• Journal of Electrochemical Science and Technology
• /
• v.14 no.3
• /
• pp.272-282
• /
• 2023

Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni⁴⁺ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

• Membrane and Water Treatment
• /
• v.5 no.3
• /
• pp.183-195
• /
• 2014

The efficiency of two metal ions (cadmium, zinc) removal from aqueous solutions by ultrafiltration (UF) and Polymer Enhanced Ultrafiltration (PEUF) processes were investigated in this work. The UF and PEUF studies were carried out using an ultrafiltration tangential cell system equipped with 5.000 MWCO regenerated cellulose. A water-soluble polymer: the polyacrylic acid (PAA) was used as complexant for PEUF experiments. The effects of transmembrane pressure, pH, metal ions and loading ratio on permeate fluxes and metal ions removals were evaluated. In UF process, permeate fluxes increase linearly with increasing pH for different transmembrane pressure, which may be the consequence of the formation of soluble metal hydroxyl complexes in the aqueous phase. In PEUF process, above pH 5.0, the Cd(II) retention reaches a plateau at 90% and Zn(II) at 80% for L = 5. Also, cadmium retention at different L is greater than zinc retention at pH varying from 5.0 to 9.0. In a mixture solution, cadmium retention is higher than zinc for different loading ratio, this is due to interactions between carboxylic groups of PAA and metal ions and more important with cadmium ions.

• Journal of Wetlands Research
• /
• v.18 no.4
• /
• pp.424-431
• /
• 2016

LID facilities like bio-retention cells is applied to manage stormwater. LID concept becomes an important part in stormwater management, and the clear understanding of hydrologic performance and hydrologic impact on the corresponding catchment has been needed. In this study, the application of flow duration curves as design strategy is investigated. Bio-retention cells like many LID facilities are installed to reproduce natural hydrologic processes. In this study, the attempt to determine the size of a bio-retention cell is carried out to satisfy the flow duration criteria. From the results, it is shown that "5 mm * the area of a target catchment" which is the current facility design capacity is valid for the drainage area with 20-30% impervious rate. In the 100% impervious catchment where LID facilities are typically installed, the design capacity to intercept stormwater of approximately 47 mm depth is required to reproduce natural flow duration curves. This means that about 11% of the target catchment area should be allocated as a bio-retention cell. However, the criteria of the design capacity and facility surface area should be set at the possible implementation conditions in reality, and site-specific hydrologic characteristics of a target catchment should be considered.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.17 no.3
• /
• pp.329-338
• /
• 2019

Suction of unsaturated bentonite buffers is a very important input parameter for hydro-mechanical performance assessment and design of an engineered barrier system. This study analyzed suction measurement techniques and constitutive models of unsaturated porous media reported in the literature, and suggested suction measurement techniques and constitutive models suitable for bentonite buffer in an HLW repository. The literature review showed the suction of bentonite buffer to be much higher than that of soil, as measured by total suction including matric suction and osmotic suction. The measurement methods (RH-Cell, RH-Cell/Sensor) using a relative humidity sensor were suitable for suction measurement of the bentonite buffer; the RH-Cell /Sensor method was more preferred in consideration of the temperature change due to radioactive decay heat and measurement time. Various water retention models of bentonite buffers have been proposed through experiments, but the van Genuchten model is mainly used as a constitutive model of hydro-mechanical performance assessment of unsaturated buffers. The water characteristic curve of bentonite buffers showed different tendencies according to bentonite type, dry density, temperature, salinity, sample state and hysteresis. Selection of water retention models and determination of model input parameters should consider the effects of these controlling factors so as to improve overall reliability.

• Journal of the Institute of Electronics Engineers of Korea SD
• /
• v.45 no.7
• /
• pp.37-43
• /
• 2008

In this paper, the dependence of electrical characteristics of Silicon-$Al_2O_3$-Nitride-Oxide-Silicon (SANOS) memory cell transistors and program/erase (P/E) speed, reliability of memory device on interface trap between Si substrate and tunneling oxide and bulk trap in nitride layer were investigated using charge pumping method which has advantage of simple and versatile technique. We analyzed different SANOS memory devices that were fabricated by the identical processing in a single lot except the deposition method of the charge trapping layer, nitride. In the case of P/E speed, it was shown that P/E speed is slower in the SANOS cell transistors with larger capture cross section and interface trap density by charge blocking effect, which is confirmed by simulation results. However, the data retention characteristics show much less dependence on interface trap. The data retention was deteriorated as increasing P/E cycling number but not coincides with interface trap increasing tendency. This result once again confirmed that interface trap independence on data retention. And the result on different program method shows that HCI program method more degraded by locally trapping. So, we know as a result of experiment that analysis the SANOS Flash memory characteristic using charge pumping method reflect the device performance related to interface and bulk trap.

• Membrane Journal
• /
• v.19 no.1
• /
• pp.63-71
• /
• 2009

In this study, polysulfone which has excellent mechanical and thermal stability with low cost was used for preparing a non-conducting polymer matrix as a reinforced composite membrane for fuel cell application. The membranes were prepared by phase separation method. Polymer concentration and retention time were controlled to investigate the effects on the membrane morphology. The resaltant membranes showed all sponge-like structure independent of polymer concentration. The mechanical and thermal stability were improved with increasing polymer concentration in contrast to the membrane porosity. As a result, the membranes prepared with the retention time for 2 mins using 20 wt% of polymer solution was suitable for a fuel cell compositite membrane providing optimum properties such as approximately 80% of high porosity, 1.3 MPa of tensile strength, and less than 1% of thermal shrinkage both machine and transverse direction.

• Biomolecules & Therapeutics
• /
• v.4 no.2
• /
• pp.148-153
• /
• 1996

Activation of the T lymphocytes results in a variety of early biochemical events ultimately leading to cell proliferation and lymphokine production. Stimulation of the signal transduction cascade in T cells through the T cell receptor coincides with activation of the phosphatidylinositol-phospholipase C (PI-PLC) pathway. Therefore, we have established a model system to screen immune-simulator that can increase the hydrolysis of phosphoinositides in human T cell leukemia Jurkat cells. As a result of screening from herbal medicine extract, 4 extracts (O1ibanum, Ephedrae Herba, Real Gar, Saussureae Radix) were found 14 increase the production of inositol phosphates. All the active fraction from the four kinds of extract were fluted in a different retention time on C-18 HPLC and these active fraction also showed difference in cell specificity. And all the active fractions increased DNA synthesis in T cell. Therefore, it is suggested that the active fraction among 4 extracts might contain a compound having different properties one another.

• Journal of the Microelectronics and Packaging Society
• /
• v.24 no.3
• /
• pp.47-52
• /
• 2017

This research scrutinizes the data retention characteristics of the MLC NAND Flash Memory instigated by the loss effect of trapped charge when the memory is in the state of program saturation. It is attributed to the threshold voltage saturation phenomenon which engenders an interruption to the linear increase of the voltage in the memory cell. This phenomenon is occasioned by the outflow of the trapped charge from the floating gate to the control gate, which has been programmed by the ISPP (Incremental Step Pulse Programming), via Inter-Poly Dielectric (IPD). This study stipulates the significant degradation of thermal retention characteristics of threshold voltage in the saturation region in contrast to the ones in the linear region. Thus the current study evaluates the data retention characteristics of voltage after the program with a repeated reading test in various measurement conditions. The loss effect of trapped charge is found in the IPD layer located between the floating gate and the control gate especially in the nitride layer of the IPD. After the thermal stress, the trapped charge is de-trapped and displays the impediment of the characteristic of reliability. To increase the threshold saturation voltage in the NAND Flash Memory, the storage ability of the charge in the floating gate must be enhanced with a well-thought-out designing of the module in the IPD layer.

• Korean Journal of Environmental Agriculture
• /
• v.23 no.4
• /
• pp.234-239
• /
• 2004

[ $NO_3$ ]-N and T-N removal rates of cattail wetland cells were compared with those of reed wetland cells. The examined cells were a part of a pond-wetland system composed of two ponds in series and six wetland cells in parallel. Each wetland cell was 25m in length and 6m in width. Cattails (Typha angustifolia) were transplanted into three cells and reeds Phragmites australis) into another three ones in June 2000. Water of Sinyang stream flowing into Kohung Estuarine lake located in the southern part of the Korean Peninsula was pumped into the primary pond, its effluent was discharged into the secondary pond Effluent from the secondary pond was funneled into each cell. Two cattail and reed cells were chosen for this research. Water quantity and quality of influnt and effluent were analyzed front May 2001 through October 2001. The volume of influent and effluent of the cells averaged about $20.0\;m^3/day$ and $19.3\;m^3/day$, respectively. Hydraulic retention time was approximately 1.5 days. Influent $NO_3$-N concentration for the four cells averaged 2.39 mg/L. Effluent $NO_3$-N concentration far the cattail and reed cells averaged 1.74 and 1.78 mg/L, respectively. Average $NO_3$-N retention rate for the cattail and reed cells by mass was 30 and 29%, respectively. Influent T-N concentration far the four cells averaged 4.13 mg/L. Effluent T-N concentration for the cattail and reed cells averaged 2.55 and 2.61 mgL respectively. Average T-N retention rate for the cattail and reed cells by mass was 39 and 38%, respectively. $NO_3$-N and T-N concentrations in effluent from the cattail cells were significantly low (p=0.04), compared with those from the reed cells. Cattail wetland cells were more efficient for $NO_3$-N and T-N abatement than reed ones.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.17 no.1
• /
• pp.41-47
• /
• 1981

The characteristics of septic tank sludges were investigated and the kinetic coefficients in the aerobic biodegradation were evaluated from bach treatability tests. Using an unbiased statistical method, the estimated values, k (substrate removal rate coefficient) =0. 0175hr-1 at 17\ulcornerC, K. (Michaelis Menten constant) = 248mg/ e, a (cell yield coefficient)=0.625, and Kd (cell decay coefficient:' =0. 00192hr-1 were obtained based on biodegradable COD(mg/ \ulcorner) and volatile suspended solids(mg/\ulcorner). The relationship between COD and BOD, COD (mg/\ulcorner) =2. 1 BOD(mg/\ulcorner) +250, also was established for the septic tank sludges. Dilution was inevitable for the grit removal because of the high viscosity of the sludges. An aerobic activated sludge process rather than anaerobic processes was recommended for the removal of soluble organics after the removal of grit and suspended solids. A multi-stage activated sludge process was adapted for this highly concentrated and not easily-degradable waste. It was estimated that a four-stage activated sludge process would require 40 hours retention time compared to 92 hours for a single-stage process, 52 hours for a double-stage process, and 46 hours for a three stage process in order to achieve an effluent quality of 84mg/ e COD( 40mg/ e BOD) with about 4, OOOmg/ \ulcorner MLSS from an influent quality of I, 500mg/ t COD(714mg/.e BOD), while multi-stages beyond four stage would not save the required retention time significantly.