• Title/Summary/Keyword: carbon concentration

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Adsorption behaviour of film-forming amine on pre-oxidized carbon steel surface

  • Genxian, Lin;Yun, Sun;Canshuai, Liu;Jun, Fang;Lijun, Song;Bin, Liu
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1185-1194
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    • 2022
  • The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.

Properties of Water-Based Paint According to the Mixing Ratio of Powdered Activated Carbon (분말활성탄 혼입률에 따른 수성도료의 특성)

  • Choi, Byung-Cheol;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.48-49
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    • 2020
  • Recently, as people's interest in environmental pollution increases, interest in indoor air pollution as well as outdoors is increasing. Accordingly, this study prepares functional paints by mixing powder activated carbon, which is a porous material, into aqueous paints, and examines the adsorption performance of volatile organic compounds (VOCs) and formaldehyde (HCHO). As a result of the experiment, the concentration of volatile organic compounds (VOCs) and formaldehyde (HCHO) tended to decrease as powder activated carbon was incorporated. It is believed that physical adsorption was achieved by the micropores of powdered activated carbon. However, in the adsorption test method, it is judged that the concentration was affected by the inflow of outside air as the chamber cover was opened to put the test object in the empty chamber where a certain concentration was maintained.

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Carbon Dioxide Fluctuation in Suncheon Bay Measured by Infrared and Ultrasonic sensors (적외선과 초음파 센서로 측정한 순천만 이산화탄소 변동)

  • Kim, Sang-Jin;Kim, Min-Seong;Lee, Kyung-Hun;Kwon, Byung-Hyuk;Yoon, Hong-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.1
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    • pp.157-164
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    • 2021
  • Wind and temperature were measured with a three-dimensional ultrasonic anemometer and the carbon dioxide concentration was measured using an infrared sensor in the tidal flat of Suncheon Bay. In general, as the temperature increases, the concentration of carbon dioxide increases, and as the temperature decreases, the carbon dioxide also decreases in the atmosphere. However, since photosynthesis declined immediately after the sunset, the concentration of carbon dioxide increased as the temperature decreased. In addition, near the high tide when the tidal flat is covered with seawater, the atmospheric turbulence was strong despite an increase in temperature, resulting in a decrease in carbon dioxide concentration. It is necessary to quantitatively evaluated the effects of photosynthesis, respiration and atmospheric turbulence on the change of carbon dioxide concentration over tidal flat ecosystems.

The Relationship between the Fractionation Characteristics and Decomposition Rate of Organic Carbon in Nam River and Geumho River (남강 및 금호강에서 유기탄소 존재형태와 분해속도와의 관계)

  • Ho-Sub Kim;Seok-Gyu Kim;Seung-Young Oh
    • Journal of Korean Society on Water Environment
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    • v.39 no.2
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    • pp.131-141
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    • 2023
  • In this study, the relationship between organic carbon distribution characteristics and decomposition rate classified according to the particle size and biological degradation characteristics in water was investigated for the Nam river and Geumho river. The average concentrations of TOC in the Nam river and Geumho river were 2.7±1.2 mg/L and 5.0±1.2 mg/L, respectively, but the composition ratios for each type of organic carbon were similar. An average value of 80.9% of TOC was present as DOC and 72.8% of DOC consisted of Refractory-DOC (RDOC). In addition, the change in the RDOC composition ratio according to temporal and spatial distribution was the smallest. There was no difference in the decomposition rate of organic carbon except for TOC by the site (p≥0.108, one-way ANOVA), and the decomposition rates of Labile-POC (LPOC) and LDOC were similar at 0.139±0.102 and 0.137±0.149 day-1, respectively (p=0.110, paired t-test). The coefficient of variation (CV) of the decomposition rate of DOC (average 8.1%), which had the smallest composition ratio of organic carbon, was 1.1, showing the largest temporal variation. The TOC, POC, and DOC decomposition rates showed a significant correlation with the ratio of the initial concentration to the concentration after 25 days of decomposition (OC25/OC0) (r2=0.89~0.94, p<0.001), and the decomposition rates of LPOC and LDOC were significantly correlated with the ratio of the initial concentration to the concentration after 5 days of decomposition (LOC5/LOC0) (r2=0.67~0.75). This suggests that it is possible to estimate the decomposition rate through the concentration of each type of organic carbon.

Effect of Triacetin and Activated Carbon on the Hardness of Cellulose Acetate Filter containing Activated Carbon (활성탄과 가소제가 탄소복합필터의 경도에 미치는 영향)

  • 신창호;김종열;김정열;김영호;이영택
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.2
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    • pp.157-163
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    • 2000
  • Filter hardness is important to filter and cigarette manufactures because it is directly related to the ability of a plugmaker during making filter and to the acceptability of the filter by the consumer. In general, glycerol triacetate(Triacetin, TA) is the currently used common plasticizer in making filters from cellulose acetate tow and the effect of triacetin on hardness of filter which is made of mono cellulose acetate tow was well known. But unfortunately, the effect of triacetin on the hardness of cellulose acetate filter containing ativated carbon(carbon filter) was not reported so far. In this study, we manufactured filters with various carbon content at different triacetin concentrations and then analyzed the filter hardness and pressure drop. Filter hardness was directly increased with triacetin concentration but pressure drop was not affected and the effect of carbon content on filter hardness was smaller than that of triacetin concentration. However, pressure drop was directly increased with carbon content.

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Global Carbon Budget and Ocean Buffering against Rising Atmospheric CO2 Concentration

  • Kwon, O-Yul
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.773-781
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    • 2002
  • The natural carbon cycle has been perturbed since the mid-19th century by anthropogenic CO$_2$emissions from fossil fuel combustion and deforestation due to population growth and industrialization. The current study simulated the global carbon cycle for the past 42 years using an eight-box carbon cycle model. The results showed that since the terrestrial biospheric carbon sink was roughly offset by the deforestation source, the fossil fuel emission source was partitioned between the atmospheric and oceanic sinks. However, the partitioning ratio between the atmosphere and the ocean exhibited a change, that is, the carbon accumulation rate was faster in the atmosphere than in the ocean, due to a decrease in the so-called ocean buffering capacity. It was found that the ocean buffering capacity to take up excess CO$_2$decreased by 50% in terms of the buffer factor over the past 42 years. Accordingly, these results indicate that if the current CO$_2$emission trend continues, the future rate of increase in the atmospheric CO$_2$concentration will accelerate.

Study on the Dissolution Characteristics of Liquid $CO_2$ Released by Fixed Pipeline (고정 파이프라인에서 분사된 액체 이산화탄소 용해특성 연구)

  • 김남진;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.9
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    • pp.863-871
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    • 2004
  • The use of fossil fuels like coal, oil and natural gases around the world causes an increase of the carbon dioxide content in the atmosphere. In order to reduce the concentration of the greenhouse gas, the idea of carbon dioxide sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth by fixed pipeline are performed. The results show that carbon dioxide droplets change to carbon dioxide bubbles in gas phase around 500m in depth, and the droplets are completely dissolved below 500 m in depth if the liquide carbon dioxide is released both at 1,000 m in depth with the initial diameter of 0.007m or less and at 1,500m in depth with the diameter of 0.011m or less.

Regional Background Levels of Carbon Monoxide Observed in East Asia during 1991~2004 (1991~2004년 동아시아에서 관측한 일산화탄소의 지역적 배경 농도)

  • Kim, Hak-Sung;Chung, Yong-Seung
    • Journal of the Korean earth science society
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    • v.27 no.6
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    • pp.643-652
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    • 2006
  • Data of the carbon monoxide concentration observed in Mt. Waliguan in China (WLG), Ulaan Uul in Mongolia (UUM), Tae-ahn Peninsula in Korea (TAP), and Ryori in Japan (RYO) were analyzed for a long period between 1991 and 2004. The annual average concentration of carbon monoxide was the highest at TAP $(233{\pm}41ppb)$ followed by $RYO(171{\pm}36ppb),\;UUM(155{\pm}26ppb),\;and\;WLG(135{\pm}22ppb)$. The seasonal variations being high in spring and low in summer were observed in other areas of Eastern Asia except WLG. TAP was high in carbon monoxide concentration in all seasons compared to WLG, UUM and RYO and shows wide distribution of concentration in the histogram, which is caused by the influence of large-scale air pollution due to its downwind location close to the East Asian continent, China in particular. Also, our data was compared with data measured at Mauna Loa (MLO) in Hawaii. According to the origin of the isentropic backward trajectory and its transport passage, carbon monoxide concentration observed in TAP was analyzed as follows: continental background airflows (CBG) were $216{\pm}47ppb$; regionally polluted continental airflows (RPC) were $316{\pm}56ppb$; Oceanic background airflows (OBG) were $108{\pm}41ppb$; and Partly perturbed oceanic airflows (PPO) were $161{\pm}6ppb$. The high concentration of carbon monoxide in TAP is due to the airflow from East Asian continent origin rather than that from the North Pacific origin. Especially, RPC which passes through the eastern China appeared to be the highest in concentration in spring, fall, and winter. However, OBG was affected by the North Pacific air mass with a low carbon monoxide concentration in summer. The NOAA satellite images and GEOS-CHEM model simulation confirmed a large-scale air pollution event that was in the course of expansion from southeastern China bound to the Korean Peninsula and the Korea East Sea by way of the Yellow Sea.

The Effect of Silicon-Alloying on the Characteristics of the Pyrolytic Carbonds Deposited in Tumbling Bed by CVD (Tumbling Bed에서 화학증착법에 의해 증착되는 열분해탄소의 특성에 미치는 Silicon-Alloying의 효과)

  • 윤영진;이재영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.166-172
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    • 1983
  • In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.

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Measurement of Black Carbon Concentration and Comparison with PM10 and PM2.5 Concentrations monitored at the Chungcheong Province in Korea. (충청지역 블랙카본 농도 측정 및 PM10, PM2.5 농도와의 비교 분석 연구)

  • Cha, Youngbum;Lee, Shihyoung;Lee, Jeonghoon
    • Particle and aerosol research
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    • v.13 no.2
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    • pp.97-104
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    • 2017
  • In order to characterize atmospheric aerosols in Chungcheong area, black carbon concentration, which is known to be closely related to global warming, was measured and compared with $PM_{10}$, $PM_{2.5}$ concentrations and various meteorological parameters such as wind velocity and wind direction. Multi Angle Absorption Photometer (MAAP), a filter-based equipment, was used for the black carbon measurement, and the $PM_{10}$, $PM_{2.5}$ concentrations, wind velocity and wind direction were provided by the local monitoring stations. Black carbon concentration was monitored to be high in spring and winter but low in fall. $PM_{10}$ concentration was observed to be high when westerly wind was strong.