• Steel and Composite Structures
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• 제34권2호
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• pp.261-277
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• 2020

The main objective of this research paper is to consider vibration analysis of vacancy defected graphene sheet as a nonisotropic structure via molecular dynamic and continuum approaches. The influence of structural defects on the vibration of graphene sheets is considered by applying the mechanical properties of defected graphene sheets. Molecular dynamic simulations have been performed to estimate the mechanical properties of graphene as a nonisotropic structure with single- and double- vacancy defects using open source well-known software i.e., large-scale atomic/molecular massively parallel simulator (LAMMPS). The interactions between the carbon atoms are modelled using Adaptive Intermolecular Reactive Empirical Bond Order (AIREBO) potential. An isogeometric analysis (IGA) based upon non-uniform rational B-spline (NURBS) is employed for approximation of single-layered graphene sheets deflection field and the governing equations are derived using nonlocal elasticity theory. The dependence of small-scale effects, chirality and different defect types on vibrational characteristic of graphene sheets is investigated in this comprehensive research work. In addition, numerical results are validated and compared with those achieved using other analysis, where an excellent agreement is found. The interesting results indicate that increasing the number of missing atoms can lead to decrease the natural frequencies of graphene sheets. It is seen that the degree of the detrimental effects differ with defect type. The Young's and shear modulus of the graphene with SV defects are much smaller than graphene with DV defects. It is also observed that Single Vacancy (SV) clusters cause more reduction in the natural frequencies of SLGS than Double Vacancy (DV) clusters. The effectiveness and the accuracy of the present IGA approach have been demonstrated and it is shown that the IGA is efficient, robust and accurate in terms of nanoplate problems.

• Bulletin of the Korean Chemical Society
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• 제21권6호
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• pp.588-594
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• 2000

Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

• 세라미스트
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• 제21권4호
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• pp.388-405
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• 2018

In this paper, we review about current development of electrode materials for Li-ion batteries and catalysts for fuel cells. We scrutinized various electrode materials for cathode and anode in Li-ion batteries, which include the materials currently being used in the industry and candidates with high energy density. While layered, spinel, olivine, and rock-salt type inorganic electrode materials were introduced as the cathode materials, the Li metal, graphite, Li-alloying metal, and oxide compound have been discussed for the application to the anode materials. In the development of fuel cell catalysts, the catalyst structures classified according to the catalyst composition and surface structure, such as Pt-based metal nanoparticles, non-Pt catalysts, and carbon-based materials, were discussed in detail. Moreover, various support materials used to maximize the active surface area of fuel cell catalysts were explained. New electrode materials and catalysts with both high electrochemical performance and stability can be developed based on the thorough understanding of earlier studied electrode materials and catalysts.

• 대한조선학회논문집
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• 제47권5호
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• pp.697-702
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• 2010

A WIG(Wing-In-Ground effect) craft flies close to the water surface by utilizing a cushion of relatively high pressurized air between its wing and water surface. This implies that when one designs such craft it is important to have lightweight structures with adequate strength to resist external loads with some margins. To investigate this requirement, this paper deals with the structural analysis of the bottom plate of small WIG craft having a design landing weight of 1.2-ton. As building materials for the WIG craft, pre-preg carbon/epoxy composites are considered. The strength information of the bottom plate is obtained using the first-ply-failure analysis in conjunction with a mid-plane symmetric laminated plate theory. As a result, the first-ply-failure location, load and deflection of the bottom plate are obtained. The calculated strength information is compared with the water reaction load for the bottom plate of seaplanes considered when they land on the water surface -the same fluid-structure interaction mechanism as that of WIG craft. In the calculation of seaplane water reaction load information, the rules shown in FAR(Federal Aviation Regulations) Part 25 are used. Through the comparison, the structural integrity of the bottom plate for the WIG craft is checked.

• Steel and Composite Structures
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• 제25권2호
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• pp.141-155
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• 2017

This paper presents an investigation into the magneto-thermo-mechanical vibration and damping of a viscoelastic functionally graded-carbon nanotubes (FG-CNTs)-reinforced curved microbeam based on Timoshenko beam and strain gradient theories. The structure is surrounded by a viscoelastic medium which is simulated with spring, damper and shear elements. The effective temperature-dependent material properties of the CNTs-reinforced composite beam are obtained using the extended rule of mixture. The structure is assumed to be subjected to a longitudinal magnetic field. The governing equations of motion are derived using Hamilton's principle and solved by employing differential quadrature method (DQM). The effect of various parameter like volume percent and distribution type of CNTs, temperature change, magnetic field, boundary conditions, material length scale parameter, central angle, viscoelastic medium and structural damping on the vibration and damping behaviors of the nanocomposite curved microbeam is examined. The results show that with increasing volume percent of CNTs and considering magnetic field, material length scale parameter and viscoelastic medium, the frequency of the system increases and critically damped situation occurs at higher values of damper constant. In addition, the structure with FGX distribution type of CNTs has the highest stiffness. It is also observed that increasing temperature, structural damping and central angle of curved microbeam decreases the frequency of the system.

• 항공우주시스템공학회지
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• 제12권6호
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• pp.32-40
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• 2018

본 연구에서는 error-outlier 기반의 충격위치탐지 알고리즘과 다중화된 FBG 센서를 이용하여 탄소섬유 강화 플라스틱 복합재 평판 구조물에 대한 충격위치탐지를 수행하였다. 알고리즘의 주요 변수인 오차 임계값(ET)이 0.3 nm, 상수 수준(CL)이 110일 때 최적의 충격위치탐지 결과(최대 오차= 31.82 mm, 평균 오차= 6.31 mm)가 도출되었다. 또한 주어진 최적의 변수 조건에서의 충격위치탐지 과정과 결과를 상세히 분석하였다. 본 연구에서 제시된 다중화된 FBG 센서와 error-outlier 기반의 충격탐지 알고리즘은 복합재 구조물에 대한 충격탐지에 적합한 것으로 판단되며, 향후 다양한 구조 건전성 감시에 활용될 것으로 기대된다.

• Steel and Composite Structures
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• 제30권3호
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• pp.281-292
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• 2019

In this paper, analysis of critical fluid velocity and heat transfer in the nanocomposite pipes conveying nanofluid is presented. The pipe is reinforced by carbon nanotubes (CNTs) and the fluid is mixed by $AL_2O_3$ nanoparticles. The material properties of the nanocomposite pipe and nanofluid are considered temperature-dependent and the structure is subjected to magnetic field. The forces of fluid viscosity and turbulent pressure are obtained using momentum equations of fluid. Based on energy balance, the convection of inner and outer fluids, conduction of pipe and heat generation are considered. For mathematical modeling of the nanocomposite pipes, the first order shear deformation theory (FSDT) and energy method are used. Utilizing the Lagrange method, the coupled pipe-nanofluid motion equations are derived. Applying a semi-analytical method, the motion equations are solved for obtaining the critical fluid velocity and critical Reynolds and Nusselt numbers. The effects of CNTs volume percent, $AL_2O_3$ nanoparticles volume percent, length to radius ratio of the pipe and shell surface roughness were shown on the critical fluid velocity, critical Reynolds and Nusselt numbers. The results are validated with other published work which shows the accuracy of obtained results of this work. Numerical results indicate that for heat generation of $Q=10MW/m^3$, adding 6% $AL_2O_3$ nanoparticles to the fluid increases 20% the critical fluid velocity and 15% the Nusselt number which can be useful for heat exchangers.

• 한국재료학회지
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• 제28권11호
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• pp.633-639
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• 2018

In anion exchange membrane fuel cells, Pd nanoparticles are extensively studied as promising non-Pt catalysts due to their electronic structure similar to Pt. In this study, to fabricate Pd nanoparticles well dispersed on carbon support materials, we propose a synthetic strategy using mixed organic ligands with different chemical structures and functions. Simultaneously to control the Pd particle size and dispersion, a ligand mixture composed of oleylamine(OA) and trioctylphosphine(TOP) is utilized during thermal decomposition of Pd precursors. In the ligand mixture, OA serves mainly as a reducing agent rather than a stabilizer since TOP, which has a bulky structure, more strongly interacts with the Pd metal surface as a stabilizer compared to OA. The specific roles of OA and TOP in the Pd nanoparticle synthesis are studied according to the mixture composition, and the oxygen reduction reaction(ORR) activity and durability of highly-dispersed Pd nanocatalysts with different particles sizes are investigated. The results of this study confirm that the Pd nanocatalyst with large particles has high durability compared to the nanocatalyst with small Pd nanoparticles during the accelerated degradation tests although they initially indicated similar ORR performance.

• 한국정보통신학회논문지
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• 제23권1호
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• pp.97-102
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• 2019

최근 들어 산업현장에서의 재난 사고는 해마다 증가하고 있는 추세이다. 조선업의 경우 밀폐된 공간이 많기 때문에 작업시 발생하는 각종 유해가스에 대한 이슈와 작업장 구조가 복잡하기 때문에 사고가 발생하였을 경우 격벽으로 인한 통신, 사용자 위치추적의 어려움 등에 대한 문제점이 제기된다. 이러한 상황에서 여러 가지 재해나 재난이 발생할 경우 작업자의 피난이나 구조에 있어 상당한 어려움이 발생한다. 이에 본 논문에서는 밀폐된 공간에서 각종 재해나 재난이 발생할 경우 사고를 사전에 방지하기 위한 통합안전시스템을 제안한다. 제안하는 통합안전시스템은 작업자들에 대한 위치정보의 데이터를 실시간 관리하고 작업장에서 발생하는 가스, 산소, 이산화탄소 등의 수치도 실시간으로 관리가 가능하기 때문에 사고를 미연에 방지할 수 있다.

• Advances in concrete construction
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• 제6권6호
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• pp.645-658
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• 2018

Despite being one of the most abundantly used construction materials because of its exceptional properties, concrete is susceptible to deterioration and damage due to various factors particularly corrosion, improper loading, poor workmanship and design discrepancies, and as a result concrete structures require retrofitting and strengthening. In recent times, Fiber Reinforced Polymer (FRP) composites have substituted the conventional techniques of retrofitting and strengthening of damaged concrete. Most of the research studies related to concrete strengthening using FRP have been performed on undamaged test specimens. This contribution presents the results of an experimental study in which concrete specimens were damaged by mechanical loading and elevated temperature in laboratory prior to application of Carbon Fiber Reinforced Polymer (CFRP) sheets for strengthening. The test specimens prepared using concrete of target compressive strength of 28 MPa at 28 days were subjected to compressive and splitting tensile testing up to failure and the intact pieces of the failed specimens were collected for the purpose of repair. In order to induce damage as a result of elevated temperature, the concrete cylinders were subjected to $400^{\circ}C$ and $800^{\circ}C$ temperature for two hours duration. Concrete cylinders damaged under compressive and split tensile loads were re-cast using concrete and rich cement-sand mortar, respectively and then strengthened using CFRP wrap. Concrete cylinders damaged due to elevated temperature were also strengthened using CFRP wrap. Re-cast and strengthened concrete cylinders were tested in compression and splitting tension. The obtained results revealed that re-casting of specimens damaged by mechanical loadings using concrete & mortar, and then strengthened by single layer CFRP wrap exhibited strength even higher than their original values. In case of specimens damaged by elevated temperature, the results indicated that concrete strength is significantly dropped and strengthening using CFRP wrap made it possible to not only recover the lost strength but also resulted in concrete strength greater than the original value.