• Title/Summary/Keyword: charge localization

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Crossover from weak anti-localization to weak localization in inkjet-printed Ti3C2Tx MXene thin-film

  • Jin, Mi-Jin;Um, Doo-Seung;Ogbeide, Osarenkhoe;Kim, Chang-Il;Yoo, Jung-Woo;Robinson, J. W. A.
    • Advances in nano research
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    • v.13 no.3
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    • pp.259-267
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    • 2022
  • Two-dimensional (2D) transition metal carbides/nitrides or "MXenes" belong to a diverse-class of layered compounds, which offer composition- and electric-field-tunable electrical and physical properties. Although the majority of the MXenes, including Ti3C2Tx, are metallic, they typically show semiconductor-like behaviour in their percolated thin-film structure; this is also the most common structure used for fundamental studies and prototype device development of MXene. Magnetoconductance studies of thin-film MXenes are central to understanding their electronic transport properties and charge carrier dynamics, and also to evaluate their potential for spin-tronics and magnetoelectronics. Since MXenes are produced through solution processing, it is desirable to develop deposition strategies such as inkjet-printing to enable scale-up production with intricate structures/networks. Here, we systematically investigate the extrinsic negative magnetoconductance of inkjetprinted Ti3C2Tx MXene thin-films and report a crossover from weak anti-localization (WAL) to weak localization (WL) near 2.5K. The crossover from WAL to WL is consistent with strong, extrinsic, spin-orbit coupling, a key property for active control of spin currents in spin-orbitronic devices. From WAL/WL magnetoconductance analysis, we estimate that the printed MXene thin-film has a spin orbit coupling field of up to 0.84 T at 1.9 K. Our results and analyses offer a deeper understanding into microscopic charge carrier transport in Ti3C2Tx, revealing promising properties for printed, flexible, electronic and spinorbitronic device applications.

Effect of Annealing Temperature with Silver Nanoparticles Incorporation on the Electronic Structure of Poly (3, 4-ethylenedioxythiphene) : poly (styrenesulfonate) Film (은 나노입자가 함침된 Poly (3, 4-ethylenedioxythiphene) : poly (styrenesulfonate)필름의 전자 구조상태에 미치는 열처리효과 연구)

  • Wang, Seok-Joo;Lee, Cho-Young;Park, Hyung-Ho
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.503-506
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    • 2008
  • The effect of silver nanoparticles (NPs) incorporation on the electronic properties of poly (3, 4-ethylenedioxythiphene) : poly(styrenesulfonate) (PEDOT : PSS) films was investigated. The surface of silver NPs was stabilized with trisodium citrate to control the size of silver NPs and prevent their aggregation. We obtained ca. 5 nm sized silver NPs and dispersed NPs in PEDOT : PSS solution. Sheet resistance, surface morphology, bonding state, and work function values of the PEDOT : PSS films were modified by silver NPs incorporation as well as annealing temperature. Sodium in silver NPs solution could lead to a decrease of work function of PEDOT : PSS; however, large content of silver NPs have an effect on the increase in work function, resulting from charge localization on the silver NPs and a decrease in the number of charge-trapping-related defects by chemical bond formation.

Effects of Pre-formed Space Charges by Negative DC Voltages on PD Characteristics in XLPE (부극성 직류전압에 의해 사전 형성된 공간전하가 XLPE의 부분방전특성에 미치는 영향)

  • 황보승;이준호
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.7
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    • pp.310-313
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    • 2003
  • The purpose of this paper is to evaluate the effects of pre-formed space charges by DC stress on partial discharge(PD) characteristics in XLPE. We have suggested a modified pulsed electro-acoustic(PEA) method and successfully measured both space charge distribution and current simultaneously. It has been demonstrated that the PD patterns are strongly influenced by the pre-formed space charge distributions, which are hardly disappeared up to AC 8㎸ in electrode configuration including air gap between XLPE layer and electrode. From the results, it could be said that the pre-formed space charges by DC stress can play harmful and dangerous roles in insulating system under AC operating voltages because of the field distortion and localization due to the pre-formed space charge.

X-ray Photoemission Spectroscopy Study of Cation-Deficient La$_{0.970}$Mn$_{0.970}$O$_3$ System (양이온 결손 La$_{0.970}$Mn$_{0.970}$O$_3$의 X-ray Photoemission Spectroscopy 관측)

  • 정우환
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.50-54
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    • 1999
  • We have measured the x-ray photoemission spectroscopy of cation deficient La0.970Mn0.970O3 as a function of temperature. Detailed results on the chemical shifts and changes in Mn 2p and Lp 3d core levels due to variation of temperature have been obtained. The Mn 2p 3/2 and 1/2 main peaks and La 3d core spectrum shift to lower binding energy levels with increasing temperature. This XPS behavior is correlated with the strength of localization of Mn3+. The Jahn-Teller effect due to Mn3+ besides the conventional random potential effects is likely to localize charge carriers in La-.970Mn0.970O3.

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Localization Developments on Electric Igniter for Thermal Battery of a Missile on K-PSAM (신궁 장입유도탄 열전지용 전기식 착화기 국산화 개발)

  • Ahn, Mahn-Ki;Jeon, Jae-Hyun;Ahn, Gil-hwan;Lee, Seung-Young
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.4
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    • pp.536-542
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    • 2017
  • In this paper, authors described on localization development's results about an electric igniter in thermal battery with a pyrotechnic heat sources. Especially, the development test and evaluation(DT&E) process and the methods in the developments of the electric igniter which is parts of a domestic thermal battery on K-PSAM was in charge of government and developed for defense of a local areas in Korea. We have proposed a process of design and manufacture on the electric igniter. Finally, we verified a quality and a reliability of the electric igniter from test results by Fisher-Snedecor's law and over 99.5 %(C.L. 95 %) for K-PSAM.

Study on International Marketing of Korean Fashion Enterprises (한국 패션기업의 국제마케팅 현황 분석 및 강화 방안)

  • Son, Mi-Young
    • Journal of the Korean Home Economics Association
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    • v.44 no.10
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    • pp.9-20
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    • 2006
  • Due the globalization trends of industry environment, not only fashion companies of the developed countries but also those of NICs and the developing countries are pursuing to globalize their businesses. This study was conducted (i) to identify the characteristics of international marketing mix of Korean fashion companies operating in oversea fashion markets and (ii) to analyze the performance of Korean fashion companies related to international marketing mix. The data were collected from inter-Korean fashion enterprises. A questionnaire was distributed to a person in charge of international division/international trade division who doing business in domestic market and a person in charge of a local subsidiary in oversea market. The methods of analysis used in this study were factor analysis, cluster analysis, and one-way ANOVA. The results of this study are as follows: First, according to factor analysis and cluser analysis, Korean fashion companies were classified in four (4) clusters. The fashion companies in Cluster I put their priority on price. The companies in Cluster II are traditional fashion companies which have relatively low power of product and price. The companies in Cluster III put their priority on product, and the companies in Cluster IV put their priority on local market. Second, according to ANOVA, a growth rate of sales make significant difference among 4 clusters and Clusters II and III were comparatively high in performance.

A study on Quench Characteristics considering Winding Tension in Superconducting Coil using Acoustic Emission Technique (권선장력을 고려한 초전도 계자코일의 퀀치특성 및 AE 신호특성에 관한 연구)

  • 이준현;이민래;손명환;권영길
    • Progress in Superconductivity and Cryogenics
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    • v.1 no.2
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    • pp.8-14
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    • 1999
  • In this study, acoustic emission(AE) technique has been applied to detecting quench which is one of the serious peoblems to assure the integrity of superconducting coil at cryogenic temperature. The characteristics of AE parameters have been analyzed by correlating with the number of quenches, whinding tension of superconducting coil and charge rate of transport current. The quench localization was also performed using AE signals and there was also good correlation between quench current and AE parameters such as AE energy and AE events. In this study, it was confirmed that AE signals were mainly due to the conductor motion which caused by premature quenching. It was also found that optimized winding tension at superconducting coil was needed to prevent quench caused by conductor motion.

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An Extended $H\ddot{u}ckel$ Study of Two Dimensional Layered Compound: FeOCl

  • Kim, Sang Ho;Kim Hojing
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.132-137
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    • 1993
  • The electronic structure of two dimensional layered compound, FeOCl, is studied with the band model and the cluster model approximation employing Extended-Huckel (EH) method. We examine the effects of intercalation (e.g., localization of transferred electron, conductivity increase). FeOCl has the electronic structure typical for layered compounds as expected. For FeOCl-$Li_{1/2}$ system, the charge transfer from Li to the FeOCl lattice occurs, and electrons are built up almost exclusively on Fe atoms. The partially filled band of FeOCl-$Li_{1/2}$ complex is responsible for the increase in conductivity.

Formation of Charged Exciton in GaAs-AlGaAs Double-Quantum-Well Structure at High Magnetic Field (GaAs 이중 양자우물구조에서 고자기장에 유도된 대전된 엑시톤의 발생)

  • Kim, Yong Min
    • Journal of Integrative Natural Science
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    • v.2 no.4
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    • pp.265-269
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    • 2009
  • The photoluminescence was measured in GaAs-AlGaAs double-quantum-well structure at high magnetic field. Although the phototransition characteristics displayed a free-particle transition at low magnetic field, the change of free-particle transition into bound-exciton transition was observed at high magnetic field (above 10 T). A charged exciton formation due to charge-unbalanced electron-hole was identified by using a spin-polarized photoluminescence method. An increase of exciton formation due to the localization of free-particle at magnetic field was observed according to the increase of magnetic field.

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Photoluminescence and Electroluminescence properties of poly(9-vinylcarbazole) blended with diphenoquinone and stilbenquinone derivatives (Diphenoquinone과 Stilbenquinone 유도체를 혼합한 PVCz의 PL과 EL 특성)

  • Lee, Tae-Hoon;Ryu, Jung-Yi;Lee, Mun-Hak;Kim, Tae-Hoon;Chung, Su-Tae;Kim, Sung-Bin;Park, Seong-Soo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.1
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    • pp.75-82
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    • 2004
  • The photoluminescence and electroluminescence of poly(9-vinylcarbazole) (PVCz) containing different ratio 1.3,5-dimethly-3,5-di-tert-butyl-4,4-diphenoquinone (MBDQ), 1.3,5-diemthyl-3.5-di-tert-butyl-4,4-stylbenquinone (MBSQ) were characterized. As the contents of DQ and SQ increased, the intensity of peaks at 516 and 540nm increased in PL spectra. The results of TOF measurement were shown that the hole mobility of PVCz decreased as the ratio of DQ or SQ increased. On the other hand, the electron mobility of PVCz increased. Therefore Electron transport is more favorable than hole transport in these charge transfer complexes, due to the stronger localization of the holes. Evidence for better electron transport is the higher mobility of electrons in pure DQ or SQ compared to hole mobility in pure PVCz, and lower DQ or SQ concentration required for equivalent mobilities in the charge-transfer complexes.

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