS-RBI(Ver.3.0) program supporting the quantitative cause analysis, and the consequences were compared with the results of K-CARM(Ver2.0) program which assesses the quantitative risk in an usual method. As a result we found that the consequences of the KS-RBI program were similar to those of the K-CARM program. Therefore, the KS-RBI program could be applied to the quantitative risk assessment. In addition, it can be safely said that through appling the damage ranges of accidents by weighted average, industrial sites can come up with the effective plans of mitigation and emergency.

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