Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Triallyl Borate as an Effective Separator/Cathode Interphase Modifier for Lithium-ion Batteries

  • Ha Neul Kim (Advanced Batteries Laboratory, Department of Chemistry, Incheon National University) ;
  • Hye Rim Lee (Advanced Batteries Laboratory, Department of Chemistry, Incheon National University) ;
  • Taeeun Yim (Advanced Batteries Laboratory, Department of Chemistry, Incheon National University)
  • Received : 2023.02.23
  • Accepted : 2023.04.04
  • Published : 2023.08.31
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Abstract

Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni4+ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea (NRF) (NRF-2022R1F1A1069039 and 2017R1A6A1A06015181), and the Technology Innovation Program (20011905) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).

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