• Title/Summary/Keyword: carbide analysis

Search Result 335, Processing Time 0.032 seconds

The Properties Analysis of 600V Grade Polyvinyl Chloride Insulated Wire with Variation of Thermal Stress (열적 스트레스 변화에 따른 600V 비닐절연전선의 특성 분석)

  • 최충석
    • Fire Science and Engineering
    • /
    • v.15 no.1
    • /
    • pp.108-115
    • /
    • 2001
  • In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to 600V grade polyvinyl chloride insulated wire (IV). In the structure analysis, normal wire has the properties of direction on the surface, but in case of deteriorated wire at above $400^{\circ}c$, it formed the carbide, the crack and the crystal. The surface composition rate of normal wire was Cu : 100%, but the section composition of the deteriorated wire at $800^{\circ}c$ showed Cu : 78.89%, O : 21.11%. In result of analyzing the differential scanning calory of copper wire, the new reaction peak was observed on the deteriorated wire at above $700^{\circ}c$. In case of the deteriorated wire as $150^{\circ}c$ at the differential thermal analysis, an endothermic reaction appeared at $264^{\circ}c$ lower than the reactive point of normal wire. The occupation rate of oxygen according to the deterioration of copper wire is about 20% at $500^{\circ}c$.

  • PDF

A Study on Slurry Isolation Through Chemical Processing, with Comparative Analysis and Validation (화학적 처리를 적용한 Slurry 분리 및 비교분석 검증 연구)

  • Na, Wonshik
    • Journal of Digital Contents Society
    • /
    • v.14 no.1
    • /
    • pp.35-40
    • /
    • 2013
  • The use of slurry with a mix of abrasives and coolant for making Wire Saw in the photovoltaic industry has sharply increased with the semiconductor wafer. In this paper, the slurry was isolated, purified and dried by microwave drying method with high-purity silicon carbide powder obtained through chemical processing. Dried slurry bulk was first pulverized and chemical treatment was applied to produce powder. The produced slurry powder was then analyzed by going through the following analysis; thermal analysis, particle size analyses: SEM shots, elemental analysis, XRF and XRD. The results of this study found the recovery rate of the power obtained though the chemical processing to be higher than the one obtained from mineral processing. The results anticipate infrastructure building and active responses to increasingly stronger domestic and international environmental regulations through the integration and recycling of large amounts of slurry in the photovoltaic industry.

Fabrications and Analysis of Schottky Diode of Silicon Carbide Substrate with novel Junction Electric Field Limited Ring (새로운 전계 제한테 구조를 갖는 탄화규소 기판의 쇼트키 다이오드의 제작과 특성 분석)

  • Cheong Hui-Jong;Han Dae-Hyun;Lee Yong-Jae
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.10 no.7
    • /
    • pp.1281-1286
    • /
    • 2006
  • We have used the silicon-carbide(4H-SiC) instead of conventional silicon materials to develope of the planar junction barrier schottky rectifier for ultra high breakdown voltage(1,200 V grade). The substrate size is 2 inch wafer, Its concentration is $3*10^{18}/cm^{3}$ of $n^{+}-$type, thickness of epitaxial layer $12{\mu}m$ conentration is $5*10^{15}cm^{-3}$ of n-type. The fabticated devices are junction barrier schottky rectifier, The guard ring for improvement of breakdown voltage is designed by the box-like impurity of boron, the width and space of guard ring was designed by variation. The contact metals to rectify were used by the $Ni(3,000\:{\AA})/Au(2,000\:{\AA})$. As a results, the on-state voltage is 1.26 V, on-state resistance is $45m{\Omega}/cm^{3}$, maximum value of improved reverse breakdown voltage is 1180V, reverse leakage current density is $2.26*10^{-5}A/CM^{3}$. We had improved the measureme nt results of the electrical parameters.

Fatigue Life of the Repair TIG Welded Hastelloy X Superalloy

  • SIHOTANG, Restu;CHOI, Sang-Kyu;PARK, Sung-Sang;BAEK, Eung-Ryul
    • Journal of Welding and Joining
    • /
    • v.33 no.5
    • /
    • pp.26-30
    • /
    • 2015
  • Hastelloy X in this study was applied in jet engine F-15 air fighter as shroud to isolate the engine from outer skin. After 15 years operation at elevated temperature the mechanical properties decreased gradually due to the precipitation of continues second phases in the grain boundaries and precipitated inside the grain. The crack happened at the edge of the shroud due to the thermal and mechanical stress from jet engine. Selective TEM analysis found that the grain boundaries consist of $M_{23}C_6$ carbide, $M_6$ Ccarbide and small percentage of sigma(${\sigma}$) phase. Furthermore, it was confirmed the nano size of ${\sigma}$ and miu (${\mu}$) phase inside the grain. In this study, it was investigated the microstructure of the degraded shroud component and HAZ of repair welded shroud. In the HAZ, it was observed the dissolution of the $M_{23}C_6$ carbides and smaller precipitates, the migration of the undissolved larger $M_{23}C_6$ carbide and $M_6$ Ccarbide. It is also observed the liquation due to the simply melt of the segregated precipitates in the grain boundaries. Interestingly, the segregated second phases which simply melt in the grain boundaries more easily happened at higher heat input welding condition. High temperature tensile test was done at $300^{\circ}C$, $700^{\circ}C$ and $900^{\circ}C$. It was obtained that the toughness of welded sample is lower compare to the non-welded sample. The solution heat treatment at $1170^{\circ}C$ for 5 minutes was suggested to obtain a better mechanical properties of the shroud. The high cycle fatigue number of the repair welded shroud shows a much lower compare to the shroud. In addition, the high cycle fatigue number at room temperature after solution heat treatment was almost double compare to the before solution heat treatment under 420-500MPa stress amplitude. However, the high cycle fatigue number of repaired welded sample was shown a much lower compare to the non- welded shroud and solution treated shroud. One of the main reasons to decrease the tensile strength and the high cycle fatigue properties of the repair welded shroud is the formation of the liquid phase in HAZ.

Simulation and analysis of DC characteristics in AlGaN/GaN HEMTs on sapphire, SiC and Si substrates (Sapphire SiC, Si 기판에 따른 AlGaN/GaN HEMT의 DC 전기적 특성의 시뮬레이션과 분석)

  • Kim, Su-Jin;Kim, Dong-Ho;Kim, Jae-Moo;Choi, Hong-Goo;Hahn, Cheol-Koo;Kim, Tae-Geun
    • Journal of IKEEE
    • /
    • v.11 no.4
    • /
    • pp.272-278
    • /
    • 2007
  • In this paper, we report on the 2D (two-dimensional) simulation result of the DC (direct current) electrical and thermal characteristics of AlGaN/GaN HEMTs (high electron mobility transistors) grown on Si substrate, in comparison with those grown on sapphire and SiC (silicon carbide) substrate, respectively. In general, the electrical properties of HEMT are affected by electron mobility and thermal conductivity, which depend on substrate material. For this reason, the substrates of GaN-based HEMT have been widely studied today. The simulation results are compared and studied by applying general Drift-Diffusion and thermal model altering temperature as 300, 400 and 500 K, respectively. With setting T=300 K and $V_{GS}$=1 V, the $I_{D,max}$ (drain saturation current) were 189 mA/mm for sapphire, 293 mA/mm for SiC, and 258 mA/mm for Si, respectively. In addition, $G_{m,max}$ (maximum transfer conductance) of sapphire, SiC, Si was 38, 50, 31 mS/mm, respectively, at T=500 K.

  • PDF

A Study on the Properties of Transition Metal Nitride Coating Materials for the Recovery of Tungsten and Rare Metals (텅스텐 및 희유금속 회수를 위한 초경합금 전이금속질화물 코팅소재 특성연구)

  • Kim, Jiwoo;Kim, Myungjae;Kim, Hyokyeong;Park, Sohyun;Seo, Minkyeong;Kim, Jiwoong
    • Resources Recycling
    • /
    • v.31 no.1
    • /
    • pp.46-55
    • /
    • 2022
  • The recycling of coated cemented carbide scraps is becoming increasingly significant for the recovery of rare metals. However, coatings consisting of Group IV and V transition metal nitrides are one of the challenging factors in obtaining high-purity materials. We investigated the structural, elastic, and mechanical properties of Group IV and V transition-metal nitrides (TiN, VN, ZrN, NbN, HfN, and TaN) using first-principle calculations. Convergence tests were performed to obtain reliable calculated results. The equilibrium structures of the nitrides were in good agreement with those of a previous study, indicating the reliability of the data. Group IV transition metal nitrides show a higher covalent bonding nature. Thus, they exhibit a higher degree of brittleness than that of Group V transition metal nitrides. In contrast, Group V transition metal nitrides show weaker resistance to shear loading and more ductile behavior than Group IV transition metal nitrides because of the metallic bonds characterized by valence electron concentration. The results of the crystal orbital Hamilton population analysis showed good agreement with the shear resistance tendencies of all transition metal nitrides.

The Microstructures and Properties of Surface Layer on the Tool Steel Formed by Ion Nitriding -Effects of Process Parameter- (마이크로 펄스 플라즈마 질화에 의해 생성된 금형 공구강의 표면층에 관한 연구 -공정 변수의 영향-)

  • Lee, J.S.;Kim, H.G.;You, Y.Z.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.14 no.1
    • /
    • pp.8-16
    • /
    • 2001
  • The effects of gas composition, pressure, temperature and time on the case thickness, hardness and nitride formation in the surface of tool steels(STD11 and STD61) have been studied by micro-pulse plasma nitriding. External compound layer and internal diffusion layer and the diffusion layer were observed in the nitrided case of tool steels. The relative amounts and kind of phases formed in the nitrided case changed with the change of nitriding conditions. Generally, only nitride phases such as ${\gamma}(Fe_4N)$, ${\varepsilon}(Fe_{2-3}N)$, or $Cr_{1.75}V_{0.25}N_2$ phases were detected in the compound layer, while nitride and carbide phases such as ${\varepsilon}-nitride(Fe_{2-3}N)$, $(Cr,Fe)_{\gamma}C_3$ or $Fe_3C$ were detected in the diffusion layer by XRD analysis. The thickness of compound layer increased with the increase of nitrogen content in the gas composition. Maximum case depth was obtained at gas pressure of 200Pa.

  • PDF

Effect of Tempering Condition on Hydrogen Diffusion Behavior of Martensitic High-Strength Steel (템퍼링 조건이 마르텐사이트계 고강도강의 수소확산거동에 미치는 영향)

  • Park, Jin-seong;Hwang, Eun Hye;Lee, Man Jae;Kim, Sung Jin
    • Corrosion Science and Technology
    • /
    • v.17 no.5
    • /
    • pp.242-248
    • /
    • 2018
  • Martensitic high-strength steels revealed superior mechanical properties of high tensile strength exceeding 1000 Mpa, and have been applied in a variety of industries. When the steels are exposed to corrosive environments, however, they are susceptible to hydrogen embrittlement (HE), resulting in catastrophic cracking failure. To improve resistance to HE, it is crucial to obtain significant insight into the exact physical nature associated with hydrogen diffusion behavior in the steel. For martensitic steels, tempering condition should be adjusted carefully to improve toughness. The tempering process involves microstructural modifications, that provide changes in hydrogen diffusion/trapping behavior in the steels. From this perspective, this study examined the relationship between tempering condition and hydrogen diffusion behavior in the steels. Results based on glycerin measurements and hydrogen permeation evaluations indicated that hydrogen diffusion/trapping behavior was strongly affected by the characteristics of precipitates, as well as by metallurgical defects such as dislocation. Tempering condition should be adjusted properly by considering required mechanical properties and resistance to HE.

Effects of Pressure on Properties of SiC-$ZrB_2$ Composites through SPS (SPS법에 의한 SiC-$ZrB_2$ 복합체의 특성에 미치는 압력의 영향)

  • Shin, Yong-Deok;Lee, Jung-Hoon;Kim, Chul-Ho;Jin, Beom-Soo;Wu, Na
    • Proceedings of the KIEE Conference
    • /
    • 2011.07a
    • /
    • pp.1449-1450
    • /
    • 2011
  • The SiC-$ZrB_2$ composites were produced by subjecting a 40:60 (vol.%) mixture of zirconium diboride($ZrB_2$) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering(SPS) under argon atmosphere at 50MPa(P50) and 60MPa(P60) pressure. The relative density, 94.13% of P60 sample was lower than that, 94.75% of P50 sample. Reactions between ${\beta}$-SiC and $ZrB_2$ were not observed via x-ray diffraction (hereafter, XRD) analysis. The trend of flexural strength of SiC-$ZrB_2$ composites were in accordance with the relative density. The properties of a SiC-$ZrB_2$ composites through SPS under argon atmosphere were positive temperature coefficient resistance in the temperature range from $25^{\circ}C$ to $500^{\circ}C$, and electrical resistivity of P50 and P60 sample were $6.75{\times}10^{-4}$ and $7.22{\times}10^{-4}{\Omega}{\cdot}cm$ at room temperature, respectively.

  • PDF

The Drawing Properties of Aluminum Wire in Aged Overhead Conductor (폐가공송전선용 Al선재의 신선가공 특성)

  • Kim, Shang-Shu;Ku, Jae-Kwan;Lee, Young-Ho;Kim, Byung-Geol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.6
    • /
    • pp.482-487
    • /
    • 2013
  • The new recycling technology for aged aluminum wires in overhead conductor have been carried out. We are attempting to develop remanufacturing method for them for more effective way of recycling in stead of its conventional remelting process. The drawing process of aged aluminum wires play a role in remanufacture process. Drawing process was performed under lubricant. The speed of drawing was between 500 m/min and 1,000 m/min. These machines have 11 or 12 dies house for breakdown of the feedstock. Material of the die is tungsten carbide and they have generally 25% reduction ratio. The paper investigates the mechanical properties during drawing process of aged aluminum wire. The results of tensile tests and microscopic analysis were discussed to underscore the hardening features of drawing aluminum wire. Various graphs are presented accompanied by discussion about their relevance on the process.