• Title/Summary/Keyword: carbon fibers

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Synthesis, Self-assembly, and Catalytic Activity of 1H-Imidazole Amphiphiles

  • Park, Jun-Ha;Kim, Min-Soo;Seo, Sang-Hyuk;Chang, Ji-Young
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2193-2198
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    • 2011
  • We prepared polycatenar 1H-imidazole amphiphiles having a structure in which a 1H-imidazole head was connected through a benzene ring to a pheny group having two or three oligo(ethylene glycol) chains and studied their supramolecular assembly by fluorescence spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM). When the aqueous solutions of the amphiphiles ($5{\times}10^{-5}M{\sim}10^{-3}M$) were deposited onto a carbon-coated copper grid and dried, twisted structures with diameters of ~200-300 nm were imaged by TEM and AFM. We presume that the structures comprised a chain of the amphiphile dimers formed via successive hydrogen bonding between the 1H of the imidazole group and 3N of the neighboring one. In a solution of pH 4, entangled fibers with diameters of several nanometers were observed by TEM. In a pH 10 solution, film-like aggregates formed exclusively. The 1H-imidazole amphiphiles hydrolyzed tetraethoxysilane to induce gelation to form fibrous and spherical silica structures at neutral pH in aqueous solutions. No silica was formed when imidazole was used instead of the amphiphiles, suggesting that the selfassembled aggregates of the amphiphiles were responsible for the gelation.

Estimation of Fatigue Characteristics Using Weibull Statistical Analysis with Aramid Fiber on LNGC Secondary Barrier (LNGC 2차 방벽에 적용된 Aramid 섬유의 Weibull 통계 분석을 이용한 피로특성 평가)

  • Park, Jin Hyeong;Oh, Dong Jin;Kim, Min Gyu;Kim, Myung Hyun
    • Journal of the Society of Naval Architects of Korea
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    • v.54 no.5
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    • pp.415-420
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    • 2017
  • Insulation systems in Liquefied Natural Gas Carriers (LNGC) are vulnerable to sloshing impact and fatigue loads because of waves. If gas leaks into the primary barrier, the Flexible Secondary Barrier (FSB) prevents the leakage of gas in this system. Fatigue strength of the FSB largely depends on the behavior of composite materials. In this study, a new system is applied to the FSB using aramid fiber to improve the fatigue strength of the secondary barrier, with the intention of replacing conventional E-glass fibers. The manufacturing method involved varying the ratio of the aramid fiber to the E-glass fiber for optimum design of the FSB. The fatigue tests results of the secondary barrier using aramid fiber were superior to that using E-glass fiber. The statistical analysis is performed to obtain the fatigue test results and estimate the probability of failure as well as the design guideline of LNGC secondary barriers.

A study on wear with diacharge valve materials in linear compressor (Linear compressor 토출밸브의 재질에 따른 마멸 특성에 관한 연구)

  • Park, Young-Do;Gu, Su-Hak;Kim, Jung-Hae;Park, Jin-Sung;Lee, Jae-Keun
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.899-903
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    • 2009
  • Recently, research and development of the linear compressor are being active. The reason is that the one has not only higher efficiency than reciprocating type, but also lower noise. But because the dicharge valve of linear compressor is operated in high pressure and temperature circumstance, it is important to prevent leakeage. In this paper three other plastic reinforced composite materials were used. Those are TPI, PEEK and PEK which were containing other volume and kind of carbon fibers. First, for assessing mechanical properties, we measured the hardness and the heating property of the trst sepecimen by the microvickers hardness tester and the differential scanning calorimeter respectively. Finally, through FALEX tester, we could know the characteristics of the wear proving the results of before-conducted experiments.

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Sound Pressure Sensitivity Variation of the Hollow Cylinder Type Sagnac Fiber Optic Sensor According to the Mandrel Install Direction and Its Material (Sagnac형 광섬유 센서를 이용한 중공 원통형 맨드릴의 재료 및 설치 방향에 따른 음압 감지 변화 연구)

  • Lee, Jong-Kil
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.7
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    • pp.626-633
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    • 2012
  • In this paper, sound pressure sensitivity of the fiber optic acoustic sensor according to sensor direction and mandrel material were investigated experimentally. Three different directions were selected as stand, lay, and hole. Hollow cylinder type mandrel dimension is 30 mm in outer diameter, 45 mm in length, and 2 mm in thickness, and about 50 m optical fibers were wounded on the surface of the mandrel. Non-directional sound speaker was used as a sound source. Sagnac interferometer and single mode fiber, a laser with 1,550 nm in wavelength, $2{\times}2$ coupler were used. Based on the experimental results, lay direction's sensitivity is the highest in the frequency range of 2 kHz~4 kHz. 'PTFE+carbon' material is more sensitive than PTFE in the frequency range of 5 kHz~20 kHz. Sound pressure detection sensitivity depends on the mandrel direction and material under certain frequency.

The Exit Hole Burr Generation of CFRP with Ultrasonic Vibration (초음파 진동에 따른 CFRP의 출구 구멍 버 생성)

  • Won, Sung-Jae;Li, Ching-Ping;Park, Ki-Moon;Ko, Tae Jo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.1
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    • pp.134-140
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    • 2017
  • CFRP has many industrial applications due to its low weight and high strength properties. CFRP is a composite material composed of carbon fibers embedded in a polymer matrix; it provides excellent resistance to fatigue wear, corrosion, and breakage due to fatigue. It is increasingly demanded in aircraft, automotive, and medical industries due to its superior properties to aluminum alloys, which were once considered the most suitable for specific applications. The basic machining methods of CFRP are drilling and route milling. However, in the case of drilling, the delamination of each layer, uncut fiber, resin burning, spalling, and exit burrs are barriers to successful application. This paper investigates the occurrence of exit burrs when drilling holes with ultrasonic vibration. Depending on design parameters such as the point angle, the characteristics of hole drilling were identified and appropriate machining conditions were considered.

A Study on the Development of a Hybrid Fiber Reinforced Composite for a Type 4 CNG Vessel (CNG용 Type 4 하이브리드 섬유 복합재 용기 개발에 대한 연구)

  • Cho, Sung-min;Cho, Min-sik;Jung, Geunsung;Lee, Sun-kyu;Lee, Seung-kuk;Park, Ki-dong;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.4
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    • pp.97-103
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    • 2017
  • The objective of this study is to develop and commercialize an on-board fuel storage system for CNG vehicles. A type 4 vessel is made of resin-impregnated continuous filament windings on a polyamide (PA6) liner. In particular, this study localized the PA6 liner's fabrication and development. To analyze the filament winding, a specimen test was performed, and the results were verified values obtained using finite element analysis. In this study, the filament winding and fibers were optimized for a 207 bar composite cylinder in a compressed natural gas vehicle.

Comparison of Labyrinthulid Strains L4 and L75 by Fatty Acid Composition and Characteristics

  • Dang, Diem Hong;Nakahara, Toro
    • Fisheries and Aquatic Sciences
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    • v.11 no.3
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    • pp.149-158
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    • 2008
  • Labyrinthulids are unicellular heterotrophic marine microalgae. Two labyrinthulid strains, L4 and L75, which produce generous amounts of polyunsaturated fatty acids(PUFAs), were isolated from leaves floating in the coastal areas of Quang Ninh province, Vietnam, and Fukuoka Prefecture, Japan, respectively. Both strains had spindle-shaped cells surrounded by ectoplasmic networks. Numerous oil bodies were observed in each cell, mostly in the vicinity of cell membranes. When soybean oil or soybean lecithin was used as a carbon source with peptone as a nitrogen source, the proportion of PUFAs reached 25-30% and 50-56% for L4 and L75, respectively. After 14 days of growth at $25^{\circ}C$, L4 produced 0.3 mg PUFAs/g-agar in PYA-SBO medium and 0.6 mg PUFAs/g-agar in PYA-SBL medium. In comparison, L75 produced 0.2 mg PUFAs/g-agar in both types of media. The differences between the two strains included changes in cellular morphology and the capacity for attaching tightly to fibers when cultured in liquid PYA medium containing 2% SBL. In addition, when the strains were grown under the same conditions, L4 had a higher growth rate and produced more PUFAs than L75.

Simultaneous Imaging Using Combined Optical Coherence Tomography (OCT) and Photoacoustic Microscopy (PAM) (광간섭 단층 촬영 장치와 광음향 현미경의 결합을 통한 동시 이미지 획득 연구)

  • Kim, Sehui;Lee, Changho;Han, Seonghoon;Kang, Hyun Wook;Oh, Junghwan;Kim, Jeehyun;Kim, Chulhong
    • Journal of Biomedical Engineering Research
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    • v.34 no.2
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    • pp.91-96
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    • 2013
  • In this study, we developed an integrated optical coherence tomography - photoacoustic microscopy (OCT-PAM) system to simultaneously provide optical absorption and scattering information. Two different laser sources, such as a pulsed laser for PAM and a superluminescent diode for OCT, were employed to implement the integrated OCT-PAM system. The performance of the OCT-PAM system was measured by imaging carbon fibers. We then imaged black and white hairs to demonstrate the simultaneous OCT-PAM imaging capabilities. As a result, OCT can produce 3-D images of both black and white hairs, whereas PAM is only able to image the black hair due to strong optical absorption of black hair.

Possibility of Electro-Active Papers (EAPap) Actuators (Electro-Active Papers(EAPap) 작동기의 가능성 연구)

  • 김재환
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.495-498
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    • 2002
  • Recently, the advent of electro-active papers (EAPap) actuators has been reported. In this paper, the possibility of the actuators is demonstrated. EAPap is a paper that produces large displacement with small force under an electrical excitation. EAPap is made with a chemically treated paper by constructing thin electrodes on both sides of the paper. When electrical voltage is applied on the electrodes the EAPap produces bending displacement. To improve the bending performance of EAPap, different paper fibers-softwood, hardwood, bacteria cellulose, cellophane, carbon mixture paper, electrolyte containing paper and Korean traditional paper, in conjunction with additive chemicals were tested. Two attempts were made to construct the electrodes: the direct use of aluminum foil and the gold sputtering technique. It was found that a cellophane paper exhibits a remarkable bending performance. When 2MV/m of excitation voltage was applied on the paper actuator, more than 3mm of tip displacement was observed out of the 30 mm long paper beam. This is quite low excitation voltage compared to that of other EAPs. The actuation principle of electro-active paper (EAPap) and possible applications are addressed.

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Thin Films for Environmental Application and Energy Devices

  • Kim, Young-Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.91-91
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    • 2012
  • We aim in synthesizing various functional thin films thinner than ~ 10 nm for environmental applications and photovoltaic devices. Atomic layer deposition is used for synthesizing inorganic thin films with a precise control of the film thickness. Several examples about application of our thin films for removing volatile organic compounds (VOC) will be highlighted, which are summarized in the below. 1) $TiO_2$ thin films prepared by ALD at low temperature ($<100^{\circ}C$) show high adsorption capacity for toluene. In combination with nanostructured templates, $TiO_2$ thin films can be used as building-block of high-performing VOC filter. 2) $TiO_2$ thin films on carbon fibers and nanodiamonds annealed at high temperatures are active for photocatalytic oxidation of VOCs, i.e. photocatalytic filter can be created by atomic layer deposition. 3) NiO can catalyze oxidation of toluene to $CO_2$ and $H_2O$ at $<300^{\circ}C$. $TiO_2$ thin films on NiO can reduce poisoning of NiO surfaces by reaction intermediates below $200^{\circ}C$. We also fabricated inverted organic solar cell based on ZnO electron collecting layers on ITO. $TiO_2$ thin films with a mean diameter less than 3 nm on ZnO can enhance photovoltaic performance by reducing electron-hole recombination on ZnO surfaces.

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