• 제목/요약/키워드: burn-off

검색결과 63건 처리시간 0.024초

Microstructural changes of polyacrylonitrile-based carbon fibers (T300 and T700) due to isothermal oxidation (1): focusing on morphological changes using scanning electron microscopy

  • Oh, Seong-Moon;Lee, Sang-Min;Kang, Dong-Su;Roh, Jae-Seung
    • Carbon letters
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    • 제18권
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    • pp.18-23
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    • 2016
  • Polyacrylonitrile (PAN)-based carbon fibers have high specific strength, elastic modulus, thermal resistance, and thermal conductivity. Due to these properties, they have been increasingly widely used in various spheres including leisure, aviation, aerospace, military, and energy applications. However, if exposed to air at high temperatures, they are oxidized, thus weakening the properties of carbon fibers and carbon composite materials. As such, it is important to understand the oxidation reactions of carbon fibers, which are often used as a reinforcement for composite materials. PAN-based carbon fibers T300 and T700 were isothermally oxidized in air, and microstructural changes caused by oxidation reactions were examined. The results showed a decrease in the rate of oxidation with increasing burn-off for both T300 and T700 fibers. The rate of oxidation of T300 fibers was two times faster than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature.

활성탄소섬유의 미세기공 분석 및 흡착특성 (Micropore Analysis and Adsorption Characteristics of Activated Carbon Fibers)

  • 문동철;이광호;김창수;김도형;김미란;신채호;박일영;남성열;이창기
    • 분석과학
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    • 제13권1호
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    • pp.89-95
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    • 2000
  • 식물섬유, 합성섬유 및 혼합섬유를 원료로 하여 3등급의 활성탄소섬유를 제조하고 미세기공 및 세공특성을 검토하였다. 제조한 활성탄소섬유의 흡착등온선은 모두 $20{\AA}$ 이하의 기공크기를 나타내는 Type I을 보였으며 미세기공 직경은 $5.6{\pm}0.3{\AA}$ 이내에서 최대 분포를 나타냈다. 활성탄소섬유의 질소 또는 아르곤 흡착에 의한 비표면적($S_{BET}$), 산화율, 액상 요오드흡착에 대한 상관 관계를 조사한 결과 비표면적이 $1600m^2g^{-1}$까지는 비표면적의 증가와 액상 요오드흡착량이 직선 관계를 나타냈으나 그 이상의 비표면적에서는 요오드 흡착량이 낮은 결과를 보이고, 비표면적이 증가할수록 제품의 burn-off가 크게 나타났다.

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LPI 레이더에 대한 원격지원 재머의 주엽 재밍 효과 (Jamming Effect of Stand-Off Jammer to Main Lobe of LPI Radar)

  • 임중수;채규수
    • 융합정보논문지
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    • 제10권3호
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    • pp.16-21
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    • 2020
  • 본 논문은 저 측엽 안테나를 사용하는 LPI(Low Probability Interceptor)레이다를 재밍하는 원격지원 재머의 특성에 대하여 기술한다. LPI 레이다는 재밍 영향을 줄이기 위해서 송수신 안테나의 측엽을 감소시킨다. 레이다는 재머가 표적과 같은 위치에 있는 자체보호 재머에 대해서는 재밍 효과를 쉽게 예측할 수 있으나, 표적과 다른 위치에서 재밍하는 원격지원 재머에 대해서는 재밍 효과를 예측하기가 어렵다. 본 논문에서는 LPI 레이다의 측엽을 재밍하는 원격지원 재머의 재밍 효과를 신호재밍비(SJR)와 재밍 유효 한계거리를 사용하여 분석하였다. 또한 안테나의 측엽이 -30dB 이하인 경우에는 재밍 효과가 미약하여, 안테나 주엽에 대한 원격지원 재밍 방법을 제안하고 재밍 효과를 분석하였다. 본 연구는 항공기용 원격지원 재머 설계 및 운용에 유용하게 사용될 것으로 판단된다.

Properties of Activated Carbon Blacks Filled SBR Rubber Composites

  • Ao, Geyou;Hu, Quanli;Kim, Myung-Soo
    • Carbon letters
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    • 제9권2호
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    • pp.115-120
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    • 2008
  • Rubber reinforcing carbon black N330 was treated by physical activation under $CO_2$ to different degrees of burn-off. The mechanical properties indicating the reinforcement of SBR (Styrene-Butadiene Rubber) vulcanizates filled by activated carbon blacks, such as tensile strength, modulus at 300% strain and elongation at break were determined. During $CO_2$ activation of fresh carbon blacks, the development of microporous structure caused an increase of extremely large specific surface area and the porosity turned out to be an increasing function of the degree of burn-off. The tensile strength and modulus at 300% of activated carbon blacks filled rubber composites were improved at lower loading ratios of 20 and 30 phr, but decreased drastically after 30 phr, which is considered that it might be difficult to get a fully dispersed rubber mixture at higher loading ratios for fillers having very large specific surface areas. However, the Electromagnetic Interference (EMI) shielding effectiveness of SBR rubber composites having activated carbon black at 74% yield were improved at a large extent when compared to those having raw carbon black and increased significantly as a function of increasing loading ratio.

SM45C 중실축의 마찰용접 기계적 특성에 관한 연구 (A Study on the Mechanical Properties of the Friction Welding with Solid Shaft of SM45C)

  • 구건섭
    • 한국생산제조학회지
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    • 제21권6호
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    • pp.932-937
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    • 2012
  • In the presented study, SM45C carbon steel parts were joined by friction welding. The welding process was carried out under optimized conditions using statistical approach. The study of SM45C is conducted with various combinations of process parameters. Parameter optimization, microstructure and mechanical property correlation are the major contribution of the study. The welded joints were produced by varying spindle revolution speed, friction pressure, upset pressure and burn-off length. Tension tests were applied to welded parts to obtain the strength of the joints. Fracturs properties were additionally obtained experimentally under fluctuated tensile loads. Microstructures using microphotographs were examined in the weld interface and weld region and heat affected zone and base metal and flash zone of welded parts. Finally, Hardness variations in welding zone and base metal were also obtained. Through these tests, the optimum conditions of parameters for ${\phi}20$ SM45C in friction welding were obtained when the friction spindle revolution was 1,950 rpm, the friction pressures was 30 MPs, upset pressures was 50 MPs.

고속 전원차단 회로 설계 제작 및 측정 (A Design of High-speed Power-off Circuit and Analysis)

  • 정상훈;이남호;조성익
    • 전기학회논문지
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    • 제63권4호
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    • pp.490-494
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    • 2014
  • In this paper, a design of high-speed power-off circuit and analysis. The incidence of high-dose transient radiation into the silicon-based semiconductor element induces the photocurrent due to the creation of electron-hole pairs, which causes the upset phenomenon of active elements or triggers the parasitic thyristor in the element, resulting in latch-up. High speed power-off circuit was designed to prevent burn-out of electronic device caused by Latch-up. The proposed high speed power-off circuit was configured with the darlington transistor and photocoupler so that the power was interrupted and recovered without the need for an additional circuit, in order to improve the existing problem of SCR off when using the thyristor. The discharge speed of the high speed power interruption circuit was measured to be 19 ${\mu}s$ with 10 ${\mu}F$ and 500 ${\Omega}$ load, which was 98% shorter than before (12.8 ms).

MCFC 배가스용 촉매연소기 연소특성에 관한 연구 (A Study on the Combustion Characteristics of MCFC Offgas Catalytic Combustors)

  • 이상민;이연화;안국영;박인욱
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.132.1-132.1
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    • 2010
  • Anode off-gas of high temperature fuel cells such as MCFC still contain combustible components such as hydrogen, carbon monoxide and hydrocarbon. Thus, it's very important to fully burn anode off-gas and use the generated heat in order to increase system efficiency. In the present study, catalytic combustors have been applied to high temperature MCFC system so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study has been focused on the experimental investigation on the combustion characteristics of multiple commercial catalysts having different structures and compositions. In order to determine the design conditions of the catalytic combustor, parameters such as inlet temperature, space velocity and excess air ratio have been varied and optimized for combustor design. Results show that $H_2$ in off-gas assists $CH_4$ combustion in a way that it decreases minimum inlet temperature limit and increases maximum space velocity while keeping high fuel conversion efficiency.

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MCFC Off-gas 촉매연소기 설계에 관한 연구 (A Study on the Design of MCFC Off-Gas Catalytic Combustor)

  • 이상민;이영덕;안국영;홍동진;김만영
    • 한국수소및신에너지학회논문집
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    • 제18권4호
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    • pp.406-412
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    • 2007
  • An experimental study on the design of a catalytic combustor for 1.6 kW MCFC system has been performed. The roles of the catalytic combustor are to completely burn anode off-gas and to supply sufficient $CO_2$ to cathode channels. In order to avoid hot spot or fuel slippage, flow uniformity at the catalyst inlet was achieved by installing two crossing perforated plates between the catalyst and the mixing chamber with minimal pressure drop. A Pd/Ce/Ni-$Al_2O_3$ catalyst was used for complete combustion of the off-gas at GHSV=36,000.

TEM Study of Micropores Developed on Pitch-based Carbon Fiber

  • Ryu, Seung-Kon;Lu, Ji Gui
    • Carbon letters
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    • 제7권2호
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    • pp.114-118
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    • 2006
  • Isotropic pitch-based carbon fiber has been activated by steam diluted in nitrogen in order to characterize the microporosity. Especially, 40 wt% burn-off ACFs were prepared from different conditions to compare the pore structure and size. The ACFs were thinly sliced to investigate the inside pores by TEM and image analyzer. As expected, the adsorption characteristics of these ACFs were quite different from one another because of different pore structure and size. Most pores are not slit-shaped but rather round. Small round micropores become broad and irregular as increasing the activation time and temperature.

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