• 한국세라믹학회지
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• 제53권2호
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• pp.222-226
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• 2016

The synthesis of pure calcium carbonate nanocrystals was achieved using a simultaneous injection method to produce nano particles of uniform size. These were characterized using scanning electron microscopy and powder X-ray diffraction. The nano particles were needle-shaped aragonite polymorphs, approximately 100-200 nm in length. The aragonite polymorph of calcium carbonate was prepared using aqueous solutions of $CaCl_2$ and $Na_2CO_3$, which were injected simultaneously into double distilled water at $50^{\circ}C$ and then allowed to react for 1.5 h. The resulting whisker-type nano aragonite with high aspect ratio (30) is biocompatible and potentially suitable for applications in light weight plastics, as well as in the medical, pharmaceutical, cosmetic and paint industries.

• 한국재료학회지
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• 제25권2호
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• pp.61-67
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• 2015

$Fe_2O_3$ coated plate mica($Fe_2O_3$/mica) for infrared reflectance red pigment was prepared under hydrothermal treatment. $Fe_2O_3$ was perfectly coated on mica via the difference of surface charge between $Fe_2O_3$ and mica particles at pH 3. $Fe_2O_3$/mica was then calcined at $800^{\circ}C$ to stabilize the coated layer on mica. The infrared(IR) reflectance pigments were characterized by X-ray diffraction, FE-SEM, zeta potential, and a UV-Vis-NIR spectrophotometer. In particular, the CIE color coordinate and IR reflectance properties of $Fe_2O_3$/mica pigments were investigated in relation to the thickness variation of the $Fe_2O_3$ layer coated on mica of various lateral sizes. The isolation-heat red paints containing the pigments were prepared and optimized with a thinner, settling agent, and dispersant. Then, the films were made. The thermal property of isolation-heat on these films was observed through the relationship of the IR reflectance value, which was based on the variation of the $Fe_2O_3$ layer's thickness coated on mica and mica's lateral size as IR reflectance pigment. With an increase in IR reflectance on these films, the thermal property of isolation-heat was effectively enhanced.

• 한국표면공학회지
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• 제51권2호
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• pp.95-103
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• 2018

Recently, many types of constructional steels have been often exposed to under severe corrosive environments due to acid rain with increasing environmental contamination. In order to inhibit their corrosion in severe corrosive environments, a painting method has been widely applied to numerous constructional steels of land as well as marine. Therefore, development of paint having a good quality of corrosion resistance is considered to be very important. In this study, four types of anti-corrosive paints (AP: Phenol epoxy, AC: Ceramic epoxy, AT: Coal tar epoxy, AH: High solid epoxy) were coated to the specimens, and then, were immerged in various salt solutions (0.1, 0.3, 3, 6, 9 and 15% NaCl solutions) for 11 days. And, the corrosion resistance of these samples by effect of osmotic pressure with salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. The corrosion current densities of all samples (AC, AT and AH) submerged in 3% NaCl solution exhibited the smallest values compared to other salt solutions. However, in the case of lower values of salt solutions than 3% NaCl solution, the corrosion current density increased again because it makes easier for water, dissolved oxygen and chloride ion etc. to invade toward inner side of coating film due to increasing of the osmotic pressure than 3% NaCl solution, but in the case of higher values of salt solutions than 3% NaCl solution, the coating film is easily deteriorated due to high concentration of chloride ion rather than the osmotic pressure, which resulted in increasing the corrosion current density. In particular, the AC sample indicated the best corrosion resistance in 6% NaCl solution compared to other samples. Consequently, it is considered that the corrosion mechanism of the coated steel plate is completely different from bare steel plate, and the corrosion resistance of coating film by osmotic pressure and chloride ion depend on various types of epoxy of paint in NaCl solution.

• 한국재료학회지
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• 제26권10호
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• pp.561-569
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• 2016

$SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were synthesized using the polymerized complex method. Generally, phosphorescent phosphors synthesized by conventional solid state reaction show a micro-sized particle diameter; thus, this process is restricted to applications such as phosphorescent ink and paint. However, it is possible to synthesize homogeneous multi-component powders with fine particle diameter by wet process such as the polymerized complex method. The characteristics of $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ powders prepared by polymerized complex method with one and two step calcination processes were comparatively analyzed. Temperatures of organic material removal and crystallization were observed through TG-DTA analysis. The crystalline phase and crystallite size of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were analyzed by XRD. Microstructures and afterglow characteristics of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphors were measured by SEM and spectrofluorometry, respectively.

• 한국정보통신학회논문지
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• 제16권6호
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• pp.1330-1334
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• 2012

잠수함이 가장 취약한 시기는 잠수함이 스노클이나 잠망경 운용을 위하여 잠망경 심도로 항해할 경우이며, 이때에는 비음향 탐지센서인 레이더와 광학, 사람에 의한 시각에 탐지될 확률이 매우 높다. 따라서 본 논문에서는 이러한 상황에서 탐지되는 취약성을 극복하고자 잠수함 마스트 및 잠망경 부분에 비음향 스텔스를 적용하고자 한다. 먼저 비음향 탐지센서에 대해서 조사하고, 그에 따른 스텔스 기법을 분야별 분석하여 최적화한 결과 다층형 구조로 선체표면부터 RAM layer, IR layer, Camouflage layer 구조로 각각 RAM layer는 자성재료인 페라이트계열로 3~5 mm, IR layer는 Ceramic 또는 Nickel 계열로 1~2 mm, Camouflage layer는 군청색 계열 페인팅을 제시하였다.

• 대한치과보철학회지
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• 제35권1호
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• pp.144-164
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• 1997

The purpose of this study were to investigate the chemical composition, mean particle size, linear thermal expansion coefficient and metal-bonding strength of the regular opaque powder and core powder. In this study, 4 types of ceramic powders, namely Duceram Jacket Opaque powder, Duceram Opaque powder, Vita Hi-Ceram powder, Vita VMK Paint On-88 powder were used. Chemical composition was evaluated by EDS(Energy Dispersive X-ray Spectrophotometer, Oxford QX-2000, England), particle size was measured by MALVERN Instruments(MALVERN Instruments SB. OC., U.S.A.. ad linear thermal expansion coefficient was measured by dilatometer(Motoyama, Japan). Bond strength was measured by the Universal tsting machine(Istron Co., Ltd., U.S.A.). The Results were as follows : 1. Through recognition of the relative difference in chemical composition between the core powder and the regular opaque powder, the difference in the proportion of $Al_2O_3$ in each type of material is demonstrated ; Duceram Jaket Opaque powder : 30.16%, Duceram Opaque powder : 16.60%, Vita Hi-Ceram : 63.64%, Vita VMK Paint-On 88 : 16.16%. 2. There was no significant difference in the proportion of metal-bonding materials between the core powder and the regular opaque powder. 3. In the regular opaque powder, alkaline materials were incoporated in order to increase the coefficient of thermal expansion. 4. In the particle size analysis, there was no significant difference in mean particle size or in the particle size distribution between the core powder and the regular opaque powder. 5. In the thermal expansion test for temperature range of $25-600^{\circ}C$, the regular opaque powder had higher coefficient of thermal expansion than that of core powder. 6. In the 4 point flexural bending test, there was no statistically significant difference in the mean bond strength between the core powder and the opaque powder among the Duceram products.

• 한국조경학회지
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• 제30권2호
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• pp.63-69
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• 2002

The Second Namsan Tunnel required renovation. The landscape design was conducted as part of the comprehensive programs for renovation. The landscape design covered site analysis, design development, a working drawing and a maintenance plan. In May of 2001, the Second Namsan Tunnel was renovated and reopened to traffic. The tunnel was recreated as a new type of tunnel with function and beauty. The entrance and retaining wall of the tunnel has public character. Users are greatly affected by the entrance and retaining walls along roads. The landscape architect had to find new materials and methods to improve the environment and to combine artwork with the entrance and walls of the tunnel. The surface of the tunnel entrance and retaining walls are artistically treated with ceramic tiles and paint. Various regional characteristics and cultural meaning are symbolically expressed. Or the tunnel entrance from the Joong-gu side, entitled "Glory of the Future", the hibiscus symbolizes the bright and glorious future of Korea. On the retaining walls, entitled "Hope", the promising Joong-gu is symbolized through image of Korean magpies, mountains, rocks, roses, winds and nature. As for the tunnel entrance from the Yongsan-gu side, entitled "Vivid Spirit", pine trees symbolize the Koreans′strong will and an enterprising spirit. On the retaining walls, entitled "Lively Motions", Yongsan-gu is symbolized through image of pigeons, mountains, rocks, roses, winds and clear skys. The entrance and retaining wall of the Second Namsan Tunnel, whose surfaces are treated with tiles and paint with artistic value, would create an atmosphere using large-scale wall paintings. In this artwork, users would perceive a unique sense of place through the symbolic images of the vertical planes of the tunnel.

• 한국결정성장학회지
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• 제25권4호
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• pp.153-159
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• 2015

무기안료는 우수한 열적, 화학적 안정성으로 인해 페인트, 고화도 세라믹 잉크, 아트 타일, 건물의 외장재 등의 다양한 응용 분야에 적용될 수 있어 큰 관심을 받고 있다. 기존에는 $PbCrO_4$, CdS, CdSe 등의 조성이 노란색 무기 안료로 널리 사용되어 왔으나 Cd, Cr, Pb, Se 같은 유해물질을 포함하고 있어 최근에는 사용에 제한되고 있다. 따라서 본 연구에서는 ceria 기반의 조성을 이용하여 고상법으로 친환경 노란색 무기안료를 합성하였다. XRD와 SEM을 통해 합성된 $Ce_{1-x}Zr_xBi_yO_{2-y/2}$ 노란색 무기안료의 결정구조와 형상을 확인하였고, UV-vis. spectrophotometer와 CIE $L^*a^*b^*$ 분석으로 Zr과 Bi함량에 따른 노란색 무기안료의 발색 특성 변화를 확인하였다. 노란색 무기안료의 결정구조는 주로 하소온도의 변화에 의존하는 것으로 확인되었고, 발색 특성과 흡수단은 하소온도와 Zr, Bi 함량이 모두 영향을 미치는 것으로 나타났다. 결과적으로 합성된 모든 무기안료는 자외선과 500 nm 이하의 가시광선을 효율적으로 흡수하였고, $Ce_{0.44}Zr_{0.36}Bi_{0.20}O_{0.19}$(x = 0.36, y = 0.20) 조성의 무기안료에서 가장 선명한 노란색 색조를 확인할 수 있었다.

• 대한토목학회논문집
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• 제28권5A호
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• pp.691-697
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• 2008

강구조물의 현장연결 방식으로 널리 사용되고 있는 고장력볼트 마찰이음은 연결부의 부식 방지를 위해 도장을 실시하는 것이 일반적으로 허용되고 있다. 고장력볼트 이음부의 마찰면에 도장을 실시하는 경우에는 도장의 정도가 이음부의 미끄러짐 내력에 미치는 영향이 문제로 된다. 본 연구는 마찰면에 새로운 도장형식인 세라믹계 도장사양을 적용한 경우의 고장력볼트 마찰이음부의 미끄러짐 거동을 파악하기 위한 목적으로 실시하였다. 실험은 소정의 세라믹 도장사양을 적용한 고장력볼트 마찰이음 시험편을 대상으로 미끄러짐 시험을 실시하여 미끄러짐 하중 및 미끄러짐 계수를 측정하였으며, 이로부터 세라믹계 도장사양을 실시한 고장력볼트 연결부의 안전성 및 사용성을 검토하였다. 그 결과 미끄러짐 발생시의 하중-변위 특성은 각 도료사별로 다소의 차이가 발생하였으나, 평균 미끄러짐 계수는 도로교표준시방서의 설계기준인 마찰계수 0.4를 초과하는 결과를 나타내고 있다. 그러나 세라믹계 도장을 실시한 고장력볼트 연결부의 안전성과 사용성을 확보하기 위해서는 상세 도장조건에 대한 기준의 제정 및 시방서의 개정이 필요할 것으로 판단된다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2004년도 추계학술대회 논문집
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• pp.78-81
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• 2004

A technical performance of the coating depends greatly on the thickness of painting film or coating film. Therefore the confirmed report of the technique to measure accurately is essential to the coating film thickness for the assessment about a coating quality performance. In this paper, two gap sensors - eddy current gap sensor and capacitance gap sensor - which has a different operating principle were used to measure the thickness of a nonmagnetic substance coating film such as paint, enamel or ceramic that was coated on the metallic material. A capacitance gap sensor was used to measure the distance between the sensor head and a coating film and an eddy current gap sensor to measure the distance between the sensor head and a base metal. Then the thickness of a coating film was obtained by the difference of two measurement value. At this result, the suggested dual sensor can measure an arbitrary film thickness to be coated on a base metal as the measurement value of coating thickness exists accurately within the 2％ error.