• Title/Summary/Keyword: carbide behavior

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A Study of Carbide Thapping and Growth in the Directional Solidification of MAR-M247 LC Super alloy (Ni기 초내열합금의 일방향 응고에서 탄화물의 Trapping과 성장 거동)

  • Lee, Jae-Hyeon;Jin, Geon;Lee, Yong-Tae;Choe, Seung-Ju
    • 연구논문집
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    • s.26
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    • pp.95-102
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    • 1996
  • The carbide growth behavior of MAR-M247 LC alloy was investigated by directional solidification and quench method. The carbide volume fraction, trapping and growth behavior were correlated with the growth rate. It was found that the carbide volume fraction decreases at slower growth rate. This decreasing was caused by lower solid-liquid interface trapping ability at the slower growth rate.

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Finite element modeling of the vibrational behavior of multi-walled nested silicon-carbide and carbon nanotubes

  • Nikkar, Abed;Rouhi, Saeed;Ansari, Reza
    • Structural Engineering and Mechanics
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    • v.64 no.3
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    • pp.329-337
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    • 2017
  • This study concerns the vibrational behavior of multi-walled nested silicon-carbide and carbon nanotubes using the finite element method. The beam elements are used to model the carbon-carbon and silicon-carbon bonds. Besides, spring elements are employed to simulate the van der Waals interactions between walls. The effects of nanotube arrangement, number of walls, geometrical parameters and boundary conditions on the frequencies of nested silicon-carbide and carbon nanotubes are investigated. It is shown that the double-walled nanotubes have larger frequencies than triple-walled nanotubes. Besides, replacing silicon carbide layers with carbon layers leads to increasing the frequencies of nested silicon-carbide and carbon nanotubes. Comparing the first ten mode shapes of nested nanotubes, it is observed that the mode shapes of armchair and zigzag nanotubes are almost the same.

Oxidation Behavior of WC-TiC-TaC Binderless Cemented Carbide under Low Partial Pressure of Oxygen

  • Uchiyama, Yasuo;Ueno, Shuji;Sano, Hideaki;Tanaka, Hiroki;Nakahara, Kenji;Sakaguchi, Shigeya;Nakano, Osamu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.355-356
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    • 2006
  • WC-TiC-TaC binderless cemented carbide was oxidized under low partial pressure of oxygen (50ppm) at 873K for 1 to 20 h. Surface roughness was measured using atomic force microscope, and effect of TiC amount on oxidation behavior of the carbide was investigated. WC phase was oxidized more easily than WC-TiC-TaC solid solution phase. With an increase in TiC amount, WC-TiC-TaC phase increased and the oxidation resistance of the carbide increased.

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Characteristics of Hardness of $(Cr,\;Fe)_7C_3$ in the Chromium-Carbide-Type Chromium White Iron Hardfacing Weld Deposits (크롬탄화물형 크롬백철 오버레이 용착금속에서의 $(Cr,\;Fe)_7C_3$의 경도특성)

  • Baek Eung-Ryul
    • Journal of Welding and Joining
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    • v.23 no.2
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    • pp.75-80
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    • 2005
  • The effect of chemical constituents of $(Cr,\;Fe)_7C_3$ carbide phase on its hardness in the chromium-carbide type Cr white iron hardfacing weld deposits has been investigated. In order to examine $(Cr,\;Fe)_7C_3$ carbide phase, a series of filler metals with varying chromium contents was used. The alloys were deposited once or twice on a mild steel plate using the self?shielding flux cored arc welding process. The hardness of $(Cr,\;Fe)_7C_3$ carbide phase was measured by the micro-Vickers hardness test. It was shown that hardness of $(Cr,\;Fe)_7C_3$ carbide phase increased with increasing Cr content in $(Cr,\;Fe)_7C_3$ carbide phase. This behavior of the hardness of $(Cr,\;Fe)_7C_3$ carbide phase was explained by the types of chemical bonds that hold atoms together in $(Cr,\;Fe)_7C_3$ carbide phase.

Effect of Alloying Elements and Homogenization Treatment on Carbide Formation Behavior in M2 High Speed Steels (합금성분변화와 균질화처리에 따른 M2 고속도강의 탄화물 형성거동)

  • Ha, Tae Kwon;Yang, Eun Ig;Jung, Jae Young;Park, Shin Wha
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.589-597
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    • 2010
  • In the present study, the effect of variation in alloying elements on the carbide formation behavior during casting and homogenization treatment of M2 high speed steels was investigated. M2 high speed steels of various compositions were produced by vacuum induction melting. Contents of C, Cr, W, Mo, and V were varied from the basic composition of 0.8C, 0.3Si, 0.2Mn, 4.0Cr, 6.0W, 5.0Mo, and 2.0V in weight percent. Homogenization treatment at $1150^{\circ}C$ for 1.5 hr followed by furnace cooling was performed on the ingots. Area fraction and chemical compositions of eutectic carbide in as-cast and homogenized ingots were analyzed. Area fraction of eutectic carbide appeared to be higher in the ingots with higher contents of alloying elements the area fraction of eutectic carbide also appeared to be higher on the surface regions than in the center regions of ingots. As a result of the homogenization treatment, $M_2C$ carbide, which was the primary eutectic carbide in the as-cast ingots, decomposed into thermodynamically stable carbides, MC and $M_6C$. The latter carbide was found to be the main one after homogenization. Fine carbides uniformly distributed in the matrix was found to be MC type carbide and coarsened by homogenization.

Effect of Microstructure on Fracture Behavior of Multi-phase Low-density Steel (다상계 저비중강의 파괴거동에 미치는 미세조직의 영향)

  • Shin, Sun-Kyoung;Park, Seong-Jun;Cho, Kyung Mox
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.6
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    • pp.306-316
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    • 2013
  • Microstructure and fracture behavior of a multi-phase low-density steel were investigated. After hot-rolling and heat treatment, the microstructure of low-density steel was composed of coarse ferrite grains and elongated bands which include second phases such as austenite, martensite and ${\kappa}$-carbide depending on holding time during isothermal heat treatment. After tensile test, microcracks were observed at martensite or ${\kappa}$-carbide interface in the elongated bands. Coarse ferrite grains showed cleavage fracture behavior regardless of second phase. The cleavage fracture of ferrite could be attributed to their coarse grain size and solute atoms that increase ductile-to-brittle transition temperature of ferrite. Despite of the tendency of cleavage fracture in coarse ferrite grains, a specimen having coarse spheroidized ${\kappa}$-carbide particles in the elongated bands showed high total elongation of 30%. Thus, the easiness of plastic deformation in the elongated band seems to play an important role in retardation of cleavage crack formation in coarse ferrite grains.

Effect of Volume Fraction of Cr Carbide Phase on the Abrasive Wear Behavior of the High Cr White Iron Harcfacing Weld Deposits (고크롬 철계 오버레이용접층의 긁힘마모거동에 미치는 크롬탄화물 양의 영향)

  • 백응률
    • Journal of Welding and Joining
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    • v.16 no.1
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    • pp.125-133
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    • 1998
  • The effect of volume fraction of Cr carbide phase (Cr CVF) on the low stress abrasion resistance in the chromium-carbide-type high Cr white iron hardfacing weld deposits has been investigated. In order to examine Cr CVF, a series of alloys with varying Cr CVF by changing chromium and carbon contents and the ratio of Cr/C were employed. The alloys were deposited once or twice on a mild steel plate using the self-shielding flux cored arc welding process. The low stress abrasion resistance of the alloys against sands was measured by the Dry Sand/Rubber Wheel Abrasion Test (RWAT). It was shown that hardness and abrasion resistance increased with increasing Cr CVF within the whole test range (Cr CVF : 0.23-0.64). Both primary Cr carbide and eutectic Cr carbide were particularly effective in resisting wear due to their high hardness.

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Effects of Interface Boundary Strength on Wear and Wear Transition during Sliding in Silicon Carbide Ceramics (탄화규소계 세라믹스에서 미끄럼시의 마모 및 마모천이에 미치는 계면강도의 영향)

  • Kim, Dong-Jin;Park, Seong-Khil;Ryu, Hyun;Um, Chang-Do;Cho, Seong-Jai;Kim, Seock-Sam
    • Tribology and Lubricants
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    • v.11 no.4
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    • pp.21-27
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    • 1995
  • The effects of interface boundary strength on wear and wear transition during sliding have been investigated in silicon carbide ceramics. Three different microstructures, i.e., solid state sintered silicon carbide, liquid phase sintered silicon carbide and liquid phase sintered silicon carbide composite reinforced with TiB$_{2}$ particulates, were designed by hot pressing. Examinations of crack patterns and fracture modes indicated that interface boundaries were relatively strong between silicon carbide grains in the solid state sintered silicon carbide, intermediate in the liquid phase sintered silicon carbide and weak between silicon carbide grains and TiB$_{2}$ particles in the composite. Wear data and examinations of worn surfaces revealed that the wear behavior of these silicon carbide ceramics could be significantly affected by the interface strength. In the solid state sintered silicon carbide, the wear occurred by a grooving process. In the liquid phase sintered silicon carbide and composite, on the other hand, an abrupt transition in wear mechanism from initial grooving to grain pull-out process occurred during the test. The transition occurred significantly earlier in the composite than in the carbide.

Material Degradation of X20 Steel (12Cr-1MoVNi) for Boiler Tube of Power Plant (발전설비 보일러 튜브용 X20강의 가속열처리에 의한 재질 열화)

  • Choe, Byung-Hak;Yoon, Kee Bong;Lee, Nam-Hyuck;Kim, Sin;Lee, Gil-Jae;Kim, Kwang-Ho;Kwon, Dong Il
    • Korean Journal of Metals and Materials
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    • v.46 no.5
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    • pp.276-282
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    • 2008
  • Material degradation of Cr steels in boiler tubes was accompanied by the microstructural changes including carbide behavior and crack formation. The microstructural change and the mechanical behavior of hardness and creep properties in accelerated heat-treatments were studied in order to identify the material degradation of the X20 Cr steel. The degradation behavior was occurred in the hardness increasing followed by decreasing due to carbide dissolution and precipitation.

Toughening of Boron Carbide Ceramics by Addition of $TiB_2$ ($TiB_2$ 첨가에 의한 탄화붕소 소결체의 파괴인성 증진)

  • 이채현;박원규;김종희
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.464-470
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    • 1996
  • Toughening mechanism of boron carbide ceramics by the addition of titanium boride was investigated. Speci-men was prepared by hot pressing of boron carbide with upto 30vol% of titanium boride particulates. Toughness of boron carbide ceramics was increased from 4.7 MPa m1/2 to 6.3 MPa m1/2 with 15 vol% TiB2 addition. But further increase of TiB2 content results in slow decrease of toughness. From microstructure evaluation and crack propagation behavior it is concluded that the major toughening mechanism is crack deflection pheno-mena.

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