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Absorption of Carbon Dioxide into Polar Solvents of 2-Amino-2-Methyl-1-Propanol  

Son, Young-Sik (Division of Chemical Engineering, Pusan National University)
Heo, Nam-Hwan (Technical Research Laboratories, POSCO)
Lee, Sung-Su (Technical Research Laboratories, POSCO)
Park, Sang-Wook (Division of Chemical Engineering, Pusan National University)
Publication Information
Korean Chemical Engineering Research / v.47, no.3, 2009 , pp. 380-385 More about this Journal
Abstract
The absorption rate of carbon dioxide with 2-amino-2-methyl-1-propanol(AMP) was measured in such non-aqueous solvents as methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, and propylene carbonate, and in water at 298 K and 101.3 kPa using a semi-batch stirred tank with a plane gas-liquid interface. The overall reaction rate constant, obtained under the condition of fast reaction regime, from the measured rate of absorption was used to get the elementary reaction rate constants in complicated reactions represented by reaction mechanism of carbamate formation and the order of overall reaction of $CO_2$ with amine. The correlation between the elementary reaction rate constant and the solubility parameter of the solvent was also presented.
Keywords
Absorption; Carbon Dioxide; 2-Amino-2-Methyl-1-Propanol; Organic Solvent;
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Times Cited By KSCI : 1  (Citation Analysis)
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