• Clean Technology
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• v.13 no.4
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• pp.237-243
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• 2007

Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dimethyl ether (DME) and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing DME as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of DME and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the DME composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature.

• Journal of Dental Rehabilitation and Applied Science
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• v.23 no.1
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• pp.43-53
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• 2007

The purpose of this experimental study was to examine the effect of the decontamination of carbon dioxide ($CO_2$) laser in treatment of ligature-induced peri-implantitis in dogs. A total 24 implants with a sandblasted with large-grit and acid-etched (SLA) surface were inserted in six mongrel dogs. After a 3-month healing period, experimental peri-implantitis characterized by a bone loss of about 3mm was established by inducing with wires. And then wires were removed and plaque control was implemented. Surgical treatment involving flap procedure + debridement of implants surface with chlorhexidine and saline (group 1), flap procedure + GBR with absorbable collagen membrane (Bio-Gide) and mineralized bone graft (Bio-Oss) (group 2), and flap procedure + $CO_2$ laser application + GBR (group 3) was performed. The animals were killed 8 weeks and 16 weeks after treatment, respectively. A histomorphometric analysis confirmed statistically considerable new bone formation within the limit of the 5 most coronal threads in group 3 compared with group 1 at 16 weeks (P<0.05). And intragroup analysis showed considerable increase of new bone formation in group 3 at 16 weeks compared with 8 weeks (P<0.05). The present study demonstrates considerable new bone formation after treatment of experimental peri-implantitis with flap procedure, $CO_2$ laser application and GBR.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.122.1-122.1
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• 2011

The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

• The Korean Journal of Mycology
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• v.9 no.1
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• pp.7-12
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• 1981

Attempts were made to investigate the effects of the temperature and carbon dioxide concentration in the growing room and soil moisture after casing on the mycelial growth, sporophore formation and mushroom yield of Agaricus bisporus (Lange) Sing. The growing room temperature influenced the mycelial growth in the casing layer after casing and the sporophore formation of Agaricus bisporus. The mycelial growth was the rapidest at $30^{\circ}C$ and gradually decreased with the temperature going down, while the sporophore formation and mushroom yield were the best at $25^{\circ}C$. The other factor which affected the mycelial growth and sporophore formation was the moisture content of casing soil. The mycelial growth was the best at 70 percent moisture, and the sporophore formation and mushroom yields were the highest at 60 percent moisture. The concentration of carbon dioxide in the growing room after casing had an important effect upon the mycelial growth in the casing layer and the sporophore formation. When the concentration of carbon dioxide was 0.16 percent, the mycelial growth and the sporophore formation were not inhibited. At 0.5 to 2.0 percent $CO_{2}$ the myceilal growth and the sporophore formation were severely decreased. The sporophore size of the mushroom was the maximum when the room temperature during the vegetative mycelium growth was $20^{\circ}C$ and the moisture content of casing soil was 70 percent.

• Corrosion Science and Technology
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• v.6 no.5
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• pp.227-232
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• 2007

The corrosion behavior of carbon steel (N80) in carbon dioxide saturated 1%NaCl solution with and without acetic acid or acetate was investigated by weight-loss test, electrochemical methods (polarization curve, Electrochemical impedance spectroscopy). The major objective is to make clear that the effect of acetic acid and acetate on the corrosion of carbon steel in $Co_2$ environments. The results indicate that either acetic acid or acetate accelerates cathodic reducing reaction, facilitates dissolution of corrosion products on carbon steel, and so promotes the corrosion rate of carbon steel in carbon dioxide saturated NaCl solution. All Nyquist Plots are consisting of a capacitive loop in high frequency region, an inductive loop in medial frequency region and a capacitive arc in low frequency region. The high frequency capacitive loop, medial frequency inductive loop and low frequency capacitive arc are corresponding to the electron transfer reaction, the formation/adsorption of intermediates and dissolution of corrosion products respectively. All arc of the measured impedance reduced with the increase of the concentration of Ac-, especially HAc. However, the same phenomenon is not notable after reducing pH value by adding HCl. HAc is a stronger proton donor and can be reduced directly by electrochemical reaction firstly. Ac- can't participate in electrochemistry reaction directly, but $Ac^-$ an hydrate easily to create HAc in carbon dioxide saturated environments. HAc is as catalyst in $Co_2$ corrosion. As a result, the corrosion rate was accelerated in the presence of acetate ion even pH value of solution increased.

• Bulletin of the Korean Chemical Society
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• v.15 no.12
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• pp.1054-1058
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• 1994

Different behavior on the formation of soluble intermediate was observed depending on the substrate employed during the nucleation of lead dioxide from plumbous ion using a rotating ring-disk electrode. It was found that no soluble intermediate was formed at glassy carbon electrode, while the presence of soluble intermediate could be detected at platinum substrate. From the different anodic behavior of two substrates, the formation of a probable Pb(Ⅲ) soluble intermediate was suggested. A most probable nucleation mechanism at the platinum substrate involving a second order chemical reaction was derived on the basis of rotating disk electrode experiments.

• Geophysics and Geophysical Exploration
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• v.27 no.1
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• pp.1-22
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• 2024

Carbon dioxide capture utilization and storage (CCUS) techniques have received significant global attention as they are part of efforts to achieve carbon neutrality by 2050. Large-scale carbon dioxide capture and storage (CCS) projects are being actively pursued in North America, the North Sea, the Middle East, and Oceania. Considering the current situation in South Korea, identifying large-scale CCS sites that can secure an annual domestic carbon storage capacity of 30 million tons by 2050 is crucial Therefore, this study analyzed the formation process and geological characteristics of overseas large-scale CCS projects in terms of plate tectonics. We utilized the GPlates program to interpret the formation processes of large-scale CCS projects in North America, the North Sea, Middle East, and Oceania from the perspective of plate tectonics. Additionally, we investigated the geological structure of the CO₂ storage layer and interpreted seismic imaging results obtained from each CCS site. This study will help identify a domestic large-scale CCS site.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.380-385
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• 2009

The absorption rate of carbon dioxide with 2-amino-2-methyl-1-propanol(AMP) was measured in such non-aqueous solvents as methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, and propylene carbonate, and in water at 298 K and 101.3 kPa using a semi-batch stirred tank with a plane gas-liquid interface. The overall reaction rate constant, obtained under the condition of fast reaction regime, from the measured rate of absorption was used to get the elementary reaction rate constants in complicated reactions represented by reaction mechanism of carbamate formation and the order of overall reaction of $CO_2$ with amine. The correlation between the elementary reaction rate constant and the solubility parameter of the solvent was also presented.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.4
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• pp.391-399
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• 2016

In this study, carbon dioxide ($CO_2$) was used as an inhibitor of scale production on the surface of RO membrane. In order to compare the effects of $CO_2$ injection on scale production, four RO modules: 1) without $CO_2$ injection and anti-scalant (RO module #1), 2) with only $CO_2$ injection (RO module #2), 3) with only anti-scalant (RO module #3), 4) with both $CO_2$ injection and anti-scalant (RO module #4), were operated for 60 days under constant flux mode. The trans-membrane pressure (TMP) was observed to decrease significantly in RO modules with $CO_2$ injection as compared with the other RO modules. When the feed water pH was controlled at 5.0 by injecting $CO_2$, the maximum TMP in RO modules #2 and #4 was founded to decrease by 42 and 40%, respectively. Moreover, the $Ca^{2+}$ concentration in the concentrate was 20mg/L lower in RO modules without $CO_2$ injection which is attributed to the scale formation on the surface of the RO membranes. The SEM-EDS analysis further showed a serious fouled RO membrane surface in RO modules #1 and #3.

• Proceedings of the KOR-BRONCHOESO Conference
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• 1983.05a
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• pp.7.2-8
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• 1983

Chronic laryngotracheal stenosis is becoming increasingly prevalent. Many acceptable procedures such as repeated dilation, laryngotracheoplasty and end-to-end anastomosis had been done according to it's indication, but it have given less than favorable results. Since 1972 the experimental and clinical experiences of Jako and Strong, the carbon dioxide laser has offered a valuable tool to the otolaryngologist. Mihashi (1976) and Lyons (1980) reported use of laser to the management of laryngotracheal stenosis with successful results. From April 82' to March 83', using the carbon dioxide laser, the various obstructing lesions were excised microendoscopically which include four patients considered failures from conventional surgical technique and one patient laryngeal stenosis occured after hemilaryngectomy and neoglottis formation. We concluded as follows, 1) Laser surgery is a useful method to the management of laryngotracheal stenosis in maintaining adequate airway. 2) Formation of granulation after laser surgery was less than other conventional methods.