Browse > Article
http://dx.doi.org/10.1016/j.net.2021.10.025

Adsorption behaviour of film-forming amine on pre-oxidized carbon steel surface  

Genxian, Lin (Suzhou Nuclear Power Research Institute Co., Ltd.)
Yun, Sun (Suzhou Nuclear Power Research Institute Co., Ltd.)
Canshuai, Liu (Suzhou Nuclear Power Research Institute Co., Ltd.)
Jun, Fang (Suzhou Nuclear Power Research Institute Co., Ltd.)
Lijun, Song (Suzhou Nuclear Power Research Institute Co., Ltd.)
Bin, Liu (Suzhou Nuclear Power Research Institute Co., Ltd.)
Publication Information
Nuclear Engineering and Technology / v.54, no.4, 2022 , pp. 1185-1194 More about this Journal
Abstract
The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.
Keywords
Condenser; Pre-oxidized carbon steel; Octadecylamine; Maintenance; Adsorption mechanism;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 A. Osnis, C.N. Sukenik, D.T. Major, Structure of carboxyl-acid-terminated self-assembled monolayers from molecular dynamics simulations and hybrid quantum mechanics molecular mechanics vibrational normal mode analysis [J] 116 (2012) 770.   DOI
2 D.H. Xia, J. Wang, Z. Qin, et al., Sulfur induced corrosion (SIC) mechanism of steam generator (SG) tubing at micro scale: a critical review [J], Mater. Chem. Phys. 233 (2019) 133.   DOI
3 D.H. Xia, Y. Behnamian, J.L. Luo, Factors influencing sulfur induced corrosion on the secondary side in pressurized water reactors (PWRs) [J], J. Electrochem. Soc. 166 (2) (2019) C49.   DOI
4 A. Zarrouk, H. Zarrok, R. Salghi, et al., Evaluation of N-containing organic compound as corrosion inhibitor for carbon steel in phosphoric acid [J], J. Mater. Environ. Sci. 4 (2) (2013) 177.
5 K.F. Khaled, Adsorption and inhibitive properties of a new synthesized guanidine [J], Appl. Surf. Sci. 255 (2008) 1811.   DOI
6 K.F. Khaled, Electrochemical behavior of nickel in nitric acid and its corrosion inhibition using some thiosemicarbazone derivatives [J], Electrochim. Acta 55 (2010) 5375.   DOI
7 A. Madhankumar, S. Nagarajan, N. Rajendran, et al., Effect of Si nanoparticles on the corrosion protection performance of organic coating on carbon steel in chloride environment [J], Met. Mater. Int. 18 (6) (2012) 965.   DOI
8 J.P. Zeng, J.Y. Zhang, X.D. Gong, Molecular dynamics simulation of interaction between benzotriazoles and cuprous oxide crystal [J], Computational and Theoretical Chemistry 963 (2011) 110.   DOI
9 Y.M. Tang, X.Y. Yang, W.Z. Yang, et al., Experimental and molecular dynamics studies on corrosion inhibition of mild steel by 2-amino-5-phenyl-1,3,4-thiadiazole [J], Corrosion Sci. 52 (2010) 242.   DOI
10 S.M. Xia, M. Qiu, L.M. Yu, et al., Molecular dynamics and density functional theory study on relationship between structure of imidazoline derivatives and inhibition performance [J], Corrosion Sci. 50 (2008) 2021.   DOI
11 W. Kuang, J. Mathews, M.L. Taylor, et al., The effect of Anodamine on the corrosion behavior of 1018 mild steel in deionized water: II. Electrochemical impedance analysis [J], Electrochim. Acta 136 (2014) 493.   DOI
12 G.J. Verib, An alternative chemistry for both operational and layup protection of high-pressure steam-water cycles using an organic filming amine, Power Plant Chemistry 13 (2011) 262.
13 W. Ronny, C. Erwin, Experience in preservation of the water steam cycle in CCPP (combined cycle power plants) with ODA (octadecylamine) [J], J. Energy Power Eng. 10 (2016) 32.
14 W. Kuang, J. Mathews, D. Macdonald, The effect of Anodamine on the corrosion behavior of 1018 mild steel in deionized water: I. Immersion and polarization tests [J], Electrochim. Acta 127 (2014) 79.   DOI
15 S. Choi, K. Fruzzetti, M. Caravaggio, et al., Filming Amines: A Pathway to Wider Use in PWRs Paper Number: 60, in: 20th NPC International Conference, 2016.
16 B. Khodyrev, A. Krichevtsov, A. Sokolyuk, Therm. Eng. 57 (2010) 553.   DOI
17 C.N. Cao, Principles of Electrochemistry of Corrosion, fourth ed., Chemical Industry Press, Beijing, 2008, p. 205.
18 C.E. Banica, E. Czempik, C. Vogt, et al., Influence of hot water conditioning on the corrosion behaviour of carbon steel, [J]. Materials and corrosion 53 (2002) 256.   DOI
19 S. Choi, Pressurized Water Reactor Secondary Side Filming Amine Application: Scoping Assessment, 2016. Technical report, 3002008187.
20 F.X. Mao, C.F. Dong, D.D. Macdonald, Effect of octadecylamine on the corrosion behavior of type 316SS in acetate buffer, Corrosion Sci. 98 (2015) 192.   DOI
21 C.W. Turner, Fouling of nuclear steam generators: fundamental studies, operating experience and remedial measures using chemical additives, AECL Nuclear Review 2 (2013) 61.   DOI
22 N. Ochoa, G. Baril, F. Moran, et al., Study of the properties of a multicomponent inhibitor used for water treatment in cooling circuits [J], J. Appl. Electrochem. 32 (2002) 497.   DOI
23 Q.Q. Liao, G.D. Zhou, H.H. Ge, et al., Characterization of surface film on iron samples treated with octadecylamine [J], Corrosion Eng. Sci. Technol. 42 (2007) 102.   DOI
24 H.H. Ge, G.D. Zhou, Q.Q. Liao, et al., A study of anti-corrosion behavior of octadecylamine-treated iron samples [J], Appl. Surf. Sci. 156 (2000) 39.   DOI
25 J. Baux, N. Causse, J. Esvan, et al., Impedance analysis of film-forming amines for the corrosion protection of a carbon steel [J], Electrochim. Acta 283 (2018) 699.   DOI
26 N. Ochoa, F. Moran, N. Pebere, The synergistic effect between phosphonocarboxylic acid salts and fatty amines for the corrosion protection of a carbon steel [J], J. Appl. Electrochem. 34 (2004) 487.   DOI
27 Z.M. Zhang, J.Q. Wang, E.-H. Han, et al., Influence of dissolved oxygen on oxide films of Alloy 690TT with different surface status in simulated primary water [J], Corrosion Sci. 53 (2011) 3623.   DOI
28 Z.M. Zhang, J.Q. Wang, E.-H. Han, et al., Trans-twins stress corrosion cracking behaviors of Alloy 690TT in lead-containing caustic solution at 330 C [J], Nucl. Eng. Des. 241 (2011) 4944.   DOI
29 C.S. Liu, J.Q. Wang, Z.M. Zhang, et al., Effect of cumulative gamma irradiation on microstructure and corrosion behaviour of X65 low carbon steel [J], J. Mater. Sci. Technol. 34 (2018) 2131.   DOI
30 T. Barres, B. Tribollet, O. Stephan, et al., Characterization of the porosity of silicon nitride thin layers by Electrochemical Impedance Spectroscopy [J], Electrochim. Acta 227 (2017) 1.   DOI
31 H. Jamil, A. Shriri, R. Boulif, et al., Electrochemical behaviour of amino alcohol-based inhibitors used to control corrosion of reinforcing steel[J], Electrochim. Acta 49 (2004) 2753.   DOI
32 S. Delaunay, Effect of Film-Forming Amine Injection on Corrosion Products Behavior in Feed Water System Conditions, Materials Ageing Institute, 2017, 6125-4501-2017-01308-EN.
33 A. Drexler, S. Weiss, N. Caris, et al., AREVA's Toolbox for Long Term Best Performance and Reliable Operation of Nuclear Steam Generators, Symposium on Water Chemistry and Corrosion in Nuclear Power Plants in Asia, Anupuram, 2015.
34 C.S. Liu, G.X. Lin, Y. Sun, et al., Effect of octadecylamine concentration on adsorption on carbon steel surface [J], Nuclear engineering and technology 52 (10) (2020) 2394.   DOI
35 N. Ochoa, F. Moran, N. Pebere, Influence of flow on the corrosion inhibition of carbon steel by fatty amines in association with phosphonocarboxylic acid salts [J], Corrosion Sci. 47 (2005) 593.   DOI
36 S. Wang, S. Song, J. Wang, et al., Correlation between passivity breakdown and composition of passive film formed on alloy 690 studied by sputtering XPS and FIB-HRTEM [J], J. Electrochem. Soc. 166 (12) (2019) C332.   DOI
37 RAMMINGER, Method for Conditioning a Power Generation Circulatory System of a Power Plant: US20140102481A1 [P], 2014, 04-17[2019-07-04].
38 I. Betova, M. Bojinov, T. Saario, Film-forming Amines in Steam/water Cycles-Structure, Properties, and Influence on Corrosion and Deposition processes [R], VTT-R-03234-14, 2014, p. 1.
39 E. Sosa, R. Cabrera-Sierra, M.E. Rincon, et al., Evolution of non-stoichiometric iron sulfide film formed by electrochemical oxidation of carbon steel in alkaline sour environment [J], Electrochim. Acta 47 (2002) 1197.   DOI