• Title/Summary/Keyword: caustic solution

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The Physical Property of the Structural Color Yarn and Fabric for Emotional Garment Using Biomimetic Technology (생체모방기술을 응용한 감성의류용 구조발색사와 직물의 물성)

  • Kim, Hyun-Ah;Kim, Seung-Jin
    • Science of Emotion and Sensibility
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    • v.15 no.1
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    • pp.141-148
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    • 2012
  • This study investigated the structural coloration and fabric hand of the caustic reduced fabrics for emotional garment using structural color yarns, which was spun by 37 alternating nylon and polyester layers capable of producing basic colors using biomimetic technology. The colorations of the three kinds of structural color yarns were confirmed using multi angle spectro-photometer, and their triangular cross sections composed with 37 alternating nylon and polyester layers were measured using SEM and were discussed with layer length in relation with coloration and spinning conditions were also set up. The apparent color difference and reflectance of the three kinds of fabrics with different density and weave pattern were analysed as ranging from 400nm to 700nm. The optimum fabric structural design which is made by warp and weft densities(194ends/in ${\times}$ 105picks/in) and caustic reduction condition by $100^{\circ}C$ temperature and 60minutes with NaOH, 20g/l solution were decided through analysis of the mechanical properties and fabric hands of these three kinds of fabrics treated with 3 kinds of the caustic reduction conditions. And it was shown that the rate of caustic reduction was increased from 13% to 23% with increasing temperature and time of caustic reduction. The extensibility, bending rigidity and shear modulus of caustic reduction treated fabrics were decreased by treatment of caustic reduction, on the other hand fabric compressibility was increased. And it was shown that the hand value of specimen number one which was treated with temperature $100^{\circ}C$ and time 60minute was the best and the hand of this fabric was better than that of Morpho $fabric^{(R)}$ made by Teijin co. Japan.

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The Extraction of Rare Earth Metal Component from the Domestic Monazite (국내부존 Monazite로부터 희토류금속의 추출)

  • Hwang, Chang-Il;Hyun, Seong-Ho;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.440-450
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    • 1992
  • Three type extraction processes of rare earth metal component from rare earth metal bearing ore were sulfuric acid digestion, caustic soda leaching and decomposition with $(NH_4)_2SO_4$. From the overall results, both caustic soda leaching and sulfuric acrid digestion were better extraction processes for domestic monazite ore. The proper conditions of sulfuric acid digestion for domestic monazite ore were reaction temperature $210^{\circ}C$, reaction time 40 min, weight ratio of $H_2SO_4$ to monazite ore 1.5 and concentration of $H_2SO_4$ 95%. Under these conditions, 98% of rare earth metal component was extracted and also the reasonable conditions for caustic soda leaching were reaction temperature $140^{\circ}C$, weight ratio of NaOH to monazite 3.0, concentration of caustic soda solution 50% and leaching time 3hrs. Under these conditions, 97% of rare earth metal component was extracted.

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Stress Corrosion Cracking of Alloy 600 and Alloy 690 in Caustic Solution

  • Kim, Hong Pyo;Lim, Yun Soo;Kim, Joung Soo
    • Corrosion Science and Technology
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    • v.2 no.2
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    • pp.82-87
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    • 2003
  • Stress corrosion cracking of Alloy 600 and Alloy 690 has been studied with a C-ring specimen in 1%, 10% and 40% NaOH at $315^{\circ}C$. SCC test was performed at 200 mV above corrosion potential. Initial stress on the apex of C-ring specimen was varied from 300 MPa to 565 MPa. Materials were heat treated at various temperatures. SCC resistance of Ni-$_\chi$Cr-10Fe alloy increased as the Cr content of the alloy increased if the density of an intergranular carbide were comparable. SCC resistance of Alloy 600 increased in caustic solution as the product of coverage of an intergranular carbide in grain boundary, intergranular carbide thickness and Cr concentration at grain boundary increased. Low temperature mill annealed Alloy 600 with small grain size and without intergranular carbide was most susceptible to SCC. TT Alloy 690 was most resistant to SCC due to the high value of the product of coverage of an intergranular carbide in grain boundary, intergranular carbide thickness and Cr concentration at grain boundary. Dependency of SCC rate on stress and NaOH concentration was obtained.

The effect of the ultrasonic wave on the texturisation of the silicon crystal-line solar cell (태양전지용 규소의 texture etching에 미치는 초음파의 영향)

  • 김정민;김영관
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.6
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    • pp.261-266
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    • 2003
  • The presence of ultrasonic wave in the caustic etching process enhances the etching rate and results in finer and more homogeneous textured structure of the crystalline silicon surface. The silicon solar cell textured in the caustic solution at $60^{\circ}C$ with ultrasonic wave gives higher cell performance than the cell textured at $70^{\circ}C$ without ultrasonic wave. This result indicates a strong possibility of lowering the production cost of the silicon solar cell through saving the thermal budget or expensive chemical normally employed in the texturisation of the crystalline silicon.

Caustic Soda Decomposition and Leaching of Monazite in Hong-Cheon Area Deposit. (홍천산 모나자이트의 가성소다 분해 및 침출)

  • Kim Joon-Soo;Yoon Ho-Sung;Kim Sung-Don;Kim Chul-Joo;Lee Jin-Young
    • Resources Recycling
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    • v.13 no.4
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    • pp.11-16
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    • 2004
  • In this study, treatment conditions for monazite concentrate in Hong-Cheon area deposit were studied with NaOH fritting decomposition and HCl leaching experiments. At condition of NaOH fritting decomposition, it was appropriate to adopt particle size of -200 mesh monazite, reaction temperature of about $460^{\circ}C$ and NaOH/TREO mole ratio of 6. In case of HCl leaching for decomposed product, it was appropriate to use hydrochloric acid of above 8N with leaching temperature of above $80^{\circ}C$, leaching time of 2 hrs and pulp density of about 10%. A rate of decomposition and leaching for monazite was above 90% under optimum conditions. Sodium phosphate compound was effectively recovered from NaOH decomposed solution, and mixed rare earth chloride solution was prepared with HCl leaching of decomposed product.

The study on the rheological properties the solution of polyvinyl alcohol(PVA) in dimethylsulfoxide(DMSO) and Ethanol(EtOH) mixed solvents (디메틸설폭사이드와 에탄을 혼합용매에 용해된 폴리비닐알코을올 용액의 유변학적 성질에 대한 연구)

  • 김학성;김병철
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.215-218
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    • 2002
  • Poly(vinyl alcohol)(PVA)는 1924년 W. O. Herrmann과 W. Haehnel이 Poly(vinyl esters)를 caustic soda 용액에서 비누화하여 합성한 뒤 많은 연구 및 사용되어지고 있는 고분자이다. 환경친화적이고, 인체에 무해하여 인공관절, 콘택트 렌즈 등에 이용이 되고 있다. 특히 구조가 선형적이고 zig-zag구조를 가지기 때문에 고강도, 고탄성을 갖는 섬유의 제조가 가능한 소재이다[1]. PVA섬유의 제조는 용매를 이용한 습식방사 및 겔방사로 섬유를 제조한다. (중략)

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A Case of Esophageal Foreign Body by Mercury Button Battery (단추형 수은전지에 의한 식도이물 1례)

  • 이진춘;김창수;박형진;노환중
    • Korean Journal of Bronchoesophagology
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    • v.5 no.1
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    • pp.73-77
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    • 1999
  • The risk of foreign body by small button-disc battery in children has been increasing because the batteries are widely used in electronic device and plaything and easily contact with children. Foreign body of mercury type button-disc battery, when lodged in the esophagus, leak a caustic solution which causes a rapid necrosis of esophageal mucosa. So it should be removed immediately when the radiologic diagnosis is made. We experienced a case of esophageal foreign body by mercuric disc battery in a 14-month-old male. This case will be discussed with literature review.

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Nonlinear Dispersion Model of Sea Waves in the Coastal Zone (연안역에서의 비선형 파낭 분산모형)

  • Pelinovsky, Efim N.;Stepanyants, Yu.;Talipova, Tatiana
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.5 no.4
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    • pp.307-317
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    • 1993
  • The problem of sea wave transformation in the coastal zone taking into account effects of nonlinearity and disperison has been studied. Mathematical model for description of regular wave transformation is based on the method of nonlinear ray theory. The equations for rays and wave field have been produced. Nonlinear wave field is described by the modified Korteweg-de Vries equation. Some analytical solutions of this equation are obtained. Caustic transformation and dissipation effects are included in the mathematical model. Numerical algorithm of solution of the Korteweg-de Vries equation and its stability criterion are described. Results of nonlinear transformation of sea waves in the coastal zone are demonstrated.

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