• Composites Research
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• v.28 no.4
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• pp.168-175
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• 2015

Recently, the applications of carbon fiber reinforced plastics (CFRPs) have become broader than ever when it comes to such industries as automotive, ships, aerospace and military because of their lightweight-ness and high mechanical properties. Thermosetting plastics like epoxy are frequently used as the binding matrix in CFRPs due to their high hardness, wetting characteristics and low viscosity. However, they cannot melted and remolded. For this reason, thermosetting plastic wastes have caused serious environmental problems with the production of fiber reinforced plastics. Thus, many studies have focused on the carbon fiber reinforced thermoplastics (CFRTPs) and recycling carbon fiber. In this study, recycled carbon fiber (RCF) was prepared from CFRPs using a pyrolysis method, which was employed to separate resin and carbon fiber. The degree of decomposition for epoxy resin was confirmed from thermal gravimetric analysis (TGA) and scanning electron microscope (SEM). The RCF was cut and ground to prepare a carbon fiber composite sheet (CFCS). CFCS was manufactured by applying recycled carbon fibers and various thermoplastic fibers. Various characterizations were performed, including morphological analyses of surface and cross-section, mechanical properties, and crystallization enthalpy of CFCS at different cooling conditions.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.313-319
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• 2012

In this work, the electroplating of copper was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and contact angle measurements. Its mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). From the results, it was found that the mechanical interfacial properties of Cu-plated carbon fibers-reinforced composites (Cu-CFRPs) enhanced with increasing the Cu plating time, Cu content and COOH group up to Cu-CFRP-30. However, the mechanical interfacial properties of the Cu-CFRPs decreased dramatically in the excessively Cu-plated CFRPs sample. In conclusion, the presence of Cu particles on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the Cu-CFRPs, but the excessive Cu content can lead the failure due to the interfacial separation between fibers and matrices in this system.

• Fibers and Polymers
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• v.2 no.1
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• pp.163-172
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• 2001

To determine three-dimensional fiber orientation states in injection-molded short fiber composites a CLSM (Confocal Laser Scanning Microscope) is used. Since the CLSM optically sections the composites, more than two cross-sections either on or below the surface of the composite can be obtained. Three dimensional fiber orientation states can be determined with geometric parameters of fibers on two parallel cross-sections. For experiment, carbon fiber reinforced polystyrene is examined by the CLSM. Geometric parameters of fibers are measured by image analysis. In order to compactly describe fiber orientation states, orientation tensors are used. Orientation tensors are determined at different positions of the prepared specimen. Three dimensional orientation states are obtained without the difficulty in determining the out-of-plane angles by utilizing images on two parallel planes acquired by the CLSM. Orientation states are different at different positions and show the shell-core structure along the thickness of the specimen.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.04a
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• pp.119-122
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• 2004

A CPGFRP(Carbon Powder Glass Fiber Reinforced Plastics) sensor was fabricated for fine crack detection of structures. The electrical resistance of the sensor was measured on condition of various composition of carbon powders and thickness of bundle of glass fibers. The resistance was decreased as the increase of the content of carbon powders and the TEX of the glass fibers. In the case of loading on CPGFRP sensor, because inner crack was propagated, the part of percolation structures was disconnected. The sensor is superior to carbon fiber for the detecting ability of fine crack.

• Applied Chemistry for Engineering
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• v.22 no.6
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• pp.672-678
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• 2011

In this work, carbon fibers were electrolessly Ni-plated in order to investigate the effect of metal plating on the electromagnetic shielding effectiveness (EMI-SE) of Ni-coated carbon fibers-reinforced epoxy matrix composites. The surfaces of carbon fibers were characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Electric resistance of the composites was tested using a 4-point-probe electric resistivity tester. The EMI-SE of the composites was evaluated by means of the reflection and adsorption methods. From the results, it was found that the EMI-SE of the composites enhanced with increasing Ni plating time and content. In high frequency region, the EMI-SE didn't show further increasing with high Ni content (Ni-CF 10 min) compared to the Ni-CF 5 min sample. In conclusion, Ni content on the carbon fibers can be a key factor to determine the EMI-SE of the composites, but there can be an optimized metal content at a specific electromagnetic frequency region in this system.

• Advanced Composite Materials
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• v.16 no.4
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• pp.377-384
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• 2007

'Green' composites were fabricated from poly lactic acid (PLA) and bamboo fibers by using a conventional hot pressing method. The insulating properties of the PLA-bamboo fiber 'green' composites were evaluated by determination of the thermal conductivity, which was measured using a hot-wire method. The thermal conductivity values were compared with theoretical estimations. It was demonstrated that thermal conductivity of PLA-bamboo fiber 'green' composites is smaller than that of conventional composites, such as glass fiber reinforced plastics (GFRPs) and carbon fiber reinforced plastics (CFRPs). The thermal conductivity of PLA-bamboo fiber 'green' composites was significantly influenced by their density, and was in fair agreement with theoretical predictions based on Russell's model. The PLA-bamboo fiber composites have low thermal conductivity comparable with that of woods.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.377-385
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• 2003

Flexural characteristics of the R.C beams strengthened with newly-developed grid-type carbon fiber plastics(CFRP-GRIDS) were investigated. The tests were conducted under the four-points load to the failure to investigate the strengthening effects of CFRP-GRIDS on the beams. Results showed that initial cracks appeared in the boundary layers of fibers embedded in the newly-placed mortar concrete slowly progressed to the direction of supports and showed fracture of fiber plastics and brittle failure of concrete in compression in sequence after the yielding of steel reinforcement. Accordingly, the appropriate area of Grid-type carbon-fiber plastics in the strengthening design of deteriorated RC structures should be limited and given based on the ultimate strength design method to avoid the brittle failure of concrete structures.

• Journal of the Korea Institute of Building Construction
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• v.23 no.5
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• pp.509-517
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• 2023

The surge in FRP(Fiber Reinforced Plastic) research signifies the industry's pursuit to counteract the longstanding issue of rebar corrosion. Notably, Carbon Fiber Reinforced Plastic(CFRP) emerges as a commendable alternative, given its superior resistance to both corrosion and chemical interactions, thus positing itself as a potential replacement for traditional steel rebars. However, the layered composition of fibers and resin in CFRP flags a notable susceptibility to elevated temperatures. Despite its promise, comprehensive studies elucidating the full spectrum of CFRP properties remain ongoing. In this investigative study, we meticulously assessed the bond strength of CFRP post-exposure to high thermal conditions. Our findings underscored a parity in bond strength amongst silica sand-coated CFRP, rib-type CFRP, and Glass Fiber Reinforced Plastic(GFRP).

• Composites Research
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• v.34 no.5
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• pp.290-295
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• 2021

The application of lightweight structural composites to automobiles as a solution in line with global fuel economy regulations to curb global warming is recognized as a megatrend. This study was conducted to provide a technical approach that can respond to the issue of replacing parts that require conductive properties to maximize the application of thermoplastic carbon fiber reinforced plastics (CFRPs), which are advantageous in terms of repair, disposal and recycling. By utilizing the properties of the low-viscosity polymerizable oligomer matrix, it was possible to prepare a thermoplastic CFRP exhibiting excellent impregnation properties while uniformly mixing the conductive filler. Various carbon-based conductive fillers such as carbon black, carbon nanotubes, graphene nanoplatelets, graphite, and pitch-based carbon fibers were filled up to the maximum content, and electrical and thermal conductive properties of the fabricated composites were compared and studied. It was confirmed that the maximum incorporation of filler was the most important factor to control the conductive properties of the composites rather than the type or shape of the conductive carbon filler. Experimental results were observed in which it might be advantageous to apply a one-dimensional conductive carbon filler to improve electrical conductivity, whereas it might be advantageous to apply a two-dimensional conductive carbon filler to improve thermal conductivity. The results of this study can provide potential insight into the optimization of structural design for controlling the conductive properties of thermoplastic CFRPs.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.515-521
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• 2023

In this study, waste carbon fiber obtained by pyrolysis of carbon fiber reinforced plastic (CFRP) was used to produce carbon fluoride through vapor phase fluorination and recycled as a reducing electrode material for lithium primary batteries. First, the physicochemical properties of the waste carbon fiber obtained by pyrolysis were determined, and the structural and chemical properties of carbon fluoride were analyzed to evaluate the effect of vapor phase fluorination on the waste carbon fiber. XRD analysis confirmed that the hexagonal network carbon laminated structure (002 peak) of the waste carbon fiber was gradually converted into a carbon fluoride structure (CF_X, 001 peak) as the temperature of gas phase fluorination increased. The discharge capacity of the lithium primary battery produced using this carbon fluoride was up to 862 mAh/g. This was compared to the discharge capacity of carbon fluoride-based Li-ion batteries made of other carbon materials. These results suggest that carbon fluoride made from waste CFRP-based carbon fibers can be used as a reducing electrode material for Li-ion batteries.