Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Characteristics of SrAl2O4: Eu2+, Dy3+ Long Afterglow Phosphors by Polymerized Complex Method

착체중합법을 이용한 SrAl2O4: Eu2+, Dy3+ 축광성 형광체의 합성

  • Kim, Tae-Ho (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Hwang, Hae-Jin (School of Material Science and Engineering, Inha University) ;
  • Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
  • Received : 2016.07.04
  • Accepted : 2016.09.08
  • Published : 2016.10.27
Download PDF
⟨ Previous Next ⟩

Abstract

$SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were synthesized using the polymerized complex method. Generally, phosphorescent phosphors synthesized by conventional solid state reaction show a micro-sized particle diameter; thus, this process is restricted to applications such as phosphorescent ink and paint. However, it is possible to synthesize homogeneous multi-component powders with fine particle diameter by wet process such as the polymerized complex method. The characteristics of $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ powders prepared by polymerized complex method with one and two step calcination processes were comparatively analyzed. Temperatures of organic material removal and crystallization were observed through TG-DTA analysis. The crystalline phase and crystallite size of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were analyzed by XRD. Microstructures and afterglow characteristics of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphors were measured by SEM and spectrofluorometry, respectively.

Keywords

References

  1. T. Katsumata, T. Nabae, K. Sasajima, S. Komuro and T. Morikawa, J. Electrochem. Soc., 144, 243 (1997). https://doi.org/10.1149/1.1837392
  2. Y. Murayama, Ceramics Japan., 32, 40 (1997).
  3. Y. Murayama, N. Takeuchi, Y. Aoki and T. Matsuzawa, U. S. Patent, No. 5, 424 (1995).
  4. T. Matsuzawa, Y. Aoki, N. Takeuchi and Y. Murayama, J. Electrochem. Soc., 143, 2670 (1996). https://doi.org/10.1149/1.1837067
  5. D. S. Kim and R. Y. Lee, Korean J. Mater. Res., 9, 1 (1999).
  6. M. Tabei and S. Shionoya, J. Lumin., 15, 201 (1977). https://doi.org/10.1016/0022-2313(77)90019-9
  7. A. Suzuki and S. Shionoya, J. Phys. Soc. Jpn., 31, 1455 (1971). https://doi.org/10.1143/JPSJ.31.1455
  8. Y. T. Yu, B. G. Kim and C. W. Nam, Korean J. Mater. Res., 8, 11 (1998).
  9. W. J. Park, S. G. Yoon and D. H. Yoon, J. Electroceram., 17, 41 (2006). https://doi.org/10.1007/s10832-006-9933-x
  10. A. Pandey and V. K. Rai, Dalton Trans., 42, 11005 (2013). https://doi.org/10.1039/c3dt50592h
  11. N. G. Eror and H. U. Anderson, MRS Proceedings. Vol.73. Cambridge University Press, 571 (1986). https://doi.org/10.1557/PROC-73-571
  12. K. H. Choi, Ph. D. Thesis (in Korean), p. 27-33, Hanyang University, Seoul (2003).
  13. Y. Y. Choi, Ph. D. Thesis (in Korean), p. 115-120, Chonbuk National University, Jeonju (2004).
  14. A. Nag and T. R. N. Kutty, J. Alloys Compd., 354, 221 (2003). https://doi.org/10.1016/S0925-8388(03)00009-4
  15. D. Jia, Opt. Mater., 22, 65 (2003). https://doi.org/10.1016/S0925-3467(02)00241-0
  16. T. Katsumata, T. Nabae, K. Sasajima and T. Matsuzawa, J. Cryst. Growth, 183, 361 (1998). https://doi.org/10.1016/S0022-0248(97)00308-4
  17. A. Meijerink, W. J. Schipper and G. Blasse, J. Phys. D: Appl. Phys., 24, 997 (1991). https://doi.org/10.1088/0022-3727/24/6/028
  18. V. Abbruscato, J. Electrochem. Soc., 118, 930 (1971). https://doi.org/10.1149/1.2408226
  19. J. Holsa, H. Jungner, M. Lastusaari, and J. Niittykoski, J. Alloys Compd., 323, 326 (2001).
  20. E. Nakazawa, and T. Mochida, J. Lumin., 72, 236 (1997).
  21. H. C. Swart, J. J. Terblans, O. M. Ntwaeaborwa, E. Coetsee, B. Mothudi and M. S. Dhlamini, Nucl. Instrum. Methods Phys. Res., Sect. B, 267, 2630 (2009). https://doi.org/10.1016/j.nimb.2009.05.041
  22. R. Chen, Y. Wang, Y. Hu, Z. Hu and C. Liu, J. Lumin., 128, 1180 (2008). https://doi.org/10.1016/j.jlumin.2007.11.094